• Bulletin of the Korean Chemical Society
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• v.30 no.2
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• pp.378-382
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• 2009

Rates of solvolyses of benzhydryl chloride ($Ph_2$CHCl, 1) and benzhydryl bromide ($Ph_2$CHBr, 2) in ethanol, methanol, and aqueous binary mixtures incorporating ethanol, methanol, 2,2,2-trifluoroethanol (TFE) and acetone are reported. Solvolyses were also carried out in TFE-ethanol mixtures. Application of the extended Grunwald-Winstein equation led to l value of 1.19 (1), 1.29 (2) and m value of 1.00 (1), 0.77 (2), correlation coefficient of 0.965 (1) and 0.970 (2). Sensitivities (l = 1.19 (1), 1.29 (2) and m = 1.00 (1), 0.77 (2)) were similar to those obtained for several previously studied solvolyses, in which an $S_N$2 pathway is proposed for the solvolyses of benzhydryl halides ($Ph_2$CHX, X = Cl or Br).

• Korean Linguistics
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• v.77
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• pp.331-357
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• 2017

The purpose of this paper is to identify the workings of intonation realized in the endings through the spoken language. To achieve this objective, this paper has analyzed 300 minutes of spontaneous speech by women from Seoul and discussed the meanings of modality and their relationship with intonation. Intonation functions significantly in polysemous modal endings in epistemic and act modality. Epistemic modality is usually expressed through indirect and soft intonations such as L:, M: and LH, whereas act modality is expressed through direct and strong intonations such as H, HL and LHL. Intonation appears to be related to the Certainty degree of information, rather than classification of modality, Lengthening relate to indirectness, H with uncertainty, L with statements or affirmation, and HL and LHL relates to assertive attitude. This paper is significant as it has overcome the abstractness of existing modality studies and has engaged in objective and comprehensive analysis with actual spontaneous speech data.

• Bulletin of the Korean Space Science Society
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• 2004.04a
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• pp.77-77
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• 2004

인공위성은 정상궤도에 들어선 후부터 수명을 다하는 시기까지 각종 복사, 열(온도차), 고진공, 미세중력, 미세운석과 우주파편 등에 의해 영향을 받게 된다. 특히, 위성체에 미치는 열환경은 위성이 궤도를 그리며 운동하는 동안 태양과 지구로부터의 복사량의 크기 및 분포에 따라 결정되는데, 약 5,50$0^{\circ}C$의 흑체온도를 갖고 있는 태양과 -27$0^{\circ}C$의 심우주는 위성체에서 태양이 비추는 부분과 반대편과의 온도를 극한으로 만들게 된다. (중략)

• Electrical & Electronic Materials
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• v.9 no.10
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• pp.1033-1039
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• 1996

Electrical and mechanical properties of polymer sheet at cryogenic temperature have been investigated. Tensile stress(and strain at break) in liquid nitrogen(77K) of 79.7MPa(l.2%) and 117.4MPa(2.05%) are evaluated for films of Polypropylene (PP) and Kapton, respectively. Dielectric loss tangent(tan .delta.) of PP and Kapton films is almost independent of the frequency and tensile stress. Also, field strength of PP film at 77K decreases with increasing the tensile stress.

• Journal of the Chungcheong Mathematical Society
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• v.33 no.1
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• pp.77-87
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• 2020

In this paper, we investigate the stability of a functional equation f(x + 3y) - 5f(x + 2y) + 10f(x + y) - 8f(x) + 5f(x - y) - f(x - 2y) - 2f(-x) - f(2x) + f(-2x) = 0 by using the fixed point theory in the sense of L. Cǎdariu and V. Radu.

• Bulletin of the Korean Chemical Society
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• v.28 no.1
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• pp.77-80
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• 2007

As neurofilament proteins are major cytoskeletal components of neuron, abnormality of neurofilament is proposed in brain with neurodegenerative disorders such as Parkinson's disease (PD). Since oxidative stress might play a critical role in altering normal brain proteins, we investigated the oxidative modification of neurofilament-L (NF-L) induced by the reaction of cytochrome c with H2O2. When NF-L was incubated with cytochrome c and H2O2, the protein aggregation was increased in cytochrome c and H2O2 concentrationsdependent manner. Radical scavengers, azide, formate and N-acetyl cysteine, prevented the aggregation of NFL induced by the cytochrome c/H2O2 system. The formations of carbonyl group and dityrosine were obtained in cytochrome c/H2O2-mediated NF-L aggregates. Iron specific chelator, desferoxamine, prevented the cytochrome c/H2O2 system-mediated NF-L aggregation. These results suggest that the cytochrome c/H2O2 system may be related to abnormal aggregation of NF-L which may be involved in the pathogenesis of PD and related disorders.

• 한국방재학회:학술대회논문집
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• 2008.02a
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• pp.783-786
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• 2008

The main goal of this study is to understand the effects of direct-runoff of chemistry and organic fertilizers which are adsorbing to sediment from farmland and non-point source discharge characteristics which are discharged to stream with soil erosion when rainfalls. pollutographs of TSS, BOD, COD, TN, and TP were measured for 10 rainfall events at watershed. EMC (Event Mean Concentration) were calculated for each rainfall event using quality and quantity measured. The result shows that the EMC ranges of 95% confidence intervals are 50.5-203 mg/L for TSS, 0.8-14.2 mg/L for $BOD_5$, 4.2-20.7 mg/L for $COD_{Mn}$, 0.2-0.5 mg/L for TP, 2.4-4.5 mg/L for TN, 1.36-3.04 mg/L for NO3--N, 0.13-0.42 mg/L for NH4+-N and 0.82-1.77 mg/L for TKN.

• Proceedings of the Korean Society of Crop Science Conference
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• 1997.10a
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• pp.76-77
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• 1997

• Journal of Contemporary Eastern Asia
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• v.20 no.1
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• pp.77-81
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• 2021

• Microbiology and Biotechnology Letters
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• v.24 no.2
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• pp.222-226
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• 1996

The enzymatic synthesis of 3, 4-dihydroxyphenyl-L-alanine (L-DOPA) was examined for the effects of the reaction additives such as sodium borate, alcohol, and organic solvents. The enzyme used was tyrosine phenol-lyase of Citrobacter freundii KCTC 2006 produced in Escherichia coli. The amounts of tyrosine phenol-lyase and pyridoxal-5-phosphate were optimized to 2.0 units/ml and 0.1 mM, respectively, for the synthetic reaction. Sodium borate, a substance that forms a complex with pyrocatechol, reduced the enzyme deactivation by pyrocatechol although it seriously inhibited the enzyme activity. Among the organic solvents tested, dimethylsulfoxide, dimethylformamide, and alcohol increased the productivity of the L-DOPA synthesis. In a reaction system with 5% methanol, L-DOPA concentration increased up to 210 mM after 24 hours, and 77.1% of which was separated as precipitates. The L-DOPA was purified to 99.96% by solubilizing and recrystallyzing the precipitates.