• 한국전기전자재료학회논문지
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• 제27권2호
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• pp.97-103
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• 2014

Phase transition properties of the copolymer films of polyvinylidene fluoride (PVDF) and trifluoroethylene(TrFE), P(VDF-TrFE), were studied with X-ray diffraction (XRD) and polarization modulated ellipsometry (PME). XRD studies on both Langmuir-Blodgett (LB) films and spin coated films exhibit conversions from ferroelectric phase to paraelectric phase at $108{\pm}2^{\circ}C$ on heating and paraelectric phase to ferroelectric phase at $78{\pm}2^{\circ}C$ on cooling. The presence of the ferroelectric-paraelectric phase transition is also confirmed by the PME technique for the first time in this study. PME was proved to be a very sensitive tool in the measurement of the structural changes at the nano-thickness films.

• 한국전기전자재료학회논문지
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• 제27권3호
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• pp.184-188
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• 2014

The electro-optic properties in Langmuir Blodgett films of poly (vinylidene fluoride trifluoroethylene) are investigated in the crossover region between two and three dimensions. The absence of finite size effect is observed in the films thinner than 20 nm, which confirms that these films are two dimensional ferroelectrics. The copolymer LB film of P(VDF-TrFE) exhibits the largest electro-optic response(26 pm/V) at 10 layer thickness. The cross-over behavior of electro-optic effect around the 10 layer thickness was discussed with the formation of nanomesa after thermal annealing.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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• pp.90-93
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• 1994

A surface acoustic wave(SAW) sensor for the detection of odorants has been constructed by depositing various phospholipids and fatty acids onto the surface of the SAW device. Applying the Langmuir-Blodgett technique. it was possible to deposit the optimal number of layer which was found to be between 10 and 20. The characteristics of a SAW device operating at 310 MHz deposited with phosphatidyl choline were analysed. Menthone, amylacetate, acetion, and other organic gases sho7\\\\`ed different affinities to the coated lipids. An explanation is given for differant odorant affinities based on the monolayer properties of phospholipids. The identification of odorants depending on the type of lipid used for coating is discussed in terms of a comparison of their normalized resonant frequency chi It pat terns. Using a number of different lipid-coated SAW devices. odorants can be identified by a computerized pattern recognition algorithm.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
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• pp.1327-1329
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• 2006

We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 2, 10, 30[mN/m](gas state, liquid state, and solid state). The physicochemical properties of the LB films on the surface of pure water are studied by AFM. Also, we then examined of the Metal-Insulator-Metal(MIM) device by means of I-V.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.491-494
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• 2000

Conductive Langmuir-Blodgett(LB) films have recently attracted much interest from the viewpoint of ultrathin film conductors at the molecular level. The result shows that the Maxwell-displacement-current(MDC) measuring technique is useful in the detection of phase-transition over the entire range of molecule areas. At the liquid-solid phase transition, a striking feature in the present current measurement was observed; the I-A isotherm for a DPPC monolayer has sharp bend. Dynamic behavior of monolayers in the presence of an external field was also investigated using the current-measuring technique. Dynamic behavier of DPPC monolayer was measured by displacement current when the molecules are stimulated by pressure velocity. As result, it is known that current is generated of higher current pe마 as compression velocity become faster. Also, in order to clarify the reorganization of the lipid monolayers, it is instructive to plot the relationship between I and 1/$A^2$.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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• pp.150-152
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• 2002

This paper, experiment manufactures device of Metal/Poly-$\gamma-Benzyl\;_D-Glutamate$ Organic Films/Metal structure using PBDG and I-V properties and C-F properties. The I-V characteristic is measured that approve voltage from 0 to +2[V] of device and the distance between electrode is larger, could know that small current flow and thin film could know that had insulation property. C-F characteristic has each other affinity between the polarization amount and frequency. Dielectric constant of MIM device could know by dipole that is voluntary polarization of LB film that polarization is happened. The capacitor properties of a thin film is better as the distance between electrodes is smaller.

