• KSBB Journal
• /
• v.5 no.2
• /
• pp.133-139
• /
• 1990

A simple and convenient method was introduced to determine the kinetic parameters for various enzymatic reaction kinetics. The method based on integrated formular can be applied to the parameter estimations from a single experiment. A modified three-parameter model was applied for the parameter estimation in reversible reaction and the equilibrium substrate concentration could be also estimated. It is possible to identify the enzymatic reaction pattern by inspecting the parameter values and the square of the correlation coefficient.

• Journal of the Korean Chemical Society
• /
• v.12 no.2
• /
• pp.61-64
• /
• 1968

Compressibility and expansibility of activation, ${\Delta}K^{\neq}\;and\;{\Delta}E^{\neq},$ are defined with the use of general principles that an activation parameter is the difference in partial molar quantities of the parameter for the transition and initial state. Two related parameters, (${\partial}{\Delta}H^{\neq}/{\partial}P)_{\gamma}\;and\;{\Delta}W^{\neq}(=P{\Delta}V^{\neq}),$ are also derived. Simpler interpretation of the existing kinetic data are possible with these activation parameters, while other derivations lead to complicated expressions of no practical significance.

• Journal of Korean Society of Water and Wastewater
• /
• v.20 no.3
• /
• pp.329-338
• /
• 2006

The research aims to provide the basic data for practical applications by correlating the bio-kinetic coefficients with the load of recalcitrant organic matter in box-mill wastewater. The activated sludge process was employed to a Wastewater disposal plant in an industrial setting, increase of consequently leading to the organic load. The parameter values derived by Monod-kinetic analysis were as follows:specific substrate removal rate $K_{max}=0.17day^{-1}$, half saturation constants $K_s=60.37mg/l$, decay coefficient $K_d=0.142day^{-1}$, microbial yield coefficient y = 0.388mg/mg, and max specific growth rate ${\mu}_{max}=0.006day^{-1}$. In view of biodegradability, the $TCOD_{Mn}/TBOD_5$ ratios of inflow and outflow were 1.07 and 1.41, and the $SCOD_{Mn}/SBOD_5$ ratios of inflow and outflow were 1.10 and 1.50, respectively. The higher $TCOD_{Mn}/TBOD_5$ ratio of outflow indicated that metabolites of a microorganism have accumulated in the cells.

• Journal of Environmental Science International
• /
• v.7 no.6
• /
• pp.773-782
• /
• 1998

The adsorption experiment of phenol(Ph) from aqueous solution on granular activated carbon was studied in order to design the fixed-bed adsorption column. The experimental data were analyzed by unsteady-state, one-dimensional heterogeneous model. Finite element method(FEM) was applied to analyze the sensitivity of parameter and to predict the fixed-bed adsorption column performance on operation variable changes. The prediction model showed similar effect to mass transfer and intraparticle diffusion coefficient changes suggesting that both parameter present mass transfer rate limits for GAC-phenol system. The Freundlich constants had a greater effect than kinetic parameters for the performance of fixed-bed adsorption column. FEM solution facilitated prediction of concentration history in solution and within adsorbent particle.

• Bulletin of the Korean Chemical Society
• /
• v.29 no.11
• /
• pp.2145-2151
• /
• 2008

• Applied Chemistry for Engineering
• /
• v.23 no.2
• /
• pp.204-209
• /
• 2012

In this study, kinetics data was obtained for steam reforming reaction of ethane over the commercial ruthenium catalyst. The variables of ethane steam reforming were the reaction temperature, partial pressure of ethane, and steam/ethane mole ratio. Parameters for the power rate law kinetic model and the Langmuir-Hinshelwood model were obtained from the kinetic data. Also, sizing of steam reforming reactor was performed by using PRO/II simulator. The reactor size calculated by the power rate law kinetic model was bigger than that of using the Langmuir-Hinshelwood model for the same conversion of ethane. Reactor size calculated by the Langmuir-Hinshelwood model seems to be more suitable for the reactor design because the Langmuir-Hinshelwood model was more consistent with the experimental results.

