• Journal of the Korean Ceramic Society
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• v.51 no.2
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• pp.72-81
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• 2014

The main mineral phases of natural hydraulic lime (NHL) as a hydraulic lime binderare $Ca(OH)_2$, $C_2S$, $C_3S$, $C_3A$, and $SiO_2$ residues. Also, NHL has the characteristic of setting and hardening by a hydration reaction with water and by carbonation reactions with carbon dioxide from the air. In this study, in an effort to investigate changes of the mineral phases by NHL hydration and carbonation reactions, transitions of mineral phases and the microstructures of hardened pastes were analyzed by XRD, DSC, SEM, and by pore size distributions using domestic and foreign-sourced NHL pastes after curing at 1, 3, 7, and 28 days. On the basis of the analysis results, it was confirmed that domestic low-grade limestone can be used for the manufacturing of NHL. The main hydration mineral phases were $Ca(OH)_2$, $CaCO_3$, $C_2S$, and $SiO_2$ residues, while in the case of foreign-sourced NHL, a small amount of an aluminium hydration phase formed. Also, the $CaCO_3$ content after the carbonation reaction increased with an increase in the curing time. After hydration for 28 days, NHL containing considerable amounts of $C_2S$ and $C_3S$ showed higher carbonation ratios than others types.

• Resources Recycling
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• v.12 no.2
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• pp.11-20
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• 2003

Limestone mine waste was used as a aggregate far permeable concrete. Void ratio, continuous void ratio, coefficient of permeability, compressive strength and flexural strength of concrete were measured and then the relationship between porosity and strength properties was investigated. Void ratio, continuous void ratio and strength properties of permeable concrete were greatly influenced by the grain size of aggregate and void filling ratio in comparison with the containing ratio of limestone mine waste. Furthermore, void ratio showed a good relation with continuous void ratio, and porosity of permeable concrete indicated a good relation with strength properties also. The coefficient of permeability of permeable concrete using limestone waste was over 0.2 cm/sec and was excellent result in comparison with normal concrete. Therefore, it could be expected that the limestone mine waste would be utilized as aggregate for pavement concrete, green concrete and water resource specie concrete in the results of this study.

• The Journal of Engineering Geology
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• v.25 no.4
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• pp.511-524
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• 2015

Groundwater causing subsidence in limestone mines is uncommon, and thus relatively poorly investigated. This case study investigated the cause and possibility of future subsidence through an evaluation of ground stability at the Samsung limestone mine, Chungcheongbuk-do. The ground near the mine area was evaluated as unstable due to rainfall permeation, and subsidence in the unmined area resulted from groundwater level drawdown. Future subsidence might occur through the diffusion of subsidence resulting from the small thickness of the mined rock roof, fracture rock joints, and poor ground conditions around the mine. In addition, the risk of additional subsidence by limestone sinkage in corrosion cavities, groundwater level drawdown due to artificial pumping, and rainfall permeation in the limestone zone necessitates reinforcements and other preventative measures.

• Advances in concrete construction
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• v.7 no.2
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• pp.87-96
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• 2019

Self-compacting concretes (SCC) are highly fluid concrete which can flow without any vibration. Their composition requires a large quantity of fines to limit the risk of bleeding and segregation. The use of crushed sand rich in limestone fines could be an adequate solution for both economic and environmental reasons. This paper investigates the influence of quarry limestone fines from manufactured crushed sand on rheological, mechanical and durability properties of SCC. For this purpose, five mixtures of SCC with different limestone fines content as substitution of crushed sand (0, 5, 10, 15 and 20%) were prepared at constant water-to-cement ratio of 0.40 and $490kg/m^3$ of cement content. Fresh SCC mixtures were tested by slump flow test, V-funnel flow time test, L-box height ratio, segregation resistance and rheological test using a rheometer. Compressive and flexural strengths of SCC mixtures were evaluated at 28 days. Regarding durability properties, total porosity, capillary water absorption and chloride-ion migration were studied at 180 days. For the two test modes in fresh state, the results indicated compatibility between slump flow/yield stress (${\tau}_0$) and V-funnel flow time/plastic viscosity (${\mu}$). Increasing the substitution level of limestone fines in SCC mixtures, contributes to the decrease of the slump flow and the yield stress. All SCC mixtures investigated achieved adequate filling, adequate passing ability and exhibit no segregation. Moreover, the inclusion of limestone fines as crushed sand substitution reduces the capillary water absorption, chloride-ion migration and consequently enhances the durability performance.