• 폴리머
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• 제29권4호
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• pp.392-398
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• 2005

Layer-by-layer(LbL) 흡착에 의한 poly(ethylene-alt-m미? anhydride) (PEMAh)/poly(4-vinyl pyridine) (P4VP) 자기조립 다층박막을 제조하였다. 자기조립 다층막을 이루는 PEMAh/P4VP 두 고분자 사이의 수소 결합과 정전기적 인력이 다층막을 이루는 원동력이라는 것이 푸리에 변환 적외선(FT-IR) 분광분석에 의해서 확인되었다. 다층막의 균일한 자기조립 과정은 PEMAh/P4VP 이중층막의 적층 수 증가에 따른 UV-vis 스펙트럼의 256 nm에서 나타나는 P4VP 특성 흡수 피크의 선형적 증가에 의해서 확인할 수 있었다. 다층막을 이루는 고분자 전해질 담지 용액의 조건 변화가 다층막 형성에 미치는 영향을 살펴보기 위하여 두 고분자 용액의 농도 및 PEMAh 담지용액의 pH를 변화시키면서 다층막을 제조하였다. 다층막의 두께, 흡착된 고분자 전해질 질량 및 표면 거칠기의 변화를 UV-vis 분광 분석, 수정진동자 미량저울(quartz crystal microbalance;QCM) 및 원자 힘 현미경(atomic force microscopy;AFM)을 이용하여 측정하였다.

• 산업식품공학
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• 제14권1호
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• pp.49-53
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• 2010

표면 플라즈몬 공명을 이용한 센서는 굴절계 기기의 일종으로서 높은 감도를 가질 뿐만 아니라 비표지 방식이라는 장점을 가지고 있다. 본 연구에서는 재래식 SPR 칩을 이용하여 시판 술 4종의 알코올 함량을 측정하였다. 또한, 재래식 SPR 칩의 감도를 개선하기 위하여 금 박막 위에 금으로 나노형상을 구축하여 나노형상 SPR 칩을 제조하여 모형 술에 대한 감도 개선 효과를 분석하였다. 재래식 SPR 칩을 이용하여 시판 술의 알코올 함량을 측정하기 위한 검량선을 개발하였을 때 시료를 전처리 하지 않고 그대로 측정하였을 때 가장 좋은 검량선을 얻을 수 있었다. 소주, 청주, 이과두주, 탁주 등 시판 술 4종에 대한 1차 회귀식의 검량식에서 결정계수는 각각 0.992, 0.933, 0.918, 그리고 0.984로 나타났다. 한편, 재래식 SPR 칩의 감도를 개선하기 위해 나노형상 SPR 칩을 제조하기 위하여 Langmuir-Blodgett(LB) 방법을 활용하였다. 본 연구에서는 수십 nm 두께의 금 박막을 바닥층으로 하여 그 위에 나노 크기의 실리카 입자를 단분자 층으로 덮어 형틀을 제조하고 다시 그 위에 금을 증착한 후 실리카 입자를 제거하는 방법으로 나노형상을 갖는 SPR 칩을 제조하였다. 나노형상 SPR 칩의 성능을 평가하였을 때 20% 알코올 함량을 가지는 모형 술에 대해서 바닥층의 두께가 50 nm, 나노형상에서 골의 깊이가 20 nm, 나노형상의 배열주기가 300 nm일 때 SPR의 감도가 가장 좋아서 95%의 감도 향상을 얻을 수 있었다. SPR의 감도는 칩과 관련된 인자, 시료의 종류 및 상태에 따라 다르게 나타날 수 있으므로 측정 목적에 알맞은 칩의 설계와 선택이 요구된다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
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• pp.103-106
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• 2003

It is well known that the state of existence of molecules on the surface of water changes during compression of the molecules. Electric methods, such as measurement of the surface potential or displacement current are also useful for investigating dynamic changes of molecular state on the water surface during compression. In this paper, We studied on the Bio thin film by Langmuir-Biodgett(LB) method. The Experiment method used displacement current, $\pi-A$ isotherm and BAM (Brewster Angle Microscopy). using the BAM, we can to the molecular orientation of monolayer on the water surface and directly see the morphology of the films on water subphase as well as that of the films.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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• pp.147-149
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• 2002

Recently, the study on development of electrical and electronic device is done to set miniature, high degrees of integration and efficiency by using inorganic materials the study of Langmuir-Boldgett(LB) method that uses organic materials because of the limitation for the ultrasmall size. The structure of MIM(Metal-Insulator-Metal) device is Cr-Au/PBLG/ Al. the number of accumulated layers are 1, 3, 5, 7, 9. The I-V characteristic of the device is measured from 0[V] to 2[V] and the characteristic of current-time of the devices. We have investigated the capacitance because PBLG system have a accumulated layers the maximum value of measured current is increased as the number of accumulated layers are decreased. The capacitor properties of a thin film is better as the distance between electrodes is smaller. The results have shown the insulating materials and could control the conductivity by accumulated layers.