• Title/Summary/Keyword: LAMBDA system

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Synthesis and Characterization of Phosphorescent Platinum and Iridium Complexes of 6-Chloro-3-phenylpyridazine

  • Lee, Sang-Jin;Seok, Kang;Lee, Jae-Sung;Lee, Seung-Hee;Hwang, Kwang-Jin;Kim, Young-Kwan;Kim, Young-Sik
    • Journal of Photoscience
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    • v.10 no.2
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    • pp.185-187
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    • 2003
  • The preparation and the photophysics of organometallic Pt(II) and Ir(III) complexes with 6-ch1oro-3-phenylpyridazine (H6Clppdz) are reported. $K_2$PtCl$_4$ and IrCl$_3$ㆍn$H_{2}O$ cleanly cyclometalate with H6Clppdz, forming the corresponding chloro-bridged dimers, (6Clppdz)Pt($\mu$-Cl)$_2$Pt(6Clppdz) and (6Clppdz)$_2$Ir($\mu$-Cl)$_2$Ir(6Clppdz)$_2$ in good yield. These chloro-bridged dimers are cleaved with acetylacetone (Hacac) to give the corresponding monomer, (6Clppdz)Pt(acac) and (6Clppdz)$_2$ Ir(acac), respectively. Both complexes show bright orange luminescence at room temperature and the emission wavelengths are different depending on the metal and the structure of complexes. (6Clppdz)Pt(acac) shows two sharp emission bands in shorter wavelength ($\lambda$$_{em}$=541 and 580 nm), while (6Clppdz)$_2$ Ir(acac) shows a broad emission band in longer wavelength ($\lambda$$_{em}$=615 nm). Strong spinorbit coupling due to the heavy metal atom allows for the formally forbidden mixing of the $^1$MLCT with the $^3$MLCT and $^3$$\pi$-$\pi$$^{*}$ states.

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Effect of Ethanol-gasoline Blending Ratio on Lean Combustion and Exhaust Emissions Characteristics in a SI Engine Fueled with Bioethanol (바이오에탄올 SI 엔진에서 에탄올-가솔린 연료 혼합비율에 따른 희박연소 및 배기 특성)

  • Yoon, Seung-Hyun;Kim, Dae-Sung;Lee, Chang-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.1
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    • pp.82-88
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    • 2011
  • Lean combustion and exhaust emission characteristics in a ethanol fueled spark-ignited engine according to ethanol-gasoline fuel blending ratio were investigated. The test engine was $1591cm^3$ and 10.5 of compression ratio SI engine with 4 cylinders. In addition, lambda sensor system was connected with universal ECU to control the lambda value which is varied from 1.0 to 1.5. The engine performance and lean combustion characteristics such as brake torque, cylinder pressure and rate of heat release were investigated according to ethanol-gasoline fuel blending ratio. Furthermore, the exhaust emissions such as carbon monoxide (CO), unburned hydrocarbon (HC), nitrogen oxides ($NO_x$) and carbon dioxide ($CO_2$) were measured by emission analyzers. The results showed that the brake torque, cylinder pressure and the stability of engine operation were increased as ethanol blending ratio is increased. Brake specific fuel consumption (BSFC) was increased in higher ethanol blending ratio while brake specific energy consumption (BSEC) was decreased in higher ethanol blending ratio. The exhaust emissions were decreased as ethanol blending ratio is increased under overall experimental conditions, however, some specific exhaust emission characteristics were mainly influenced by lambda value and ethanol-gasoline fuel blending ratio.

Design of Robust DC-DC Converter by High-Order Approximate 2-Degree-of-Freedom Digital Controller

  • Takegami, E.;Tomioka, S.;Watanabe, K.;Higuchi, K.;Nakano, K.;Kajikawa, T.
    • 제어로봇시스템학회:학술대회논문집
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    • 2004.08a
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    • pp.232-237
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    • 2004
  • In many application of DC-DC converters, loads cannot be specified in advance, i.e., their amplitudes are suddenly changed from the zero to the maximum rating. Generally, design conditions are changed for each load and then each controller is re-designed. Then, a so-called robust DC-DC converter which can cover such extensive load changes and also input voltage changes with one controller is needed. Analog control IC is used usually for the controller of DC-DC converter. Simple integral control etc. are performed with the analog control IC. However it is difficult to retain sufficient robustness of DC-DC converter by these techniques. The authors proposed the method of designing an approximate 2-degree-of-freedom (2DOF) controller of DC-AC converter. This controller has an ability to attain sufficient robustness against extensive load and DC power supply changes. For applying this approximate 2DOF controller to DC-DC converter, it is necessary to improve the degree of approximation for better robustness. In this paper, we propose a method of designing good approximate 2DOF digital controller which makes the control bandwidth wider, and at the same time makes a variation of the output voltage very small at a sudden change of resistive load. The proposed good approximate 2DOF digital controller is actually implemented on a DSP and is connected to a DC-DC converter. Experimental studies demonstrate that this type digital controller can satisfy given specifications.

