• Title/Summary/Keyword: LB films

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Study on air-water interface phenomenon and electrical property of Arachidic acid LB films (LB법을 이용한 Arachidic acid LB막의 공기-물 계면현상과 전기적특성 연구)

  • Ryu, Kil-Yong;Lee, Nam-Suk;Park, Jae-Chul;Choi, Yong-Sung;Lee, Kyung-Sub;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.263-264
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    • 2006
  • 본 연구에서는 Arachidic acid Langmuir-Blodgett (LB)막의 계면특성과 전기적 특성을 측정하였다. Arachidic aicd는 포화지방산으로 ($CH_3(CH_2)_{18}COOH$)의 구조를 가지며, 크기가 27.5[$\AA$]으로 $CH_3(CH_2)_{18}$의 소수기와 COOH의 친수기로 구성되어 있다. LB막은 박막제작시 배열과 배향의 제어가 용이하다. Chloroform을 용매로 하여 2[mmol/l]의 농도를 조성하여 ${\pi}-A$ 등온선을 통해 기체 상태, 액체 상태, 고체 상태를 관찰하였으며 편광각 현미경 (Brewster angle microscopy) 이미지를 통해 각 상태에서의 이미지를 관찰하였다. 또한 LB막의 제작시 사용되어진 ITO 기판은 친수처리 전 후의 접촉각의 측정을 통하여 막의 안정성을 확인하였다. 또한 LB막을 Metal/LB막/Metal 구조의 소자로 제작하여 전압-전류 특성을 측정하였다.

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Stimulus Current of Mixed Organic Thin Films (혼합 유기박막의 자격 전류)

  • Cho, Su-Young;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.464-466
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    • 2000
  • In the study We measured the MDC across lipidazobenzene monolayer system was the substrate. We discuss the cis-trans isomerization in Langmuir-Blodgett(LB) films and examine the relationship between the structure of mixed LB films and the generation of MDCs due to photoisomerization. As results, mixed induce monolayer of view to memory and switching, it's own function by particles level think. Also, transmission results of stimulus signal it's form by current to appear.

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Study on preparation and characterization of PPV LB films. (Poly(p-phenylenevinylene) (PPV) LB 막의 제작 및 특성 연구)

  • Kim, J.H.;Kim, K.S.;Kang, W.H.;Sohn, M.H.;Kim, Y.C.;Kim, Y.K.;Sohn, B.C.
    • Proceedings of the KIEE Conference
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    • 1994.11a
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    • pp.219-221
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    • 1994
  • Oil-soluble poly(p-phenylene(1-methoxyethylene)), as a precursor of poly(p-phenylenevinylene) (PPV), was synthesized add identified with NMR and FT-IR spectroscopy. The PPV films were prepared by PPV precursor films with a thermal treatment at $250^{\circ}C$ under vacuum, where the PPV precursor films wets formed on various substrates by using Langmuir-Blodgett(LB) method. The characterization of these films was carried out by FT-IR spectroscopy, UV-VIS absorption spectroscopym, and photoluminescence (PL). Atomic Force Microscopy (AFM) has been used to investigate He surface morphology of PPV films.

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Electronic Properties of MIM Structure Organic Thin-films that Manufacture by LB method (LB법으로 제작한 MIM 구조 유기 박막의 전자특성)

  • Choi, Young-Il;Lee, Kyung-Sup;Lim, Jung-Yeol;Song, Jin-Won
    • 전자공학회논문지 IE
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    • v.43 no.4
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    • pp.99-104
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    • 2006
  • The Langmuir-Blodgett(LB) technique has attracted considerable interest in the fabrication of electrical and electronic devices. Maxwell displacement current (MDC) measurement has been employed to study the dielectric property of Langmuir-films. MDC flowing across monolayers is analyzed using a rod-like molecular model. A linear relationship between the monolayer compression speed u and the molecular area Am. Compression speed a was about 30, 40, 50mm/min. Langmuir-Blodgett(LB)layers of Arachidic acid deposited by LB method were deposited onto slide glass as Y-type film. The structure of manufactured device is Au/Arachidic acid/Al, the number of accumulated layers are 9$\sim$21. Also, we then examined of the Metal-Insulator-Metal(MIM) device by means of I-V. The I-V characteristics of the device are measured from -3 to +3[V]. The insulation property of a thin film is better as the distance between electrodes is larger.

