• Title/Summary/Keyword: Kinetic studies

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Analysis of Old Driver's Accident Influencing Factors Considering Human Factors (인적특성을 고려한 고령 운전자 교통사고 영향요인 분석)

  • Kim, Tae-Ho;Kim, Eun-Kyung;Rho, Jeong-Hyun
    • Journal of the Korean Society of Safety
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    • v.24 no.1
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    • pp.69-77
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    • 2009
  • This paper reports the aging driver traffic accident severity modeling results. For the modeling, Poisson regression approach is applied using the data set obtained from the Korea Transportation Safety Authority's simulator-based driver aptitude test results. The test items include the estimations of moving objects' speed and stopping distance, drivers' multi-task capability, and kinetic depth perception and so on. The resulting model with the response variable of equivalent property damage only(EPDO) indicated that EPDO is significantly influenced by moving objects' speed estimation and drivers' multi-task capabilities. More interestingly, a comparison with the younger driver model revealed that the degradation of such capabilities may result in severer crashes for older drivers as suggested by the higher estimated parameters for the older driver model.

Kinetic Studies on Enzymatic Hydrolysis of Cellulose(I) -Effect of Structural Features of Cellulose on Enzyme Adsorption- (섬유소 가수분해반응에 관한 연구(I) -효소흡착에 대한 섬유소의 구조적 특성-)

  • Lee, Yong-Hun;Kim, Chul
    • KSBB Journal
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    • v.6 no.2
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    • pp.157-166
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    • 1991
  • The structural properties of cellulose are significantly changed with the progress of hydrolysis reaction. The effects of changes on such properties of cellulosic substrate as crystallinity, amicessibility of enzyme to the active site of cellulose surface, and particle size on the kinetics of enzymatic hydrolysis have been studied. Among those physical studies, the apparent surface active site of cellulose particle was found to have the most significant effect on the hydrolysis kinetics. Based on the experimental results, the adsorption affinity of enzyme and hydrolysis rate were mainly influenced by the surface roughness of cellulose particle. The extent of accesssible active site may be expressed as the change of particle diameter. The Langmuir isotherm was proposed in terms of enzyme activity to explain the actual action of enzyme protein.

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An Analysis of Research Trend for Development of Creative Convergent Formative Education Program of Natural Structure Concept (자연구조개념 주제의 창의융합조형교육프로그램 개발을 위한 연구동향분석)

  • Choi, HanHee;Lim, KyungRan
    • The Journal of the Korea Contents Association
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    • v.17 no.1
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    • pp.465-474
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    • 2017
  • This study aimed to identify the trends of related research as a basic study for the development of creative convergent formative education program of natural structure concept. This study sought to identify research trends present in previous studies. The nature structure of the preliminary research was limited to the three concepts: (i) fractal ; (ii) kinetic and (iii) biomimicry. In this study, the trends of domestic research in the last 10 years related to the concept of natural structure were analyzed using academic research information service. It was found that, to date, little research has been conducted on the three concepts across education fields. In relation to the fractal concept, previous research has focused on mathematics. This preliminary study sought to review the abovementioned three concepts or the development of a modeling education program. It should be significant, if an education program adopted unlimited modeling principles to understand the innate features of the nature structure. However, very few education programs have adopted the three concepts of the nature structure. Future studies would seek to review international research trends based on the three concepts of the nature structure and combine the results on international research trends with the results on domestic research trends found in this study.

Studies on the Denitrification in the Submerged Paddy Soil -1. The Denitrification Rates Upon the Different Levels of Nitrogen Fertilizer in Sandy Soil (논토양(土壤)의 탈질작용(脫窒作用)에 관(關)한 연구(硏究) -제(第) 1 보(報). 사질답토양(砂質畓土壤)에서 질소시비량(窒素施肥量) 차이(差異)가 탈질(脫窒)에 미치는 영향(影響))

  • Lee, Sang Kyu;Kim, Seung Hwan;Park, Jun Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.1
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    • pp.94-98
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    • 1985
  • A laboratory experiment was conducted to find out the denitrification rate upon the different levels of nitrogen fertilizer in submerged sandy soil. The results obtained were summarized as follows: 1. The highest denitrification rate was observed at 25 days after incubation. The amount was reached at 1830 ug/100g soil for 20mg nitrogen was applied in 100g soil. 2. Increases of fertilizer nitrogen was enhanced the rate of ammonification and nitrification during the incubation time. 3. Deep correlation was observed between the denitrification capacities which was determined as nitrous oxide and Mitchaelis-Menten kinetic with relation to nitrate concentration. More higher denitrification rates were observed in Mitchaelis-Menten kinetic than dentrification rate with determined as nitrous oxide. 4. A Zero order (with relation to nitrate concentration) kinetic model for denitrification was presented in this experiment condition to illustrate the variability of nitrous oxide concentrations in the submerged soil atmosphere.

