• Title/Summary/Keyword: Korean ash

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Carbonization of Coal-Fly Ash Containing High CaO Compound (CaO 화합물이 다량 함유된 비산재의 탄산화)

  • Sim, Jun Soo;Lee, Ki Gang;Kim, Yu Taek;Kang, Seung Ku
    • Journal of the Korean Ceramic Society
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    • v.50 no.1
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    • pp.18-24
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    • 2013
  • This study was conducted to recycle fly ash containing an abundance of CaO generated from combustion in a circulating layer as a carbon storage medium. The study utilized XRD, TG-DTA and XRF analyses during the hydration of fly ash and identified calcium substances within fly ash that could be used in a carbonation process. $Ca^{2+}$ ions in the calcium substances were easily converted to hydrates. A carbonation experiment was done, which used the method of $CO_2$ gas injection to produce suspensions by mixing fly ash with distilled water. The results were analyzed using TG-DTA, XRD, and pH meter measurements. The study was able to verify that the reaction was completed at a $CO_2$ flow rate of 300cc/min approximately 30 minutes after an injection into a solution with a solid-liquid ratio of 1 : 10 of fly ash and distilled water. Moreover, the stirring time of the suspensions did not influence the reaction, and the reaction time was found to diminish as the portion of the fly ash became smaller. Thus, this study produced carbon storage fly ash having a $CO_2$ storage rate of about 71% through the utilization of the CaO content contained within fly ash.

Char Oxidation Characteristics of High Ash Coal in Drop Tube Furnace (고회분탄의 촤 산화 반응 특성 연구)

  • An, Ke-Ju;Lee, Byoung-Hwa;Kim, Sang-In;Kim, Man-Cheol;Kim, Seung-Mo;Jeon, Chung-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.4
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    • pp.405-413
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    • 2013
  • The char oxidation characteristics of high ash coal were experimentally investigated at several temperatures (from 900 to $1300^{\circ}C$) for 4 types of coals (Gunvor, Glencore, Noble, and ECM) under atmospheric pressure in a drop tube furnace (DTF). The char reaction rate was calculated from the exhaust gas concentrations (CO and $CO_2$) using FT-IR, and the particle temperature was measured using the two-color method. In addition, the activation energy and pre-exponential factor for high ash coal char were calculated based on the Arrhenius equation. The results show that as the ash content increases, the particle temperature and area reactivity decreases. This is because in high ash coal, the large heat capacity of the ash, ash vaporization, and relatively low fixed carbon content of ash suppress combustibility during char oxidation. As a result, the higher ash content of coal leads to high activation energy.

Ash Drop Measuring on Tobacco Leaf Grades and Brand Cigarettes (잎담배 및 제품담배의 재떨어짐에 관한 연구)

  • Yang Burm-Ho;Ahn Dae-Jin;Jo Si-Hyung;Jeh Byong-Kwon;Kim Si-Mong;Kim Byeoung-Ku
    • Journal of the Korean Society of Tobacco Science
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    • v.26 no.2 s.52
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    • pp.117-125
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    • 2004
  • In this study, we have investigated the natural and puffing combustibility of cigarette brands and the compulsory ash-drop, and analysed factors related to the materials. Cigarette combustibility was greatly affected by the tobacco weight in cigarettes rod. Combustion rate of 4AOR cigarette made by flue-cured tobacco was 5.02 $^{mm}/_{min}\;and\;10\%$ faster than 1BO cigarette. Combustion pattern has interrelation with sugars, chlorine and ash contents among tobacco components. Combustion rate of 4DL, flue-cured tobacco was 55 seconds faster than 1CL tobacco extremely much in sugars contents, and ash drop was maintained at $21\%$ longer. Combustion time and burning rate were fast in cigarette made by expanded tobacco slice and tobacco stem and the formation of ash was poor. The length of puffed ash drop of expanded tobacco slice and tobacco stem were 18.6 mm and 25.2 mm and these forced ash drop length were 3.8 mm and 4.9 mm respectively. Puffed burning rate of general cigarette was $14.3\%$ faster than static burning rate and super slim type cigarettes was $21.3\%$ faster. Combustion rate and ash drop of domestic and foreign cigarette brands were quite different depending on tar level and cigarette types. The lower tar level, the faster combustion rate and the shorter ash drop.

