• Journal of the Korean Ceramic Society
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• v.35 no.5
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• pp.443-450
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• 1998

Layered double hydroxides(LDHs) [{{{{ {Mg }_{1-x } }}{{{{ {Al }_{x } }}({{{{ {OH}_{2 } }})]ζ+({{{{ {CO }`_{3 } ^{2- } ){ }_{x/2 } }}$.${{{{ { yH}_{2 }O }} wioth variation of layer charge densitywere synthesized by co-precipitation methdo since their charge densities have a very important role to be det-ermined the physicochemical properties of layered materials. The XRD IR and thermal studies of them were discussed and the kinetic study for the decarbonation reaction was also carried out. From the results of XRD analysis we found that the lattice parameter and the unit cell volume were linearly decreased with the amount of Al substituents(x) in the vicinity of x=2∼10${\times}$1/3${\times}$10-1 but they had nearly constant values when the x are far from these vicinit. The activation energies for the decarbonation reaction of x=6.8, 10${\times}$1/3${\times}${{{{ { 10}^{-1 } }} were estimated to be 47.0, 37.6, 39.3 kcal/mol The specific surface areas(90-120 m2/g) of stable hy-drotalcite-type LDHs were dractically decreased with increasing of layer charge density.

• BMB Reports
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• v.34 no.5
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• pp.457-462
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• 2001

Using the monomolecular film technique, we compared the interfacial properties of Staphylococcus simulans lipase (SSL) and Staphylococcus aureus lipase (SAL). These two enzymes act specifically on glycerides without any detectable phospholipase activity when using various phospholipids. Our results show that the maximum rate of racemic dicaprin (rac-dicaprin) hydrolysis was displayed at pH 8.5, or 6.5 with Staphylococcus simulans lipase or Staphylococcus aureus lipase, respectively The two enzymes interact strongly with egg-phosphatidyl choline (egg-PC) monomolecular films, evidenced by a critical surface pressure value of around $23\;mN{\cdot}m^{-1}$. In contrast to pancreatic lipases, $\beta$-lactoglobulin, a tensioactive protein, failed to inhibit Staphylococcus simulans lipase and Staphylococcus aureus lipase. A kinetic study on the surface pressure dependency, stereoselectivity, and regioselectivity of Staphylococcus simulans lipase and Staphylococcus aureus lipase was performed using optically pure stereoisomers of diglycerides (1,2-sn-dicaprin and 2,3-sn-dicaprin) and a prochiral isomer (1,3-sn-dicaprin) that were spread as monomolecular films at the air-water interface. Both staphylococcal lipases acted preferentially on distal carboxylic ester groups of the diglyceride isomer (1,3-sn-dicaprin). Furthermore, Staphylococcus simulans lipase was found to be markedly stereoselective for the sn-3 position of the 2,3-sn-dicaprin isomer.

• Proceedings of the Korean Society for Cognitive Science Conference
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• 2000.05a
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• pp.71-75
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• 2000

Conventional atom model must be criticized on the following four points. (1) Natural motions between positive and negative entities are not circular motions but linear going and returning ones, for examples sexual motion, tidal motion, day and night etc. (2) Potential energy generation was neglected when electron changes its orbit from outer one to inner one. The hv is the Kinetic energy of the photo-electron. The total energy difference between orbits comprises kinetic and potential energies. (3) The structure of the space must be taken into consideration because the properties of the electron do not change during the transition form outer orbit to inner one even though it produces photon. (4) Total energy conservation law applies to the energy flow between mind and matter because we daily experiences a interconnection between mind and body. New atomic model (the crystallizing $\pi$-bonding) was proposed in the journal of material processing technology since 1997 for the explanation of the mechanical behaviors in terms of physics. $\prod$-ray physics proved that the electrons can come out from in the nucleus and modern chemistry corresponds to the $\pi$-bonding by the nuclear electrons. The $\pi$-bonding structure of the protons outside the nucleus is that electrons move between protons of the different atoms. The perception step and the characteristic frequency in signal transduction is due to the accumulation of the $\pi$-rays outside fo the proton before their absorption to the nucleus.

