• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.219-222
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• 2004

Removal characteristics of Mn and Co was studied from the contaminated solutions via surface reaction with various calcium carbonate (calcite). Synthetic calcium carbonates which has different surface morphology as well as surface areas were prepared by a spontaneous precipitation method and used. Mn and Co removal behavior by the different solid surface demonstrate characteristic sorption behaviors depend on the type of calcite used, such as surface area or surface morphology. Calcium carbonate crystals (mostly calcite) which exhibit complicated surface morphology (c-type) shows strong sorption affinity for Mn and Co removal via sorption than on the a-type or b-type calcite crystals of less complicated surfaces. The applicability of two kinetic models, the pseudo-first-order kinetic equation and the Elovich kinetic model was examined on these sorption behavior. Elovich kinetic model was found more suitable to explain the very early stage adsorption kinetics, while the pseudo-first-order kinetic equation was successfully fitted for the adsorption kinetics after 50 hours.

• Journal of Life Science
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• v.14 no.1
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• pp.131-140
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• 2004

T7 bacteriophage gp4 is the replicative DNA helicase that unwinds double-stranded DNA by utilizing dTTP hydrolysis energy. The quaternary structure of the active form of T7 helicase is a hexameric ring with a central channel. Single-stranded DNA passes through the central channel of the hexameric ring as the helicase translocates $5'\rightarrow3'$ along the single-stranded DNA. The DNA unwinding was measured by rapid kinetic methods and showed a lag before the single-stranded DNA started to accumulate exponentially. This behavior was analyzed by a kinetic stepping model for the unwinding process. The observed lag phase increased as predicted by the model with increasing double-stranded DNA length. Trap DNA added in the reaction had no effect on the amplitudes of double-stranded DNA unwound, indicating that the $\tau7$ helicase is a highly processive helicase. Global fitting of the kinetic data to the stepping model provided a kinetic step size of 10-11 bp/step with a rate of $3.7 s^{-1}$ per step. Both the mechanism of DNA unwinding and dTTP hydrolysis and the coupling between the two are unaffected by temperature from $4∼37^{\circ}C$. Thus, the kinetic stepping for dsDNA unwinding is an inherent property of tile replicative DNA helicase.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.3
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• pp.337-343
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• 2011

A particular empirical equation for rainfall kinetic energy is needed to compute rainfall erosivity, calculated by the annual sum of the product of total rainfall energy and maximum 30-min rainfall intensity. If rainfall kinetic energy equation was different, rainfall erosivity will be produced differently. However, the previous studies in Korea had little concern about rainfall kinetic energy equation and it was not clear which rainfall kinetic energy is suitable for Korea. The purpose of this study is to analyze and evaluate the difference of the rainfall erosivity based on different rainfall kinetic energy equations obtained from previous studies. This study introduced new rainfall erosivity factors based on rainfall kinetic energy equation of Noe and Kwon (1984) that is only regression model developed in Korea. Data of annual rainfall erosivity for 21 weather stations in 1980~1999 were used in this study. The result showed that rainfall erosivity factors by the previous equations had been about 10~20% overestimated than rainfall erosivity by Noe and Kwon (1984)'s equation in Korea.

• Advances in nano research
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• v.9 no.3
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• pp.173-181
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• 2020

Adsorption and heterogeneous electro-Fenton process using iron-loaded ZSM-5 nano-zeolite were investigated for the removal of Tetracycline (TC) from wastewater. The nano-zeolite was synthesized hydrothermally and modified through impregnation. The zeolite was characterized by XRD, FT-IR, FE-SEM, N₂ adsorption-desorption, and NH₃-TPD techniques. The equilibrium data were best represented by the Freundlich isotherm. The pseudo-second-order kinetic model was the most accurate model for the adsorption of TC on the modified nano-zeolite. The effect of parameters such as pH of solution and current density were investigated for the heterogeneous electro-Fenton process. The results showed that the current density of 150 mA and pH of 3 led to the highest TC removal (90.35%) at 50 min. The nano-zeolite showed the appropriate reusability. Furthermore, the developed kinetic model was in good agreement with the removal data of TC through the electro-Fenton process.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.380-380
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• 2006

Styrene-Butadiene diblock or styrene-butadiene-styrene triblock copolymers are industrially important materials for asphalt modification and adhesives. A kinetic modeling study on non-isothermal anionic styrene-butadiene diblock copolymerization system is presented. The model deals with the association/dissociation reaction of initiator and propagating ion pairs in its kinetic scheme. By comparing model calculation results with real plant data, it is possible to obtain useful ideas for more efficient plant operation. For example, the model clearly provides important relation between the reaction temperature profile and the conversion of monomers.