• Resources Recycling
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• v.31 no.6
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• pp.3-17
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• 2022

The cement industry, which is an energy-intensive and high carbon dioxide emission industry, requires strategy for carbon neutrality and sustainable development. Most domestic cement companies are generating electricity by waste heat recovery system to improve energy efficiency during cement processes; however, few studies exist on recycling of energy related to this. Certain countries with high cement production researched on modifying the conventional waste heat recovery system to maximize waste heat recovery using various methods such as applying the Rankine cycle depending on the temperature, comparing working fluids, applying two or more Rankine cycles, and combining with other industries. In this study, we reviewed the research direction for energy efficiency improvement by summarizing waste heat recovery and utilization methods in the domestic and overseas cement industries.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.1-8
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• 2023

In this study, to reduce CO₂ emission in the cement manufacturing process, we evaluated the limestone that is used as a raw material for cement, substituted with steel slag by the various substituted levels. Based on the chemical composition of each raw materials including limestone, and blast furnace slow cooling slag, converter slag, and KR slag as an alternative raw material, we simulated the optimal cement raw mixture by the substitution levels of limestone. Test results indicated that the steel slags contain a certain level of CaO that can be used as alternative decarbonated raw materials, and it has enough to partially reduce the amount of limestonem. And we estimated the maximum usable levels of each raw material. In particular, it was confirmed that by using a mixture of these raw materials rather than using them one by one, the effect of reducing limestone was increased and CO₂ emission from the cement manufacturing process could be reduced.

• Economic and Environmental Geology
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• v.23 no.4
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• pp.369-381
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• 1990

Most of significant ore deposits in South Korea such as the Sangdong W - Mo, the Yeonhwa Pb-Zn and the Geodo Cu-Fe skarn ore deposits occur at the southern limb of the Hambaeg syncline in the Taebaeg Basin. The mineralization took place in the interbedded limestone of the Myobong Formation and the Pungchon limestone of the Great Limestone Group of the Cambrian age, generally striking E-W and dipping 25-30 degrees north. There are no outcrops of the skarn-type orebody at the northern limb of the syncline. In order to find a clue of a possible hidden orebody localized at the limestones in the northern limb, a lithogeochemical exploration by using carbon isotope and some elements such as Si, Ca, Fe and Al at the Sangdong Mine area has been attempted as for a modelling study. For this study, 45 samples from the Pungchon limestone which do not show any megascopic indication of mineralization have been taken in both the mineralized zone and the unminerallized zone at the Sangdong Mine area. Analytical data show that there are big differences in the contents of CaO and $Al_2O_3$ between the Pungchon limestone of the mineralized zone and that of the unmineralized zone. Carbon isotope data exhibit that ${\delta}^{13}C$ values of the Pungchon limestone in the mineralized zone are highter than those in the unmineralized zone. The difference in the analytical values of CaO, $Al_2O_3$ and the carbon isotope between the mineralized and the unmineralized zones is as follows ; Unminerallized zone Mineralized zone CaO 51.3% 43.5% $Al_2O_3$ 0.6% 2.4% ${\delta}^{13}C$ -0.39 permil -0.56 permil $Fe_2O_3$ 0.9% 1.4% $SiO_2$ 3.0% 2.4% The decrease in the Si content of the Pungchon limestone in the mineralized zone is contrary to the result of the previous study (Moon, 1987). On the basis of identification of the increase in the Al content of the limestone in the mineralized zone, it could be deduced that the decrease in the Si content of the Pungchon limestone might be due to the result of increase in the alteration products mainly occurred along fracture-system such as joint cracks or minor faults and that the phenomena shown by the Si and Al content in the mineralized zone might be derived from the thermal effect of granite extended mineralizing activity to the overlied limestone on the surface. Higher mean values of Fe and Al as well as lower mean values of carbon content and the ${\delta}^{13}C$ than mean values of those in the Pungchon limestone at the northern limb of the Hambaeg Syncline may be applicable in exploration for blind orebodies.

• Nuclear Engineering and Technology
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• v.24 no.1
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• pp.98-109
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• 1992