• Journal of Korean Society of Water and Wastewater
• /
• v.27 no.4
• /
• pp.457-468
• /
• 2013

Based on the activated sludge model(ASM), a mathematical model which represents the aerobic sludge digestion by sequencing batch reactor(SBR) combined with ultrasonic treatment was composed and performed in this study. Aerobic digestion using sequencing batch reactor(SBR) equipped with ultrasound treatment was also experimented for the purpose of parameter calibration. Most of the presented kinetic parameters in ASM or ASM2 could be used for the aerobic digestion of sludge but the parameters related in hydrolysis and decay rate needed modification. Hydrolysis rate constant of organic matter in aerobic condition was estimated at $0.3day^{-1}$ and the maximum growth rate for autotrophs in aerobic condition was $0.618day^{-1}$. Solubilization reactions of particulate organics and nitrogen by ultrasonication was added in this kinetic model. The solubilization rate is considered to be proportional to the specific energy which is defined by specific ultrasound power and sonication time. The solubilization rate constant by ultrasonication was estimated at $0.202(W/L)^{-1}day^{-1}$ in this study. Autotrophs as well as heterotrophs also decomposed by ultrasonic treatment and the nitrification reaction was limited by the lack of autotrophs accumulation in the digester.

• KSBB Journal
• /
• v.13 no.1
• /
• pp.52-57
• /
• 1998

The present work proposes a simple electrochemical method applicable to any immobilization processes of oxidase using a Clark type oxygen electrode as a base transducer. The present work suggests an optimal immobilization technique among three different methods of glucose oxidase(GOD) onto one side of $37[\mu}$mthick blend membranes, composed o 80% of cellulose triacetate and 20% of polycaprolactone, on the basis of the maximum Michaelis-Menten parameter(Vm) determined by either steady state or transient analyses. The electrode system was made of disk type gold cathode(4mm diameter) and Ag/AgCl anode. One side of the blend membrane was in contact with the cathode surface while the other side was immobilized with GOD either in covalent-bond or cross-linked forms, the latter being covered by $25{\mu}$m thick dialysis membrane of cellulose acetate. The resultant current density was on-line monitored by a potentiostat while glucose level was varied from 1 to 20 mM. The present study shows that direct cross-linking of GOD with glutaraldehyde was mostly preferred for fabrication of glucose sensor, on the basis of resultant kinetic parameters from either steady state or transient analyses.

• Science of Emotion and Sensibility
• /
• v.6 no.4
• /
• pp.25-32
• /
• 2003

This paper suggests the evaluation method of gait analysis in measurements obtained using the "Foot Scanner" and "Foot Analyzer" system. Previous examination method with the unaided eye on the sole of the foot and analysis method of pressure distribution in gait have been discussed by many researchers. Also they have concerned with pressure curve, COP(center of pressure) trace, and velocity in COP. However experiment results depend on test environment and conditions of subjects. Consequently we need to regard the special energy parameter for solving the problem. The kinetic energy and impulse parameter can be used as parameters of gait analysis. The results of this study confirmed the validity of presented of the parameters through the experiment with eight subjects.

• Nuclear Engineering and Technology
• /
• v.50 no.7
• /
• pp.1017-1023
• /
• 2018

The measurement and calculation of neutronic parameters in nuclear research reactors has an important influence on control and safety of the nuclear reactor. The power peaking factors, reactivity coefficients and kinetic parameters are the most important neutronic parameter for determining the state of the reactor. The position of the control shim safety rods in the core configuration affects these parameters. The main purpose of this work is to use the MTR_PC package to evaluate the effect of the partially insertion of the control rod on the neutronic parameters at the operating core of the Tehran Research Reactor. The simulation results show that by increasing the insertion of control rods (bank) in the core, the absolute values of power peaking factor, reactivity coefficients and effective delayed neutron fraction increased and only prompt neutron life time decreased. In addition, the results show that the changes of moderator temperature coefficients value versus the control rods positions are very significant. The average value of moderator temperature coefficients increase about 98% in the range of 0-70% insertion of control rods.