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Synthesis and Photocatalytic Properties of Thermally Stable Metal-Oxide Hybrid Nanocatalyst with Ultrathin Oxide Encapsulation

  • Naik, Brundabana;Moon, Song Yi;Kim, Sun Mi;Jung, Chan Ho;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.317.2-317.2
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    • 2013
  • Ultrathin oxide encapsulated metal-oxide hybrid nanocatalysts have been fabricated by a soft chemical and facile route. First, SiO2 nanoparticles of 25~30 nm size have been synthesized by modified Stobber's method followed by amine functionalization. Metal nanoparticles (Ru, Rh, Pt) capped with polymer/citrate have been deposited on functionalized SiO2 and finally an ultrathin layer of TiO2 coated on surface which prevents sintering and provides high thermal stability while maximizing the metal-oxide interface for higher catalytic activity. TEM studies confirmed that 2.5 nm sized metal nanoparticles are well dispersed and distributed throughout the surface of 25 nm SiO2 nanoparticles with a 3-4 nm TiO2 ultrathin layer. The metal nanoparticles are still well exposed to outer surface, being enabled for surface characterization and catalytic activity. Even after calcination at $600^{\circ}C$, the structure and morphology of hybrid nanocatalysts remain intact confirm the high thermal stability. XPS spectra of hybrid nanocatalyst suggest the metallic states as well as their corresponding oxide states. The catalytic activity has been evaluated for high temperature CO oxidation reaction as well as photocatalytic H2 generation under solar simulation. The design of hybrid structure, high thermal stability, and better exposure of metal active sites are the key parameters for the high catalytic activity. The maximization of metal-TiO2 interface interaction has the great role in photocatalytic H2 production.

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Development and properties of jointed Bi-2223 superconductor tape

  • Kim, Jung-Ho;Ji, Bong-Ki;Park, Hyung-Sang;Kim, Ho-Jin;Oh, Seung-Jin;Kim, Joong-Seok;Joo, Jin-Ho;Nah, Won-Soo
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.298-303
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    • 2000
  • We evaluated the electric properties of Bi-2223 jointed tapes processed by both resistive- and supercondcuting-joint methods. For the resistive-joint, filler materials of wood metal, Pb/Sn, In, and silver paste were used, whereas, for the superconductive-joint, the lap joint method were used. In the resistive-joint tape, it was observed that the electrical properties such as current transport property, n-value, and contact resistance of the tape were significantly related to the resistivity of filler materials. On the other hand, in the superconducting-joint tape, the current transport property was dependent on the uniaxial pressure. Specifically, the current transport property varied 50 to 80% with uniaxial pressure, probably due to the irregular microstructure in the transition region.

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The Literatural Study on Prescription about Low Back Pain (요통 치방에 대한 문헌적 고찰)

  • Lee, Sung-Hwan;Kim, Young-Il;Yang, Gi-Young;Kim, Jeong-Ho;Heo, Yoon-Kyoung;Lee, Hyun
    • Journal of Haehwa Medicine
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    • v.16 no.1
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    • pp.41-59
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    • 2007
  • From the study of prescription on low back pain, the following conclusions are obtained. 1. Among classified cause of low back pain, ShinHur(腎虛) lowback pain and its prescription was most mentioned. 2. Prescriptions such as ChungAWhan(靑娥丸), KookBangAnShinWhan(局方安腎丸) BoSooDan(補髓丹) BaekBaeWhan(百倍丸) DooChungWhan(杜沖丸) JangBonDan(壯本丹) NokKakWhan(鹿角丸) were used in ShinHur(腎虛) type low back pain. 3. Prescription such as TaekRanTang(澤蘭湯) JiRyongSan(地龍散) YoeShinSan(如神散) ShinKookJoo(神麴酒) SoeGuenSan(舒筋散) were used in JwaSumJilBak(閃挫跌撲) type low back pain. 4. Prescription such as ChangChulTang(蒼朮湯) JumTongTang(拈痛湯) ChulBuTang(朮附湯) YiChoChangBaekSan(二炒蒼栢散) were used in SeupYoel(濕熱) type low back pain. 5. Prescription such as ChunGoongYookGaeTang(川芎肉桂湯) GaMiSaMulTang(加味四物湯) PaHoelSanDongTang(破血散疼湯) JiRyongSan(地龍散) were used in UhHoel(瘀血) type low back pain. 6. Prescription such as (蒼術復煎散) (五積散) (摩腰丹) (滲濕湯) were used in HanSeup(寒濕) type low back pain. 7. Prescription such as GaMiYiJinTang(加味二陳湯) GongYeonDan(控涎丹) SaMoolTangHapYiJinTangGaMi(四物湯合二陳湯加味) were used in DamUem(痰飮) type low back pain. 8. Prescription such as OhJukSanGaMi(五積散加味) OhYakSoonGiSanGaMi(烏藥順氣散加味) GaMiYongHoSan(加味龍虎散) SoSokMyoungTang(小續命湯) were used in Poong(風) type low back pain. 9. Prescription such as (四物湯合二陳湯) (仰腰湯) were used in SikJuk(食積) type low back pain and (五積散) (煨腎散) (三花神祐丸) in Seup(濕) type low back pain. 10. Prescription such as ChilKiTang(七氣湯) ChimHyangGangKiTang(沈香降氣湯) ChoKiSan(調氣散) InSamSoonKiSan(人參順氣散) were used in Ki(氣) type low back pain.

