• Title/Summary/Keyword: LCP (liquid crystal polymer)

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Preparation and Dielectric Properties of LCP and BaTiO3 Composites (LCP(Liquid Crystal Polymer)와 BaTiO3복합체의 제조 및 유전특성)

  • 윤기현;이승주;양병덕;김종희
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1183-1188
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    • 2003
  • LCP (Liquid Crystal Polymer)/BT(BaTiO$_3$) composite was prepared by mixing LCP varnish and BT slurry. And the effect of the composition of LCP/BT composites and the size of BT powder on dielectric properties of LCP/BT composite were investigated. The dispersion properties of BT slurries were also studied as a function of volume fraction of dispersant, GLYMO (3-glycidyloxypropyltrimethoxysilane) added to various sized BT powders. The quantity of optimum dispersant in BT slurry decreased with an increase of BT powder size because of the decrease of specific surface area of BT powder. LCP/BT composite sheet was prepared by tape-casting method with mixing BT slurry and LCP varnish. The dielectric constant of the composites increased from 34.3 to 44.1 and their dielectric loss increased from 0.05 to 0.063 as the size of BT powder increased from 100 nm to 500 nm.

Bending and Pressing Tolerance of Flexible Polyoxetane based Liquid Crystalline Polymer/Low Molecular Weight Liquid Crystal Device

  • Jang, Chi-Woong;Lim, Tong-Kun;Kim, Moo-Jong;Kim, Ku-Nam;Kwon, Young-Wan;Jin, Jung-Il;Bae, Jung-Hun;Kim, Han-Sik
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.433-435
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    • 2005
  • We have studied the realigning behavior of liquid crystal molecules in liquid crystalline polymer/liquid crystal(LCP/LC) system when they are exposed to external stimulation such as bending and pressing. The birefringence of the LCP/LC in a flexible display device was measured as a function of bending or pressing deformation. The microscopic dynamic behavior of main chain, side chain, and the LC were characterized by FTIR and polarization optical microscopy. When the device is deformed in scattering memory state, liquid crystal(LC) director is found to align from randomly oriented domain state(scattering state) to homeotropic state.

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Comparison of Band Pass Filter Performance Using Liquid Crystal Polymer Substrate in Millimeter-Wave Band (밀리미터파 대역에서 액정 폴리머(Liquid Crystal Polymer) 기판을 이용한 대역통과필터 비교)

  • Oh, Yeonjeong;Lee, Jaeyoung;Choi, Sehwan
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.2
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    • pp.39-44
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    • 2021
  • In this paper, two types of BPF(Band Pass Filter) which are hair-pin and interdigital have been designed for millimeter-wave application using two types of material which are LCP(Liquid Crystal Polymer) and PTFE(Polytetrafluoroethylene) and also, their performances such as bandwidth, insertion loss, and in-band flatness are compared. The proposed BPF are designed as third-order filters, and their pass band is from 26.5 GHz to 27.3 GHz. Interdigital BPF using PTFE substrate has most wide -3 dB S21 bandwidth of 7.8 GHz and hair-pin BPF using LCP substrate has most narrow -3 dB S21 bandwidth among the proposed four BPF. For in-band insertion loss, hair-pin BPF using PTFE substrate achieves low insertion loss better than -0.667 dB, and hair-pin BPF using LCP substrate exhibits relatively high insertion loss among the proposed four BPF better than -0.937 dB. However, the maximum difference in insertion loss performance among the proposed four BPF is 0.27 dB, which is too small to negligible. For in-band flatness, interdigital BPF using PTFE substrate shows greatest performance of 0.017 dB, and hair-pin BPF using LCP substrate exhibits the lowest performance of 0.07 dB. There are tiny difference in in-band flatness performance of 0.053 dB. As a results, it is considered that the BPF using LCP substrate can derive the performances similar to that of the BPF using PTFE substrate in Millimeter-wave band.

Investigation on Hermeticity of Liquid Crystal Polymer Package for MEMS Based Safety Device (MEMS 기반 안전 소자에 대한 액정 폴리머 패키지의 밀폐도 연구)

  • Choi, Jinnil;Kim, Yong-Kook;Ju, Byeong-Kwon
    • Journal of Sensor Science and Technology
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    • v.24 no.5
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    • pp.287-290
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    • 2015
  • Liquid crystal polymer (LCP) is a thermoplastic polymer with superior mechanical and thermal properties. In addition, its characteristics include very low water absorption rate and possibility to apply bonding process under low temperature. In this study, LCP is utilized as a packaging material for a microelectronic system (MEMS) based safety device with suggestion of a low temperature packaging process. Highly sensitive and stable capacitive type humidity sensor is fabricated to investigate hermeticity of the packaged MEMS device.

Solid State Interfacial Phenomena of High Performance Two Phase Polymer System(I) -Preparation and Characteristics of Liquid Crystalline Polyester and Poly(ε-caprolactam) Alloy- (고기능 고분자 복합재의 고상계면 현상에 대한 연구(I) -액정 Polyester와 Poly(ε-caprolactam) Alloy의 제조와 그 특성)

  • Kang, Doo Whan;Kang, Ho Jong;Jung, Hyo Sung;Lee, Yong Moo
    • Applied Chemistry for Engineering
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    • v.8 no.1
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    • pp.49-58
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    • 1997
  • LCP/PA alloy was prepared by blending poly(${\varepsilon}-caprolactam$) (PA) with liquid crystal polyester, Vectra (LCP) having high elasticity and strength. The alloy prepared amorphous PA with more than 10 parts of thermotropic LCP had poor compatibility. To increase the compatibility of the alloy, compatibilizing agent, poly(glycinylmaleimide-co-methylmetacrylate)[poly(GMI-co-MMA)] copolymer was prepared by copolymerizing N-glycinylmaleimide(GMI) with methylmetacrylate(MMA). And then, it was blended with LCP and PA to produce LCP/PA alloy having an excellent compatibility. The compatibility characteristics of the alloy prepared from LCP and PA using the poly(GMI-co-MMA) was determined by measuring the thermal characteristics of glass transition temperature of nematic LCP, and rheological properties, and also high rate impact and flexual characteristics of the alloy were determined.