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Design of a Wastewater Treatment Plant Upgrading to Advanced Nutrient Removal Treatment Using Modeling Methodology and Multivariate Statistical Analysis for Process Optimization (하수처리장의 고도처리 upgrading 설계와 공정 최적화를 위한 다변량 통계분석)

  • Kim, MinJeong;Kim, MinHan;Kim, YongSu;Yoo, ChangKyoo
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.589-597
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    • 2010
  • Strengthening the regulation standard of biological nutrient in wastewater treatment plant(WWTP), the necessity of repair of WWTP which is operated in conventional activated sludge process to advanced nutrient removal treatment is increased. However, in full-scale wastewater treatment system, it is not easy to fine the optimized operational condition of the advanced nutrient removal treatment through experiment due to the complex response of various influent conditions and operational conditions. Therefore, in this study, an upgrading design of conventional activated sludge process to advanced nutrient removal process using the modeling and simulation method based on activated sludge model(ASMs) is executed. And a design optimization of advanced treatment process using the response surface method(RSM) is carried out for statistical and systematic approach. In addition, for the operational optimization of full-scale WWTP, a correct analysis about kinetic variables of wastewater treatment is necessary. In this study, through partial least square(PLS) analysis which is one of the multivariable statistical analysis methods, a correlation between the kinetic variables of wastewater treatment system is comprehended, and the most effective variables to the advanced treatment operation result is deducted. Through this study, the methodology for upgrading design and operational optimization of advanced treatment process is provided, and an efficient repair of WWTP to advanced treatment can be expected reducing the design time and costs.

Equilibrium and kinetic studies on the adsorption of copper onto carica papaya leaf powder

  • Varma V., Geetha;Misra, Anil Kumar
    • Membrane and Water Treatment
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    • v.7 no.5
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    • pp.403-416
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    • 2016
  • The possibility of using carica papaya leaf powder for removal of copper from wastewater as a low cost adsorbent was explored. Different parameters that affect the adsorption process like initial concentration of metal ion, time of contact, adsorbent quantity and pH were evaluated and the outcome of the study was tested using adsorption isotherm models. A maximum of 90%-94.1% copper removal was possible from wastewater having low concentration of the metal using papaya leaf powder under optimum conditions by conducting experimental studies. The biosorption of copper ion was influenced by pH and outcome of experimental results indicate the optimum pH as 7.0 for maximum copper removal. Copper distribution between the solid and liquid phases in batch studies was described by isotherms like Langmuir adsorption and Freundlich models. The adsorption process was better represented by the Freundlich isotherm model. The maximum adsorption capacity of copper was measured to be 24.51 mg/g through the Langmuir model. Pseudo-second order rate equation was better suited for the adsorption process. A dynamic mode study was also conducted to analyse the ability of papaya leaf powder to remove copper (II) ions from aqueous solution and the breakthrough curve was described by an S profile. Present study revealed that papaya leaf powder can be used for the removal of copper from the wastewater and low cost water treatment techniques can be developed using this adsorbent.

Kinetic and Mechanistic Studies of Oxidation of an Antiallergic Drug with Bromamine-T in Acid and Alkaline Media

  • Puttaswamy, Puttaswamy;Sukhdev, Anu
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3544-3550
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    • 2012
  • Cetrizine dihydrochloride (CTZH) is widely used as an anti-allergic drug. Sodium N-bromo-p-toluenesulfonamide or bromamine-T (BAT) is the bromine analogue of chloramine-T (CAT) and is found to be a better oxidizing agent than CAT. In the present research, the kinetics of oxidation of CTZH with BAT in acid and alkaline media was studied at 313 K. The experimental rate laws obtained are: -d[BAT]/dt=$k[BAT][CTZH]^{0.80}[H^+]^{-0.48}$ in acid medium and -d[BAT]/dt=$k[BAT][CTZH]^{0.48}[OH^-]^{0.52}[PTS]^{-0.40}$ in alkaline medium where PTS is p-toluenesulfonamide. Activation parameters and reaction constants were evaluated. The solvent isotope effect was studied using $D_2O$. The dielectric effect is positive. The stoichiometry of the reaction was found to be 1:1 and the oxidation products were identified as 4-chlorobenzophenone and (2-piperazin-1-yl-ethoxy)-acetic acid in both media. The rate of oxidation of CTZH is faster in acid medium. Suitable mechanisms and related rate laws have been worked out.