In this study uniaxial cyclic loading tests were performed on Cheon-Ho Mt. Limestone specimens to investigate the fatigue failure behavior. The loading rate was kept constantly at 760kg/$\textrm{cm}^2$/sec under cyclic loading. In order to reveal the fatigue behavior for each rock type, the test results were mutually compared with previous studies carried out on Indiana Limes-tone and Seong-Ju Sandstone. Fatigue data is presented in the form of S-N curves, which illustrate the relationship of maximum applied stress(S) to the number of cycles(N) required to produce failure. For the purpose of comparing the S-N curves for each rock type, the test data were formulated up to 10$^4$cycles and the correlation coefficients(R) on Cheon-Ho Mt. Limestone and Seong-Ju Sandstone specimen are 0.886 and 0.983, respectively. All three rock specimens were found to have shorter fatigue life at higher applied stress levels. The fatigue life for each rock type was considered as no less than 81.5, 70 and 74.8%, for Cheon-Ho Mt. Limestone, Indiana Limestone and Seong-Ju Sandstone, respectively. The comparison in static strength for monotonic loaded specimens and specimens which did not fail even after 10$^4$cycles indicated that the increasing rate of strength was about 6.18 and 10.96% , for Cheon-Ho Mt. Limestone and Indiana Limestone, respectively. Poisson's ratio and volumetric strain for Cheon-Ho Mt. Limestone and Seong-ju Sandstone, tended in all the cases to rapidly increase at higher stress levels and with an increase in number of cycles. This increasing trend becomes rapid and obvious just before failure. Also Poisson's ratio and volumetric strain for each stress level were compared and analyzed at the first cycle and the cycle prior to failure.

• Economic and Environmental Geology
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• v.19 no.3
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• pp.225-230
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• 1986

Various interpretations on the boundary between the $Okch{\check{o}}n$ system and the Great Limestone series of the $Chos{\check{o}}n$ system, and on the geologic structure and stratigraphy of the $Okch{\check{o}}n$ system have been yielded by the previous studies, and they are still in hot debate. The present work has mainly studied on the boundary between the $Okch{\check{o}}n$ and $Chos{\check{o}}n$ systems in the south of $Jech{\check{o}}n$, and the geology in its vicinity to clarify the previous misinterpretations if any on the geologic structure and in trun stratigraphy of the area concerned. The boundary between the $Okch{\check{o}}n$ system and the Great Limestone series of the $Chos{\check{o}}n$ system has been thought to be (1) gradational relation which means two systems are the same formation, (2) unconformable relation in which the $Okch{\check{o}}n$ system overlies the $Chos{\check{o}}n$ system, (3) unconformable relation in which the $Chos{\check{o}}n$ system overlies the Okchon system indicating that the age of the $Okch{\check{o}}n$ system is Precambrian, and (4) fault contact in which the $Okch{\check{o}}n$ system of Precambrian age comes in contact with the $Chos{\check{o}}n$ system of Cambro-Ordovician age. The present study clearly found that the relationship between the two systems is a fault zone contact. Shear zone of a width of 300 to 400m is developed, and andesitic volcanics and basic dikes are intruded along the fault zone. This fault contact is exactly the north extension of the Bonghwajae fault, which was denominated long time ago by two of the present authors. The eastern side of the fault has been uplifted so that the $S{\check{o}}changri$ formation of the $Okch{\check{o}}n$ system cropped out in the zone of the Great Limestone series. All the previous workers thought that the $S{\check{o}}changri$ formation rests on the Great Limestone series, but the present study found an overthrust having a strike of $N8^{\circ}E$ and dip of $30^{\circ}NW$ between them, and the $S{\check{o}}changri$ formation has thrusted over the Great Limestone series at the central part of the study area. In the southern and northern parts of this uplifted $S{\check{o}}changri$ formation, the Great Limestone series rests unconformably on it. In the eastern part of the study area where the Mt. Dangdu is located and the previous workers thought that the $S{\check{o}}changri$ formation rests on the Great Limestone series, Precambrian basement rock whose age is older than 1720+50 m.y. crops out in the northern part of the east-west trending high angle fault, and the Great Limestone series rests unconformably on the basement.

• The Journal of Engineering Geology
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• v.24 no.1
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• pp.39-52
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• 2014

Limestone caves that consist of main passages and branches are formed by a variety of processes, and have the characteristic of developing with a preferred orientation controlled by discontinuities such as bedding, joints, and faults around the cave. However, it is difficult to analyze a representative orientation from various orientations. To interpret the overall development orientation of limestone caves, this study proposes new development orientation analysis methods, termed the Average Span Ratio Method (ASRM) and the Individual Development Ratio Method (IDRM), using the weighting of persistence. Nine limestone caves in Korea were randomly selected for testing the new methods. The methods show a stronger development orientation for limestone caves than that obtained by traditional methods, which consider only the distribution of development orientations. Based on an analysis of the relationship between the average span and the dip angle of bedding, it is confirmed that shallowly dipping bedding is a major contributor to the expansion of span in limestone caves. In addition, using scan-line survey data acquired in the field, we perform an RMR analysis of stability of the ground around limestone caves.