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Preparation and Dielectric Properties of Ceramic(BNT)-Polymer(LCP) Composite (세라믹(BNT)-폴리머(LCP) 복합체 제조 및 유전특성)

  • Park, Myoung-Sung;Chun, Myoung-Pyo;Cho, Jung-Ho;Nam, Joong-Hee;Choi, Byung-Hyun;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.11
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    • pp.935-940
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    • 2009
  • In this research, the composites (100-x)LCP-xBNT (x = 0, 10, 20, 30, 40 vol.%) were fabricated with thermoplastic LCP(Liquid Crystal Polymer) and BNT($BaNd_2Ti_4O_{12}$) which is a high frequency dielectric material. Their dielectric properties, mechanical strength and microstructure were investigated by Impedance analyser, Instron and SEM. In order to fabricate LCP-BNT composites, LCP resin was put into the twin screw type mixer($310^{\circ}C$), melted by keeping for 10 min. After that, BNT filler was dispersed with melted LCP resin for 15 min. in the mixer. For measuring the dielectric properties and mechanical strength, Composite specimens were made by pressing composite granule (LCP-BNT) with 7 ton in the mold at $310^{\circ}C$. With increasing the BNT content (0~40 vol.%) of the composite, Its dielectric constant increased, dielectric loss and flexural strength decreased. The dielectric constant and flexural strength of composites with 20~30 vol.% of BNT filler are 4.1~6.0 and 35~55 MPa respectively. BNT/LCP composite is the potential substrate material for the high frequency application.

Preparation and Dielectrics Properties of Ceramic-polymer Composite Materials (세라믹-폴리머 복합체 제조 및 유전 특성)

  • Park, Myoung-Sung;Myoung, Seong-Jae;Chun, Myoung-Pyo;Jo, Jung-Ho;Nam, Joong-Hee;Kim, Byung-Ik;Nahm, Sahn
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.182-183
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    • 2008
  • 본 연구에서는 유전 손실이 낮고, 고분자(LCP)의 유전율을 높이기 위하여 (100-x)LCP(polymer)-xNPO(ceramic) 복합체 (x= 0, 10, 20, 30, 40, 50)의 유전 특성 및 미세구조를 연구하였다. LCP와 ceramic filler(NPO)는 Brabender Mixer를 사용하여 $300^{\circ}C$에서 혼합한 후, Hot press 사용하여 $300^{\circ}C$, 7ton 성형 압력으로 pellet 형태 $(2.5cm\times2.5cm\times0.1cm)$로 제조 하였다. LCP-NPO 복합 소재를 SEM을 통해 미세구조를 관찰하였고, 복합체의 유전 특성을 조사하였다.

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Dielectric and Mechanical Properties of BNT-LCP Composites

  • Park, Myoung-Sung;Cho, Jeong-Ho;Kim, Byung-Ik;Chun, Myoung-Pyo;Nahm, Sahn
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.7
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    • pp.547-553
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    • 2011
  • We investigated the dielectric and mechanical properties of ceramic polymer composite xBNT - (1-x)LCP (x= 0, 10, 20, 30, 40 vol.%). The disk shaped BNT ($BaNd_2Ti_4O_{12}$) - LCP (liquid crystal polymer) composite samples were prepared by compression molding method. With increasing the BNT content in composites from 10 to 40 vol.%, the dielectric constant increased but the dielectric loss as well as bending strength of composites reduced. These composites were well described with modified Lichtenecker's model having k = 0.392 and 0.303 for the first and second ball milled BNT filled composites, which means that the BNT filler in composites are well dispersed. The dielectric constant of the composite comprised of the second milled BNT ($D_{50}$ = 1.39 um) was higher that of the composite of the first milled BNT ($D_{50}$= 2.45 um), which seems to be related with the different particle size and dispersion of BNT fillers in LCP matrix. The bending strength of the composite containing the second milled BNT was superior to that of the composite of the first milled BNT.

Thermal and Electro-Optic Properties of a Side Chain Liquid Crystalline Polysilozanes cotaining a Low Molecuar Weight LIquid Crystal

  • Lee, Tae-Jeong;Kim, Eun-Yeong;Huh, Jae-Ho;Wang, Young-Soo;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 1997.10a
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    • pp.32-35
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    • 1997
  • Aggregation states ans electro-optic properties of a binary mixture by mixing a side chain type liquid crystalline polymer(LCP) and a low molecular weight liquid crystal(LMLC) have been studied. Side chain liquid crystalline polysiloxanes were synthesized from allyl bromide, p-hydroxy benzoic acid, p-cyanophenol, p-methoxyphenol and polysiloxanes. Low molecular weight liquid crystals were synthesized from allyl bromide, p-hydroxy benzoic acid and 4-cyano 4'-hydroxy biphenyl. And then, their properties were compared with blended liquid crystals. The thermal properties of the blended liquid crystals were evaluated using differential scanning calorimetry. The phase behavior of blended sample with temperature were also observed polarized microscope with hot stage. Thus, it seemed to us that a study of LC polysiloxanes with LMLC would be useful, especially in view of the fact that, systematic investigations have been carried out on the effects of changes in LCP/LMLC binary system on the properties of this relatively new type of liquid crystal.

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