Association with Kinetic Characteristics of sperm in Duroc Boar and the Zygote Arrest 1 gene Polymorphism (g.2540T>C) (Zygote arrest 1 유전자 변이(g.2540T>C)와 두록 정액의 운동학적 특성과의 연관성 분석)

  • Lee, Mi Jin;Ko, Jun Ho;Cho, Kyu Ho;Choi, Tae Jeong;Kim, Yong Min;Kim, Young Sin;Jin, Dong Il;Cho, Eun seok;Kim, Nam Hyung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.116-123
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    • 2018
  • The sperm quality is determined by the kinetic characteristics and acrosome integrity of the sperm. In the previous studies, analysis of semen quality had large errors because those experiments by using microscope had been conducted by people. In recent years, the molecular biological methods have been newly developed to complement the previous techniques. The ZAR1 gene is known to be a gene that affects early embryonic development in vertebrates, but there is no study of the association with semen. In this study, we analyzed the association between the kinetic characteristics and ZAR1 single nucleotide polymorphism (SNP) genotype. To detect the SNPs, we performed sequencing using genomic DNA from the whole bloods of Duroc pigs. We identified an SNP in the ZAR1 gene g.2540T>C. ZAR1 SNP genotypeing in 105 pigs revealed that the major and minor alleles were T and C, respectively. After we analyzed the association between the kinetic characteristics of sperm and the ZAR1 SNP genotype, we found a significant association in MOT (p<0.01), VSL (p<0.05) of the kinetic characteristics in the Duroc boars. It was confirmed that the boars with T allele were lower in MOT and VSL than C allele. Therefore, pigs with C allele are judged to be better at the MOT and VSL of semen. Based on these results, ZAR1 SNP genotyping may be a useful molecular biomarker to improve semen quality by applying molecular breeding technology.

Analysis of Rebound Behavior of Blast-Resistant Door Subjected to Blast Pressure (폭압 작용에 의한 방폭문의 반발거동 해석)

  • Shin, Hyun-Seop
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.6
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    • pp.371-383
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    • 2021
  • Steel-concrete single-leaf blast-resistant doors, having steel box and slab inside, are installed on the wall using supporting members such as hinges and latches. Several studies have been conducted on their deflection behavior in the same direction as that of the blast pressure, but studies on their deflection behavior in the opposite direction, that is, studies on negative deflection behavior are relatively insufficient. In this study, we conducted a parameter analysis using finite element analysis on blast-resistant doors, on their rebound behavior in the negative deflection phase. Results revealed that the plastic deformation of the door, and the change in momentum and kinetic energy during rebound, were major factors influencing the rebound behavior. Greater rebound force was developed on the supporting members in the impulsive region, than in the quasi-static region; due to the characteristics in the impulsive region, where the kinetic energy developed relatively greater than the strain energy. In the design process, it is necessary to consider excessive deformation that could occur in the supporting members as the rebound behavior progresses. Additionally, it was found that in the case of steel-concrete blast doors, the rebound force increased relatively more, when the effects of both rebound and negative blast pressure contributed to the negative deflection of the door. Since conditions for the occurrence of this superposition effect could vary depending on structural characteristics and explosion conditions, further investigation may be required on this topic.

Adsorption Characteristics of Pb(II) and Cr(III) onto C-Methylcalix[4]resorcinarene (C-Metylcalix[4]resorcinarene에서 Pb(II)와 Cr(III)의 흡착 특징)

  • Jumina, Jumina;Sarjono, Ratnaningsih Eko;Siswanta, Dwi;Santosa, Sri Juari;Ohto, Keisuke
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.454-462
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    • 2011
  • A study on the adsorption characteristics of Pb(II) and Cr(III) cations onto C-methylcalix[4]resorcinarene (CMCR) has been conducted. CMCR was produced by one step synthesis from resorcinol, acetaldehyde, and HCl. Most parameters in batch system confirm that CMCR is a good adsorbent for Pb(II) and Cr(III). Cr(III) uptake was bigger than that of Pb(II), but Cr(III) adsorption rate was slower than Pb(II). The adsorption kinetic of Pb(II) and Cr(III) adsorptions in batch followed pseudo $2^{nd}$ order kinetics model, but the kinetic of Pb(II) adsorption in fixed bed column system followed first order model. Desorption studies to recover the adsorbed Pb(II) was performed sequentially with distilled water and HCl, and the results showed that the adsorption was dominated by chemisorption.