• International Journal of High-Rise Buildings
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• v.1 no.2
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• pp.73-80
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• 2012

In order to use sea breezes to counter the heat island phenomena, i.e. to promote urban ventilation, it is necessary to clarify the effect of building morphology and height on large-scale wind fields. In this study, the sea breeze in the vicinity of the Kanto Plain in Japan is simulated using a mesoscale meteorological model incorporating an urban canopy model, and the inland penetration of sea breezes is accurately reproduced. Additionally, a mean kinetic energy balance within a domain (Control Volume; CV) moving along the sea breeze is analysed. From the results, it is clarified that the sea breeze is interrupted by the resistance and turbulence caused by buildings at the centre of Tokyo. The interruption effect is increased in accordance with the height of these buildings. On the other hand, adverse pressure gradients interrupt in the internal region.

• Environmental Engineering Research
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• v.25 no.2
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• pp.243-250
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• 2020

A down-flow hanging sponge (DHS) bioreactor was operated for the treatment of domestic wastewater. The Stover-Kincannon model was applied for kinetic evaluation of the reactor performance during the operational period. As a result, the coefficient of determination (R²) for straight lines of effluent concentration from the experimental data and from the predictive data of BOD₅; NH₄⁺-N; and TN were 0.9727; 0.9883; and 0.9934, respectively. The calculation of saturation value constant (Umax - g L^-1 d^-1) and maximum utilization rate constant (KB - g L-1 d-1) were 56.818 and 75.034 for BOD₅; 2.960 and 4.713 for NH₄⁺-N; 2.810 and 8.37 for TN, respectively. The study suggests that Stover-Kincannon model can be used for effective evaluation of kinetic removal of BOD₅; NH₄⁺-N; and TN from domestic wastewater treated in a DHS bioreactor.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.11a
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• pp.97-102
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• 1996

A methodology for estimating the number of failed fuel rods bused on the primary coolant activity in operating PWRs has been developed. This method deals with both the diffusion and the kinetic models. In case of small or medium cladding failures, the diffusion model which can consider different sizes of failure is used, whereas for large cladding failures the kinetic model is used. From the kinetic model, the release-to-birth rate ratio (R/B) is represented as a linear function of the number of failed fuel rods. This has been done by expressing the escape rate coefficient in terms of the slope of log(R/B) versus $log\;{\lambda}$. The present method has been applied to the cases of 26 cycles of several nuclear power plants for which ultrasonic testings were performed. The results show that the present method gives better predictions than the existing computer codes such as IODYNE and CADE.

• Physical Therapy Korea
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• v.27 no.2
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• pp.140-148
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• 2020

Background: Scapular winging (SW) could be caused by tightness or weakness of the periscapular muscles. Although data mining techniques are useful in classifying or predicting risk of musculoskeletal disorder, predictive models for risk of musculoskeletal disorder using the results of clinical test or quantitative data are scarce. Objects: This study aimed to (1) investigate the difference between young women with and without SW, (2) establish a predictive model for presence of SW, and (3) determine the cutoff value of each variable for predicting the risk of SW using the decision tree method. Methods: Fifty young female subjects participated in this study. To classify the presence of SW as the outcome variable, scapular protractor strength, elbow flexor strength, shoulder internal rotation, and whether the scapula is in the dominant or nondominant side were determined. Results: The classification tree selected scapular protractor strength, shoulder internal rotation range of motion, and whether the scapula is in the dominant or nondominant side as predictor variables. The classification tree model correctly classified 78.79% (p = 0.02) of the training data set. The accuracy obtained by the classification tree on the test data set was 82.35% (p = 0.04). Conclusion: The classification tree showed acceptable accuracy (82.35%) and high specificity (95.65%) but low sensitivity (54.55%). Based on the predictive model in this study, we suggested that 20% of body weight in scapular protractor strength is a meaningful cutoff value for presence of SW.

• Journal of Environmental Science International
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• v.26 no.3
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• pp.363-371
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• 2017

This study evaluates the adsorption properties of Sr ions in an aqueous solution of the synthetic zeolite (Z-Y1) prepared using coal fly ash generated from a thermal power plant. In order to investigate the adsorption characteristics, the effects of various parameters such as the initial concentrations of Sr ion, contact time, and solution pH were investigated in a batch mode. The Langmuir and Redlich-Peterson model fitted the adsorption isotherm data better than the Freundlich model. The maximum adsorption capacity of Sr ions, as determined the Langmuir model, was 181.68 mg/g. It was found that by varying the Sr ion concentration, pH, and temperature, the pseudo-second-order kinetic model describes the adsorption kinetics of the Sr ion better than the pseudo-first-order kinetic model. The calculated thermodynamic parameters of ${\Delta}H^0$ and ${\Delta}G^0$ showed that the adsorption of Sr ions on Z-Y1 was occurred through a spontaneous and an endothermic reaction. We found that the adsorption of Sr ions by Z-Y1 was more affected by pH than by temperature and Sr ion concentration.