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Exploring the Association between MBTI Personality Types and Physical Appearance: A Study using StyleCLIP Image Transformation and Transfer Learning (MBTI 성격유형과 외모의 연관성 탐색 : StyleCLIP 기반 이미지 변환 및 전이학습 활용 연구)

  • Mi-Young Jung;Yeon-ho Ryu;Lee Ho-Jung;Min-Ki Hong;Mi-Hwa Song
    • Annual Conference of KIPS
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    • 2023.11a
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    • pp.293-294
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    • 2023
  • 이 연구는 사람의 외적인 요소와 마이어스-브릭스가 제안한 16 가지 성격유형을 결부한 연구이다. 기존의 성격유형에 대한 기준을 기반으로 하여, 일반적인 MBTI 판독기와는 다르게 StyleCLIP 을 활용해서 추상적인 단어로 이미지를 변환하고 전이학습 AI 를 이용하여 비교 테스트를 진행한다. 최종적으로 이 연구를 통해 외모와 성격은 연관이 있다는 가설을 증명한다.

Detection of Peripheral Blood Telomerase Activity from Gastric Cancer Patients (위암 환자의 혈액에서 Telomerase 활성도 검출의 의의)

  • Park Ki Ho;Jung Soon Jai;Yu Young Woon;Park Sung Hwan;Lee Han Il;Joo Dae Hyun;Park Ki Hyuk;Choi Dong Rak;Jeon Chang Ho
    • Journal of Gastric Cancer
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    • v.3 no.4
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    • pp.201-205
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    • 2003
  • Purpose: Telomerase activity is generally absent in primary cell cultures and normal tissues. Telomerase is known to be induced upon immortalization or malignant transformation of human cells. Telomerase activity can be increased in immature lymphocytes and activated lymphocytes, but it is not detected in the peripheral blood of normal persons. The authors analyzed peripheral blood telomerase from patients of gastric cancer to evaluate the possibility of using it for diagnosis and as a prognostic factor. Materials and Methods: We obtained blood samples from 11 inflammatory patients and 64 gastric cancer patients. The telomerase activity was measured using the [PCR-ELISA] method. The results were correlated with the T, N, M stage, cell differentiation, vascular, neural, and lymphatic invasion, tumor size, and tumor location. Results: In the 11 inflammatory patients, telomerase activity was not detected while in the gastric cancer patients, a positive rate of $28.1\%$ was noted. The peripheral telomerase activity was not related with tumor size, tumor site, lymphatic and vascular invasion, stage, or histologic differentiation. Conclusion: The peripheral blood telomerase activity for patients of gastric cancer can be utilized as a marker for the diagnosis of not only advanced gastric cancer, but also relatively early stage gastric cancer, but not as a prognostic factor.

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Predictive Current Control of 12-Pulse Parallel Connected Dual Converter System without Interphase Reactors (상간 리액터를 제거한 12상 병렬 연결 듀얼 컨버터 시스템의 예측전류제어)

  • Park, Ki-Tae;Ji, Jun-Keun;Sul, Seung-Ki;Choi, Chang-Ho;Shin, Hyun-Seok;Lee, Chang-Won;Chang, Kye-Yong
    • Proceedings of the KIEE Conference
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    • 1996.07a
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    • pp.482-485
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    • 1996
  • In this paper, a predictive current control of 12-pulse parallel connected dual converter system without interphase reactors(IPR) is presented. Firstly, the characteristics of system without IPR are analyzed and compared with that of system with IPR. And the predictive current control of this system is discussed. Finally the validity of the presented system and the excellence of the predictive current control response is proved through the simulation results.

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Address discharge delay reduction in AC PDP by applying MgO nanoparticle under protective layer

  • Seo, Ki-Ho;Shin, Seung-Ha;Choi, Man-Soo;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.355-358
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    • 2008
  • We report a method for improving characteristics of AC PDP in this study. This improvement is obtained by spreading MgO nanoparticles on transparent dielectric layer. These nanoparticles are covered with MgO protective layer by electron beam evaporation. MgO nanoparticle has difference in cathodoluminescence stronger than MgO layer by electron beam evaporation. This method worked for reducing statistical delay especially. Efficacy, discharge voltage and luminance were also improved But these improvements has limited lifetime because continuous ion bombardments changed characteristic of MgO surface.

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Catalytic Upgrading of Geodae-Uksae 1 over Mesoporous MCM-48 Catalysts

  • Jeon, Ki-Joon;Jin, Sung Ho;Park, Sung Hoon;Jeon, Jong-Ki;Jung, Sang-Chul;Ryu, Changkook;Park, Young-Kwon
    • Bulletin of the Korean Chemical Society
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    • v.35 no.7
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    • pp.1951-1955
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    • 2014
  • Catalytic pyrolysis of Geodae-Uksae 1, a kind of miscanthus found in Korea, was carried out over mesoporous MCM-48 catalysts. For rapid product analysis and catalyst evaluation, pyrolysis-gas chromatography/mass spectrometry was used. X-ray diffraction, nitrogen sorption, pyridine adsorbed Fourier transform infrared, and NH3 temperature programmed desorption were utilized to analyze the properties of the catalysts. Compared to non-catalytic reaction, catalytic upgrading over mesoporous Al-MCM-48 catalysts produced a higher-quality bio-oil with a high stability and low oxygen content. Al-MCM-48 exhibited higher deoxygenation ability than Si-MCM-48 due to its higher acidity.