• Title/Summary/Keyword: Kinetic studies

Search Result 730, Processing Time 0.028 seconds

Moringa Oleifera, A Biosorbent for Resorcinol Adsorption-Isotherm and Kinetic Studies

  • Kalavathy, M. Helen;Swaroop, G.;Padmini, E.;Lima Rose, Miranda
    • Carbon letters
    • /
    • v.10 no.1
    • /
    • pp.23-32
    • /
    • 2009
  • The adsorption of phenolic compound resorcinol on activated carbons prepared from Moringa oleifera (Drumstick bark) has been investigated. Activated carbon was prepared by impregnating Moringa oleifera with 50% phosphoric acid in the ratio of 1:1 and 1:2(w/w), designated as MOAC1 and MOAC2. Equilibrium and isotherm studies were carried out. The influences of variables such as contact time, initial concentration of resorcinol, carbon dosage in the solution on percentage adsorption and adsorption capacity of the bark have been analysed. The equilibration time was found to be 4 h. Kinetics of resorcinol onto activated carbons was checked for pseudo first order and pseudo second order model. It was found that the adsorption of resorcinol follows pseudo second order kinetics for both MOAC1 and MOAC2. The isotherm data were correlated with isotherm models, namely Langmuir and Freundlich. Adsorption isotherms were satisfactorily fitted by both the Langmuir and Freundlich model for MOAC1 and MOAC2.

THE KINETIC STUDIES OF GLUCONIC ACID FERMENTATION (PART 1) Effect of Phenol and Catechol Derivatives on Oxygen Transfer in the Fermentation (Gluconic acid의 발효에 관한 연구(제1보) 발효조중 산소이동에 미치는 Phenol 유도분 및 Catechol 유도분의 영향)

  • LEE Keun-Tai;LEE Kyung-Hee
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.11 no.4
    • /
    • pp.205-211
    • /
    • 1978
  • The effect of phenol derivatives (guaiacol, vanillin, o-vanillin, eugenol) and catechol derivatives (pyrogallol, resoicinol) to enhance the volumetric oxygen transfer coefficient, in the aerobic fermentation was studies. Guaiacol, vanillin, o-vanillin, pyrogallol and resorcinol revealed to enchance the volumetric oxygen transfer coefficient, and eugenol had no such ability. The enhancement of the oxygen transfer ability is probably due to the formation of the charge transfer complex by the derivatives and oxygen molecules.

  • PDF

Basic Studies on Propellant Casting (II). Effects of Solid Additives on Urethane Polymerization (추진제 성형에 관한 기초연구 (제2보). 우레탄 중합에 미치는 첨가제 효과)

  • Young Gu Cheun;Ik Choon Lee;Shi Choon Kim
    • Journal of the Korean Chemical Society
    • /
    • v.25 no.4
    • /
    • pp.214-218
    • /
    • 1981
  • Kinetic studies were carried out on urethane polymerization reaction of hydroxyl-terminated polybutadiene with isophorone diisocyanate under presence of Hexogen as solid additive. The rate was found to increase with the amount of Hexogen added. However the rate acceleration was not a catalytic effect but solely due to an increase of activation entropy. The reaction was a good 2nd order process with nearly constant activation energy of 8.4 kcal/mole.

  • PDF

Removal of Heavy Metals from Aqueous Solution by Fly Ash

  • Cho, Hee-Chan;Oh, Dal-Young
    • Proceedings of the IEEK Conference
    • /
    • 2001.10a
    • /
    • pp.494-499
    • /
    • 2001
  • The present work investigates the possible use of fly ash for the removal of heavy metal ions from aqueous solutions. Batch experiments were conducted and the influences of metal concentration, pH, and fly ash concentration were investigated. Heavy metals used in these studies were zinc, lead and cadmium. Adsorption studies were done over a range of pH values (3-10) at $25^{\circ}C$ and heavy metal concentrations of 10-400 mg/L using fly ash concentrations of 10, 20 and 40 g/L. Experiments were also conducted without fly ash to determine the extent of heavy metal removal by precipitation. Kinetic and equilibrium experiments were performed and adsorption data were correlated with both Langmuir and Freundlich adsorption models. The results indicate that fly ash can be used as an adsorbent for heavy metals in the aqueous solutions, yet the degree of removal depends on the pH.

  • PDF

Characteristics of arsenic sorption on furnace slag in groundwater

  • S. R. Kanel;Saurabh Sharma;Park, Hechul
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2002.09a
    • /
    • pp.96-98
    • /
    • 2002
  • Furnace slag, a steel industry waste, has been converted into an inexpensive and efficient adsorbent. The product obtained has been utilized for the removal of arsenic from ground water. Kinetic studies have bepn described with the mechanism of adsorption The results from batch studies showed that the As(III) can be removed from the ground water within the pH range 3-7 However the maximum removal was experienced at pH 7.0. Equilibrium was attained within 24 hours. Adsorption data of arsenic correlate well with the Freundlich and Langmuir adsorption models. The maximum sorption capacity as calculated using Freundlich adsorption isotherm was found to be of 0.004 mg g-1 at pH 7 and $25^{\circ}C$.