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Optical Characterization of Sensory Rhodopsin II Thin Films using a Near-field Scanning Microwave Microscope (근접장 마이크로파 현미경을 이용한 로돕신의 광학적 특성 연구)

  • Yu, Kyung-Son;Kim, Song-Hui;Yoon, Young-Woon;Lee, Kie-Jin;Lee, Jung-Ha;Choi, Ah-Reum;Jung, Kwang-Hwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.1
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    • pp.80-85
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    • 2007
  • We report the electro-optical properties of the sensory rhodopsin II using a near-field scanning microwave microscope(NSMM). Rhodopsin was known as a photoreceptor pigment with a retinal as a chromophore via a protonated Schiff base and consists of seven ${\alpha}-helical$ transmembrane segments. The sensory rhodopsin II, expressing E. coli UT5600 with endogenous retinal biosynthesis system and purified with $Ni^{-2}-NTA$ affinity chromatography in the presence of 0.02 % DM (Dodecyl Maltoside) from Natronomonas pharaonis. We measured the absorption spectra and the transients difference of sensory rhodopsin II from Natronomonas pharaonis using a UV/VIS spectrophotometer with Nd-Yag Laser (532 nm). The absorption spectra of NpSR II showed a typical rhodopsin spectrum with a left shoulder region and the photointermediates spectra of NpSR II-ground state (${\lambda}max=498\;nm$), NpSR II-M state (${\lambda}max=390\;nm$), and NpSR II-O state (${\lambda}max=550\;nm$) during the photocycle. The observed photocycle reaction was confirmed by measuring the microwave reflection coefficient $S_{11}$ at an operating frequency of f=3.93-3.95 GHz and compared with the results of a photocycle of NpSR II.

Gaussian apodization for annular pupil (윤대 동구에 대한 Gaussian Apodization)

  • 송영란;이민희;이상수
    • Korean Journal of Optics and Photonics
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    • v.7 no.3
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    • pp.196-199
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    • 1996
  • The amplitude LSF(Line spread function, $C_1e^{{o^2}{x^2}}$ or amplitude impulse) of the Gaussian apodized annular pupil is found to be same to that of the full aperture LSF($C_0e^{{o^2}{x^2}}$). $C_0$ and $C_1$ depending on $\sigma$, ${\omega}_0=\frac{2{\pi}}{\lambda}\;\frac{a_0}{l}$ and ${\omega}_0'=\frac{2{\pi}}{\lambda}\;\frac{a_0'}{l}$ which are the geometric parameter and pupil coordinates of the annular pupil. The important inequality relation among ${\omega}_0,\;{\omega}_0'$, a (fraction of diffraction amplitude) and $\sigma$ is obtained. It is $\frac{{\omega}_0}{\sqrt{2}}<{\sigma}{\le}(\frac{1-a}{2a})^{1/2}\;{\omega}_0$, and in the case of $a=e^{-1},\;a_0'{\le}0.34a_0$. The case of λ=0.013${\mu}{\textrm}{m}$, l=20 cm, $a_0=5cm$ and $a_0=0.34a_0=1.7cm$ give a Gaussian apodized superresolution ${\Delta}=\frac{\sqrt{log2}}{\sigma}=0.008{\mu}m$ annular pupil with the intensity signal equal to $e_{-2}$ times the signal obtainable by using the full aperture system(a=1)

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Control System of Asian corn borer, Ostrinia furnacalis (Guenee) in Coix lacryma-jobi L. var. ma-yuen Stapf (율무의 조명나방 방제체계)

  • Chang, Seog-Won;Kim, Hee-Dong;Kang, Chang-Sung;Kim, Sung-Kee
    • Korean Journal of Medicinal Crop Science
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    • v.8 no.1
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    • pp.74-78
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    • 2000
  • This study was carried out to select the effective insecticides for control of Ostrinia furnacalis(Guenee) in Yonchon, northern part of Kyunggi province, where is main producing region of adlay in Korea. The Asian corn borer in adlay field had three generations a year. The first stage of adult activity was higher from late May to middle June, the second from late July to early August and the third late September. Based on difference in control value, the relative ranks of some insecticides were lambda cyhalothrin EC > cartap hydrochloride GR > carbaryl EC. In control value by different application timing of Lambda cyhalothrin EC, yields were significantly different, that is, twice applications on second generation showed the control value of $90.6%{\sim}93.5%$. Unhulled grain yield on Lambda cyhalothrin EC treated plot on second generation was higher than that in untreatred plot by 82%.