PCDDs and DFs concentrations from the fly ash and bottom ash of industrial waste incinerators in Korean (산업폐기물 소각장의 바닥재와 비산재에서 PCDDs와 DFs 농도)

  • Kim, Ki-Woong;Won, Yong Lim;Ko, Kyung Sun;Choi, Yoon Jung;Lee, Sung Kwang
    • Analytical Science and Technology
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    • v.27 no.6
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    • pp.347-351
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    • 2014
  • This study determinated the polychlorinated dibenzo-${\rho}$-dioxins and dibenzofurans (PCDDs and DFs) in fly ash and bottom ash of industrial waste incinerators. Experimental results showed that average PCDDs and DFs concentrations in fly ash were 4.5063 and 13.004 ng-TEQ/g, and in bottom ash were 0.2367 and 0.0993 ng-TEQ/g, respectively. Predominant congener in TEQ of PCDDs/DFs from fly ash were 1,2,3,4,6,7,8-HpCDD, OCDD, 2,3,4,6,7,8-HxCDF, 2,3,4,7,8-PeCDF and in bottom ash were 1,2,3,7,8-PeCDD and 2,3,4,7,8-PeCDF.

Effect of Aluminum Potassium Sulfate Addition on the Color Change in Caesalpinia Sappan Dyeing by Rice Straw Ash Solution (볏짚 잿물 매염에 의한 소목 염색에서 명반 첨가가 색상변화에 미치는 영향)

  • Seo Hee-Sung;Jeon Dong-Won;Kim Jeon-Jun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.11
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    • pp.1465-1474
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    • 2005
  • The primary purpose of this study is to investigate the differences in the characteristics of the mordants, synthetic aluminum mordants and ash solutions as natural mordants, used in Caesalpinia sappan dyeing. By introducing aluminum potassium sulfate in the ash solutions, the behavior of the aluminum in the ash solutions were observed. In the rice straw ash solutions, adjusted to the levels of pH6 and pH10, the aluminum potassium sulfate was introduced to achieve various concentration levels. From the analysis of the ash solution of pull, $K^+$ and $Na^+$ ion concentrations were found to be extremely high, while $Al^+$ ion concentration was 0. The color development in the Caesalpinia sappan dyeing by ash solution mordanting was found to be mainly governed not by the mordanting actions of the metallic ions but by those of alkali components. In the case of cotton, the application of pH10 ash solution promoted reddish color development compared to the case of non-mordanting, regardless of the aluminum potassium sulfate addition. In the case of silk, the application of pH10 ash solution increased a* value and decreased b* value compared to the case of non-mordanting.

Characteristics of Thermal Conductivity of Concrete Containing Fine Bottom Ash Aggregates (바텀애시 경량골재를 사용한 콘크리트의 열전도율 특성)

  • Park, Ji-Hun;Jung, Hoe-Won;Yang, In-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.596-603
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    • 2020
  • In this paper, an experimental study was conducted to investigate the applications of bottom ash, which is an industrial by-product obtained from thermal power plants. Bottom ash was used as fine aggregate in this study, and an experiment was conducted to determine the characteristics of the bottom ash aggregate. In addition, 25, 50, 75, and 100% contents of crushed (natural) fine aggregate were replaced with bottom ash aggregate to produce concrete mixture including bottom ash. Thereafter, test results of the unit weight, ultrasonic velocity, compressive strength, and thermal conductivity of bottom ash concrete were obtained. Moreover, the effect of the curing ages of 28 and 91 days on the material characteristics of bottom ash concrete were identified. Test results showed that bottom ash used as fine aggregate had pozzolanic reaction. Finally, based on the extensive experimental results, relationships between thermal conductivity and unit weight, ultrasonic velocity, and compressive strength was suggested.