  • PDF

Kinetic Studies on Production of Pullulan by Aureobasidium pullulans

  • Xiaobei Zhan;Xinlei Qian;Yihui Zhu;Lee, Jin-Woo
    • Journal of Life Science
    • /
    • v.11 no.2
    • /
    • pp.116-119
    • /
    • 2001
  • Xinlei studies on the production of pullulan by Aureobasidium pullulans using batch culture in a 15L bioreactor were carried out. The mathematical models were obtained in this study, which provided a reasonable description for the biomass, the product, and the substrate variation with time. The values frets the mathematical models were satisfactorily coincided with the experimental data for the biomass of A. pullulans, the production of pullulan and the utilization of sucrose as the sole carbon source.

  • PDF

Effectiveness of Group Art Therapy and Psychodrama in Changing Family Perceptions of Mothers (집단정신치료를 통한 어머니의 가족지각 변화에 대한 사례연구 - 집단미술치료와 집단정신치료극을 통하여 -)

  • Myung, Sin Young;Lee, Jung Sook
    • Korean Journal of Child Studies
    • /
    • v.21 no.4
    • /
    • pp.275-293
    • /
    • 2000
  • The study examined changes in mothers' perceptions about their families through group art therapy and group psychodrama. The 5 mothers selected as the experimental group were tested by Kinetic Family Drawing. The experimental group then participated in psychodrama This was a pre-test, 2 post-test experimental group only design. Each follow-up test was excused at 10 weeks after the previous test. Mothers' acting in the psychodrama was video-recorded. Subjects were interviewed to ascertain change in daily life after the psychotherapy. Results were that positive changes occurred in mothers regarding self-examination and understanding of their families. There were significant difference in the mothers' perceptions of themselves, their children and their families.

  • PDF

Studies on Screening and Isolation of .$\alpha$-Amylase Inhibitors of Soil Microorganisms (I)

  • Kwak, Jin-Hwan;Choi, Eung-Chil;Kim, Byong-Kak
    • Archives of Pharmacal Research
    • /
    • v.8 no.2
    • /
    • pp.67-75
    • /
    • 1985
  • To find emylase inhibitors produced by microorganisms from soil, a strain which had a strong inhibitory activity against bacteria .alpha.-amylase was isolated from the soil smaple collected in Seoul. The morphological and physiological characteristics of this strain on several media and its utilization of carbon sources showed that it was one of Streptomyces specties according to the international Streptomyces Project method. The amylase inhibitor of this strain was purified by means of acetone precipitation, adsorption on Amberlite XAD-2, and column chromatography on Amberlite CG-50 and SP-Sephadex C-25. The inhibitor was stable at the pH range of 1-10 and at 100.deg.C for half an hour, and had inhibitory activities against other amylases such as salivary .alpha.-amylase, pancreatic .alpha.-amylase, fungal .alpha.-amylase and glucoamylase. The kinetic studies of the inhibitor showed that its inhibitory effect on starch hydrolysis by .alpha.-amylase was non-competitive.

  • PDF

Experimental Studies on Risks of BB Pellets Using Gelatine Based Simulants (젤라틴 Simulant를 이용한 비비탄총 탄환의 위험성에 관한 실험적 연구)

  • Park, Dal-Jae;Kim, Hyung-Suk;Lee, Young-Soon
    • Journal of the Korean Society of Safety
    • /
    • v.26 no.3
    • /
    • pp.29-33
    • /
    • 2011
  • Experimental studies were performed to investigate the injury potential of BB pellets through gelatine based simulants. In order to record BB pellet movements penetrating into the target simulant, a high-speed video camera was used. In this study the first investigation involved the effects on concentrations, homogeneity and gelation times of the gelatine simulant. The second investigation involved the penetration depth of the pellets to the simulant by different distances between the BB gun and the simulant. The final one is associated with impact velocity, threshold velocity and penetration depth of the pellets by different kinetic energies of the BB gun. Results provided the basis in assessing the injury potential of BB pellets.

Analysis of Old Driver's Accident Influencing Factors Considering Human Factors (인적특성을 고려한 고령 운전자 교통사고 영향요인 분석)

  • Kim, Tae-Ho;Kim, Eun-Kyung;Rho, Jeong-Hyun
    • Journal of the Korean Society of Safety
    • /
    • v.24 no.1
    • /
    • pp.69-77
    • /
    • 2009
  • This paper reports the aging driver traffic accident severity modeling results. For the modeling, Poisson regression approach is applied using the data set obtained from the Korea Transportation Safety Authority's simulator-based driver aptitude test results. The test items include the estimations of moving objects' speed and stopping distance, drivers' multi-task capability, and kinetic depth perception and so on. The resulting model with the response variable of equivalent property damage only(EPDO) indicated that EPDO is significantly influenced by moving objects' speed estimation and drivers' multi-task capabilities. More interestingly, a comparison with the younger driver model revealed that the degradation of such capabilities may result in severer crashes for older drivers as suggested by the higher estimated parameters for the older driver model.