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Suggestion for Determination of DCM Design Parameter Based on the Statistical Method (통계적 방법을 이용한 DCM설계정수 결정을 위한 제안)

  • Jeong, Gyeong-Hwan;Shin, Min-Shik;Han, Gyeong-Tae;Lee, Jung-Hwa;Kim, Jae-Hwan
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.462-471
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    • 2008
  • The quality control for DCM is based on the unconfined compressive strength of laboratory treated soils, the cement contents, setting and checking the strength of in-situ treated soils. Also the strength of in-situ is checked mainly by the core boring. In case of large size construction, it might be considered the distribution of DCM strength data as normal distribution, so it might be employed a statistical method to evaluate DCM strength easily. In Japan, it has been established correlation between the strength of laboratory treated soils, the strength of in-suit treated soil and the design strength. Also It has been employed domestically the correlation suggested by Japan. But the correlation, so called $\lambda$(ratio in the strength of laboratory treated soils and the in-suit) and $\gamma$(ratio in the strength of in-suit and the design strength), might be far different with the domestic due to different DCM system and soil properties. so it might be restrictive to use domestically. Therefore in this paper, It is presented correlation between the strength of laboratory treated soils and in-suit treated soil to be employed domestically by evaluating $\lambda$ based on the domestic in-suit illustrations.

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Design of a 28GHz 8-Directional Switched Beamforming Antenna System Utilizing Butler Matrix (버틀러 매트릭스 기반 28GHz 8-방향 스위칭 빔포밍 안테나 시스템 설계)

  • Shin, Sungjin;Shin, Hyunchol
    • Journal of the Institute of Electronics and Information Engineers
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    • v.54 no.1
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    • pp.11-17
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    • 2017
  • In this paper, an 8-direction switched beamforming antenna system at 28GHz frequency band is described for 5th generation wireless communication. This system is composed of an $8{\times}8$ Butler matrix and an 8-element patch array antenna. The antenna system switches beams in 8-direction in the wide range of ${\pm}40^{\circ}$. The antenna spacing is $0.65{\lambda}$ to achieve ${\pm}40^{\circ}$ steering range. Designed results show that the 8-direction beams are placed at ${\pm}6^{\circ}$, ${\pm}17^{\circ}$, ${\pm}28^{\circ}$, ${\pm}40^{\circ}$ offset from the center. Parasitic radiation effect from the large dimension Butler matrix need to be suppressed by employing a stripline structure.

Research on Earthquake Occurrence Characteristics Through the Comparison of the Yangsan-ulsan Fault System and the Futagawa-Hinagu Fault System (양산-울산 단층계와 후타가와-히나구 단층계의 비교를 통한 지진발생특성 연구)

  • Lee, Jinhyun;Gwon, Sehyeon;Kim, Young-Seog
    • The Journal of the Petrological Society of Korea
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    • v.25 no.3
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    • pp.195-209
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    • 2016
  • The understanding of geometric complexity of strike-slip Fault system can be an important factor to control fault reactivation and surface rupture propagation under the regional stress regime. The Kumamoto earthquake was caused by dextral reactivation of the Futagawa-Hinagu Fault system under the E-W maximum horizontal principal stress. The earthquakes are a set of earthquakes, including a foreshock earthquake with a magnitude 6.2 at the northern tip of the Hinagu Fault on April 14, 2016 and a magnitude 7.0 mainshock which generated at the intersection of the two faults on April 16, 2016. The hypocenters of the main shock and aftershocks have moved toward NE direction along the Futagawa Fault and terminated at Mt. Aso area. The intersection of the two faults has a similar configuration of ${\lambda}$-fault. The geometries and kinematics, of these faults were comparable to the Yansan-Ulsan Fault system in SE Korea. But slip rate is little different. The results of age dating show that the Quaternary faults distributed along the northern segment of the Yangsan Fault and the Ulsan Fault are younger than those along the southern segment of the Yansan Fault. This result is well consistent with the previous study with Column stress model. Thus, the seismic activity along the middle and northern segment of the Yangsan Fault and the Ulsan Fault might be relatively active compared with that of the southern segment of the Yangsan Fault. Therefore, more detailed seismic hazard and paleoseismic studies should be carried out in this area.

Effects of Hydrogen-enriched LPG Fuelled Engine on Exhaust Emission and Thermal Efficiency [II] (LPG엔진에서 수소첨가가 배기 성능과 열효율에 미치는 영향 [II])

  • Kwon, T.Y.;Kim, J.H.;Choi, G.H.;Chung, Y.J.
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.4
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    • pp.297-303
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    • 2002
  • The purpose of study is obtaining low-emission and high-efficiency in LPi engine with hydrogen enrichment. The test engine was named variable compression ratio single cylinder engine (VACRE). The fuel supply system provides LPG/hydrogen mixtures based on same heating value. A varied sensors such as crank shaft position sensor (CPS) and hall sensor supplies spark timing data to ignition controller. Displacement of VACRE is $1858.2cm^3$. VACRE was runned 1400rpm with compression ratio 8. Spark timing was set MBT without knocking. Relative air-fuel ratio($\lambda$) of this work was varied between 0,8 and 1.5.