Characteristics of Uncofined Compressive Strength and Flow in Controlled Low Strength Materials Made with Coal Ash (석탄회를 활용한 저강도고유동화재의 일축압축강도 및 플로우 특성)

  • Kong, Jin-Young;Kang, Hyoung-Nam;Chun, Byung-Sik
    • Journal of the Korean Geotechnical Society
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    • v.26 no.1
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    • pp.75-83
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    • 2010
  • Controlled low strength material (CLSM) is a flowable mixture and does not need to be compacted. It is produced by mixing portland cement, fly ash, fine aggregates, water and chemical admixtures. Sand is the most commonly used fine aggregates in the conventional CLSM, but it is getting more and more difficult to obtain sand in Korea. In this study, the characteristics of unconfined compressive strength, flow and applicability of a new CLSM that is produced by mixing of pond ash, fly ash, water, cement are examined. An unconfined compressive strength satisfies the standard unconfined compressive strength (0.5~1.0 MPa) were obtained when the mixture ratio of pond ash and fly ash is 30:70~70:30, cement ratio is 3.0~5.0%, and water content is 31~34%. The results of flow test indicate that the mixture ratio of pond ash and fly ash which satisfy the standard How value (0.2 m) is 30:70~70:30.

Influence of Chemical Activators on Cement-Fly ash Paste and Strength Development of Concrete

  • Song, Jong-Taek;Yun, Sung-Dae;Kim, Jae-Young;Lee, Chin-Yong
    • The Korean Journal of Ceramics
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    • v.6 no.2
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    • pp.103-106
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    • 2000
  • The effects of replacement level, curing method and chemical admixtures were investigated in the cement-fly ash paste. The strength of cement-fly ash paste is lower than that of controlled cement paste only and the differences increase with replacement level. However, in steam curing, strength of cement-fly ash pastes is improved, especially, at early ages. In order to improve early strength, the use of $Na_2SO_4$in cement-fly ash paste increases the quality of concrete. In addition, improvement of strength of concrete including 30% of fly ash can be obtained and achieves the highest strength compared to other concrete mixtures.

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A Study on the Compressive Strength Property of Mortar using Rice Straw Ash (소성볏짚을 혼입한 모르타르의 압축강도 특성에 관한 연구)

  • Jeong, Euy-Chang;Shin, Sang-Yeop;Kim, Young-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.265-266
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    • 2012
  • The purpose of this study was to investigate the compressive strength property into mortar using rice straw ash. In an effort to evaluate the effects of rice straw ash firing temperatures on compressive strength properties of mortar, a change in the components of rice straw ash was observed according to firing temperatures, and compressive strength of mortar and X.R.F was measured. As a results, As the mortar with a mixture ratio of rice straw ash up to 15% was found to have a compressive strength superior to that of plain mortar.

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An Experimental Study on Elastic Properties of Rice Straw Ash Concrete (볏짚재 콘크리트의 탄성특성에 관한 실험적 연구)

  • 성찬용
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.42 no.1
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    • pp.92-98
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    • 2000
  • This study is performed to evaluate the elastic properties of rice straw ash concrete using reices straw ash, cement, natural sand, gravel, and superplasticizer. The following conclusions are drawn ; The ultrasonic pulse velicity is in the range of 4,084 ~4,336m/s , which has showed about the same compared to that of the normla cement concrete. The highest ultrasonic pulse velocity is showed by 5 % rice straw ash filled rice straw ash concrete. The dynamic and static modulus of elasticity is in the range of 294 $\times$10$^3$ ~347 $\times$ 10$^3$ and 266 $\times$10$^3$~328 $\times$10$^3$kgf/㎤ , respectively. It is showed about the same compared to that of the normal cement concrete. The Poisson's number of rice straw ash concrete is less than that of the normal cement concrete.

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