• Proceedings of the Korean Society for Cognitive Science Conference
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• 2000.05a
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• pp.76-86
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• 2000

Conventional atom model must be criticized on the following four points. (1) Natural motions between positive and negative entities are not circular motions but linear going and returning ones, for examples sexual motion, tidal motion, day and night etc. (2) Potential energy generation was neglected when electron changes its orbit from outer one to inner one. The hv is the kinetic energy of the photo-electron. The total energy difference between orbits comprises kinetic and potential energies. (3) The structure of the space must be taken into consideration because the properties of the electron do not change during the transition from outer orbit to inner one even though it produces photon. (4) Total energy conservation law applies to the energy flow between mind and matter because we daily experiences a interconnection between mind and body. $\prod$-rays come out from the crystallizing $\pi$-bondings when they vibrate or deform. Gaston Naessens(1950) invented a microscope, which can visualize the $\pi$-rays in blood. Unordinarily agglomerated spores of $\pi$-rays may provoke poor immunity and bad illness. The agglomerated spores of $\pi$-rays can make closed type $\pi$-bondings in the case of carbohydrates and esters but proteins build open type $\pi$-bondings because the peptide bonds are planar, which principle produces a life.

• Composites Research
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• v.14 no.2
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• pp.33-42
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• 2001

The cure kinetic equation fur 52-glass/polyester prepreg composites was established through DSC (differential scanning calorimetry). Using the established kinetic equation, the temperature distribution of the thick composite was calculated considering the change of heat transfer resistance due to resin impregnation of bleeder plies used. In order to reduce the overheat during cure of thick glass fiber composites, the cure cycle was modified by introducing the cooling and reheating steps. Then the thick glass composites were cured both by the conventional cycle without any cooling or reheating step and the modified cure cycle. The mechanical properties of the thick composites cured by the both cycles were tested by the short beam shear test and the Barcol hardness test, and then their results were compared.

• Journal of Biosystems Engineering
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• v.23 no.6
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• pp.583-590
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• 1998

This study was performed to determine the kinetic friction coefficient bulk density, dynamic and static angle of repose, and terminal velocity of the chopped rice straw in the moisture range of 8~23%, which could be used for better design and operation of the processing machinery and handling facilities. Friction coefficient was determined from the horizontal traction force measured by pulling the container holding the mass of rice straw on the various plate materials. Bulk density was measured with an apparatus consisting of a filling funnel and a receiving vessel. Dynamic angle of repose was calculated from the photos of bulk samples piled by gravity flow on a circular platform. Static angle of repose was determined by measuring the side angle of the bulk material which was left in the cylindrical container after natural discharge of the bulk sample through a circular hole in the bottom plate. Kinetic friction coefficients of rice straw on the PVC, mild steel, stainless steel, and galvanized steel were in the range of 0.303~0.434, 0.222~0.439, 0.204~0.448, and 0.206~0.407, respectively. and indicated linear increase with moisture content. The effects of moisture change on the friction coefficients were in the order of PVC, mild steel, galvanized steel, and stainless steel. Bulk density, dynamic and static angle of repose, and terminal velocity were in the range of 56.8~60.3 kg/m$^3$, 41.4~45.9$^{\circ}$, 94.4~100.8$^{\circ}$, and 1.07~4.48 m/s, respectively, and were increased linearly with the moisture content.

• Analytical Science and Technology
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• v.8 no.4
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• pp.597-601
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• 1995

The transfer of chloride ion across an anion exchange membrane (AEM) was investigated by cyclic voltammetry (CV) and electrochemical impedance spectra. In CV experiment, when the size of the hole in membrane was much smaller than the distance between membrane holes, the Cl anion transfer showed steady state voltammetric behavior. Each hole in membrane can be regarded as a microelectrode and the membrane was equivalent to a microelectrode array in this condition. When the hole in membrane was large or the distance between membrane holes was small, the CV curve of the Cl anion transfer across membrane showed peak shape, which attributed to linear diffusion. In ac impedance measurement, the impedance spectrum of the membrane system was composed of two semicircles at low de bias, corresponding to the bulk characteristics of the membrane and the kinetic process of ion transfer, respectively. The bulk membrane resistance increases with increasing dc bias and only one semicircle was observed at higher dc bias. The parameters related to kinetic and membrane properties were discussed.