Stability to the Dispersion Solvent of (N-docosyl pyridinium)-TCNQ(1:2) Complex for Langmuir-Blodgett Technique (Langmuir-Blodgett법을 위한 (N-docosyl pyridinium)-TCNQ(1:2)착체의 분산용매 중에서의 안정성)

  • Shon, Byoung-Chung;Kim, Dong-Sik;Jeong, Soon-Wook
    • Journal of the Korean Applied Science and Technology
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    • v.7 no.2
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    • pp.41-45
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    • 1990
  • A Stability to the dispersion solvent, which is acetonitrile, dichloromethane, benzene, chloroform and acetonitrile-benzene(1:1,v/v) of {N-docosyl pyridinium)-TCNQ(1:2)complex was investigated by U.V Spectrophotometer and was confirmed stabilized on acetonitrile, the dichloromethane and acetonitrile-benzene (1:1,v/v) for seven hours. Using $CdCl_2$buffer solution as subphase for LB films deposition, it was achived successively to fabricate the Y-type LB films of (N-docosyl pyridinium)-TCNQ(1:2)complex. For the sake of verifying the deposition of LB films, U.V is measured by variation of nominal layer number.

A Study on the Insulation Characteristics of Organic Thin Films of Au/Pl/Au structure (Au/Pl/Au구조의 유기박막 절연성에 관한 연구)

  • Chon, D.K.;Kim, Y.K.;Cho, C.H.;Lee, K.S.;Choi, Y.I.
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1468-1470
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    • 1998
  • Using a solution of polyamic acid salt obtained in combination with polyimide acid, we successfully prepared thermally stable multilayers(41, 35, 31 layers) films disilane-containing polyimide by Langmuir-Blodgett(LB) technique. We studied the electrically phenomena occurring at the metal(Au)/polyimide(Pl) LB film/metal(Au). Also, we then examined the of Pl LB films by means of current-voltage (I-V) and resistance measurement.

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Surface Analysis of LB Films and Monolayer for IMI-O Polymer (IMI-O 고분자의 단분자막과 LB막에 대한 표면분석)

  • Jung, Sang-Burm;Yoo, Seung-Yeop;Park, Jae-Chul;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.265-268
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    • 2000
  • We fabricated an IMI-O polymer containing an imidazole group that could form a complex structure between the monolayer and the metal ions at the air-water interface. Also. the monolayer behavior at the air-water interface and the surface morphology of metal-complexed Langmuir-Blodgett(LB) films were investigated by using Brewster angle microscopy(BAM) and Scanning Maxwell-stress Microscopy(SMM). The difference in the BAM and SMM images between the pure water and the aqueous metal ions is attributed to the interactions of the copolymers with the metal ions at the interface and the consequent change of the monolayer organization.

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A study on the NO$_2$Gas Detection chracteristics of the Octa (2-ethylhexyloxy) copper-phthalocyanine LB film (Octa (2-ethyls expel oxy) copper-phthalocyanine LB막의 NO$_2$가스 탐지 특성에 관한 연구)

  • 임준석;김영관;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.121-124
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    • 1996
  • It is well known that the metallo- phthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as NO$_2$and also chemically and thermally stable. Therefore, lots of MPcs have been studied for the potential chemical sensor for NO$_2$gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy) copper-phthalocyanine were prepared by Langmuir -Blodgett method and characterized by using UV-VIS spectroscopy and ellipsometry. Transfer condition, and characterization of LB films were investigated and preliminary results of current-voltage(I-V) characteristics of these films exposed to NO$_2$gas as a function of film thickness, temperature and temperature were discussed.

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Electrical Properties of Organic Thin Films by Deposition Type (유기박막의 누적형태에 따른 전기특성)

  • 송진원;이경섭
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.287-290
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    • 2000
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 20[mN/m]. LB layers of Arac. acid deposited by LB method were deposited onto y-type silicon wafer as x, y, z-type film. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/arachidic acid/Al, the number of accumulated layers. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V].

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The Electro-Optic Properties of Ferroelectric P(VDF-TrFE) LB Films (강유전성 고분자 P(VDF-TrFE) LB박막의 전기광학 특성)

  • Kwak, Eun-Hwi;Jung, Chi-Sup
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.7
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    • pp.566-570
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    • 2010
  • Electro-optic modulators based on 25 monolayer langmuir-blodgett films of vinylidene fluoride and trifluoroethylene, P(VDF-TrFE), were fabricated. The LB films were prepared by transferring the monolayers on to an ITO coated glass with a surface pressure of 5 dyne/cm by use of the langmuir-schaefer deposition method. Measurement of the electro-optic coefficient has been carried out using a simple reflection techique. The E/O coefficient was found to be 154.9 pm/V and that value remained stable for at least 50 days.