• Journal of Welding and Joining
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• v.24 no.1
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• pp.77-87
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• 2006

Considering ferrite grain size in the base metal, the prediction model for $A_{c3}$ temperature and prior austenite grain size at just above $A_{c3}$ temperature was proposed. In order to predict $A_{c3}$ temperature, the Avrami equation was modified with the variation of ferrite grain size, and its kinetic parameters were measured from non-isothermal data during continuous heating. From calculation using a proposed model, $A_{c3}$ temperatures increased with increasing ferrite grain size and heating rate. Meanwhile, by converting the phase transformation kinetic model that predicts the ferrite grain size from austenite grain size during cooling, a prediction model for prior austenite grain size at just above the $A_{c3}$ temperature during heating was developed.

• Journal of the Korean Society of Food Science and Nutrition
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• v.9 no.1
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• pp.59-73
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• 1980

A detailed procedure was described for the isolation of cratine kinase (ATP-Creatine phosphotransferase, E. C. 2. 7. 3. 2.) from the muscle of the snake Bungarus fasciatus. The original isolation procedure of Kuby et al. for the rabbit muscle enzyme has been modified and extended to include a chromatographic step. The properties of the enzyme have been investigated and kinetic constants for the reverse reactions determined as the followings: 1) A molecular weight of the enzyme was determined by gel filteration on Sephadex G-100 and by electrophoresis on SDS-polyacrylamide was 86,000. 2) Two reactive sulphydryl groups were detected with dithiobis nitrobenzoic acid (DTNB). 3) The nucleotide substrate specificity in the reverse reaction was determined as ADP*2'-dADP＞GDP＞XDP＞UDP with magnesium as the activating metal ion. 4) The order of the metal specificity in the reverse reaction Mg>Mn>$Ca{\sim}Co$ was determined with ADP as substrate. 5) A detailed kinetic analysis was carried out in the reverse direction with $MaADP^-$ as the nucleotide substrate. Initial velocity and product inhibition studies($MaADP^{2-}$ competitive with respect to MgADP- and noncompetitive with respect to $N-phosphorycreatine^{2-}$ ; Creatine competitive with respect to $N-phosphorycreatine^{2-}$ and noncompetitive with respect to Ma $ADP^-)$ indicated that the reaction obeyed a sequential mechanism of the rapid equilibrium random type.

• Advances in environmental research
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• v.1 no.3
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• pp.223-236
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• 2012

Biosorption of methylene blue (MB) from aqueous solution was studied with respect to the point of zero charge of coconut husk, dye concentration, particle size, pH, temperature, as well as adsorbent and NaCl concentration using coconut husk biomass. Amongst Langmuir and Freundlich adsorption isotherms studied, Langmuir adsorption isotherm showed better agreement. Pseudo second order kinetics model was found to be more suitable for data presentation as compared to pseudo first order kinetics model. Also, involvement of diffusion process was studied using intraparticle diffusion, external mass transfer and Boyd kinetic model. Involvement of intraparticle diffusion model was found to be more relevant (prominent) as compared to external mass transfer (in) for methylene blue biosorption by the coconut husk. Moreover, thermodynamic properties of MB biosorption by coconut husk were studied. Desorption of methylene blue from biomass was studied with different desorbing agents, and the highest desorption achieved was as low as 7.18% with acetone, which indicate stable immobilization. Under the experimental conditions MB sorption was not significantly affected by pH, temperature and adsorbent concentration but low sorption was observed at higher NaCl concentrations.