• Proceedings of the KIEE Conference
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• 2008.05a
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• pp.187-188
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• 2008

In this paper, we have investigated water content of semiconductive shield materials for power cables, EEA(Ethylene Ethyl Acrylate) is used polymer matrix. And filler is used CNT(Carbon Nanotube) and CB(Carbon Black). EEA, CNT and CB is favor moisture. In case of EEA, it has polyolefin resin that strong polarity combination. To research water content, experimental method used KF(Karl Fischer). KF method is Electrochemical titration based on chemical reaction. As a result, specification by KEPCO(Korea Electric Power Corporation) is lower than 800ppm. CNT and CB ratio of 80 versus 20 is best specimen that had lowest moisture content. It seem likely to increase crosslinking rate, CNT between CB.

• Journal of the Korean Society of Tobacco Science
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• v.19 no.2
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• pp.159-161
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• 1997

A study on the optimal drying condition by a vacuum drying oven was done using shredded tobacco lamina and commercial cigarettes ('This'). Changes in the mass of the experimental material were monitored for about 50 hrs at 6 different temperatures (5$0^{\circ}C$~10$0^{\circ}C$, 1$0^{\circ}C$ stepwise) while continuously operating a vacuum pump. After 30 hrs, small amount of samples from each material were taken sequentially to monitor changes in moisture content using a Karl-Fischer method (Metrohm KF 701 Titrino). Absolute moisture contents calculated from the measurements indicated an ideal data distribution could be obtained by drying at temperatures between 7$0^{\circ}C$~8$0^{\circ}C$. Results from cigarette products which contains humectant and tobacco lamina without it were compared.

• Proceedings of the KIEE Conference
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• 2005.07e
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• pp.76-78
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• 2005

Moisture contents measurement is frequently used as one of parameters for degradation diagnosis of transformer insulation. In general Karl-Fisher method is mainly used for moisture contents till now. But this method is inconvenient because of dismounting transformer for sampling oil or paper, and also partial sampling. At latest Recovery Voltage Method(RVM) is noticed for complement of this method. RVM can directly estimate moisture contents of transformer insulations in field without dismounting transformer. In this paper the accelerated aging process of oil-paper samples have been investigated at a temperature up to 140$^{\circ}C$ for 500 hours. The oil-paper insulation samples have been measured at intervals of 100 hours. Next to, we have estimated moisture contents using both Karl-Fisher Titration Method and RVM. And we have compared with Karl-Fisher Titration Method and RVM for estimating moisture contents. At last we have verified reliability of RVM which is new measurement method.

• Proceedings of the KIEE Conference
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• 2006.07e
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• pp.45-46
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• 2006

변압기 내부의 수분은 절연물의 절연내력에 악영향을 끼치므로 수분측정은 변압기 사고예방과 수명연장에 매우 중요하다. 변압기 내의 수분함유량을 검출하는 시험법으로 Karl-Fischer법과 Dew-Point법을 사용해 왔다. 그러나 이 시험법은 기기를 분해해야 하고, 국부적인 부분에 대한 정보일 뿐 아니라 분석을 즉시 현장에서 하지 못하는 단점이 있다. 따라서 기존 시험법의 단점을 보완하기 위해 회복전압법(RVM, Return Voltage Method)이 제안되었다. 본 논문에서는 모의 셀 내부에 수분을 강제로 주입하여 수분함유량 변화를 주고 Karl-Fischer법을 통한 수분함유량 측정 결과와 RVM 특성 곡선을 비교 분석하였다.

• Asian-Australasian Journal of Animal Sciences
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• v.27 no.11
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• pp.1615-1622
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• 2014

An accurate assessment of moisture content in feed ingredients is important because moisture influences the nutritional evaluation of feedstuffs. The objective of this study was to evaluate various methods for moisture content determination. In Exp. 1, the weight loss on drying (LOD) of corn, soybean meal (SBM), distillers dried grains with solubles (DDGS), whey permeate, whey powder, spray-dried porcine plasma (SDPP), fish meal, and a mixed diet of these 7 ingredients were measured by oven drying at $135^{\circ}C$ for 2 h. Additionally, the samples were dried at $105^{\circ}C$ for 3, 6, 9, 12, or 15 h. The LOD contents of the DDGS, whey permeate, and whey powder measured by drying at $135^{\circ}C$ for 2 h were greater than the values measured by drying at $105^{\circ}C$ for 3 h (p<0.05). All samples except SDPP (p = 0.70) dried at $105^{\circ}C$ for 6, 9, 12, or 15 h caused more LOD compared with the samples dried for at $105^{\circ}C$ for 3 h (p<0.05). The LOD contents of the individual ingredients were additive when dried at $105^{\circ}C$ regardless of drying time. In Exp. 2, moisture contents of corn, SBM, wheat, whey permeate, whey powder, lactose, and 2 sources of DDGS (DDGS1 and DDGS2) were measured by the Karl Fischer method, oven drying at $135^{\circ}C$ for 2 h, and oven drying at $125^{\circ}C$, $115^{\circ}C$, $105^{\circ}C$, or $95^{\circ}C$ for increasing drying time from 1 to 24 h. Drying samples at $135^{\circ}C$ for 2 h resulted in higher moisture content in whey permeate (7.5% vs 3.0%), whey powder (7.7% vs 3.8%), DDGS1 (11.4% vs 7.5%), and DDGS2 (13.1% vs 8.8%) compared with the Karl Fischer method (p<0.05). Whey permeate and whey powder were considerably darkened as the drying time increased. In conclusion, drying samples at $135^{\circ}C$ for 2 h is not appropriate for determining the moisture content in whey permeate, whey powder, or DDGS as well as the mixed diet containing these ingredients. The oven-drying method at $105^{\circ}C$ for 5 to 6 h appears to be appropriate for whey permeate and whey powder, and at $105^{\circ}C$ for 2 to 3 h for DDGS.

• Proceedings of the KIEE Conference
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• 2005.07e
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• pp.73-75
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• 2005

In present measurement of moisture contents is used as one of method for estimating degradation of transformer. Most of people use Karl-Fischer titration method for detection moisture contents but this measurement is inconvenient method because we must analyze transformer oil-paper after dismounting transformer and sampling in field. Therefore we don't directly investigate them in field. In this paper we will introduce Recovery Voltage Method(RVM) that is new method for estimating measurement in field though dismounting facility. For measure of moisture contents using RVM in accordance with accelerated thermal aging we have made experimental test cell and aged at a temperature up to 140$^{\circ}C$ for 300 hours. And we have been measured at intervals of 100 hours using RVM 5462 made in fetter company.

• Bulletin of the Korean Chemical Society
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• v.35 no.11
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• pp.3275-3279
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• 2014

A mass balance method for purity assessment of thermolabile organic reference materials was established by combining several techniques, including liquid chromatography with UV/VIS detector (LC-UV), Karl-Fischer (K-F) Coulometry, and thermal gravimetric analysis (TGA). This method was applied to three fluoroquinolones like enrofloxacin, norfloxacin and ciprofloxacin. LC-UV was used to analyze structurally related organic impurities based on UV/VIS absorbance spectra obtained in combination with LC separation. For all three organic reference materials, the UV/VIS spectra of the separated impurities were similar to that of the major component of the corresponding materials. This indicates that the impurities are structurally related to the respective reference material sharing common chromophores. Impurities could be quantified by comparing their absorbances at the wavelength of maximum absorbance (${\lambda}_{max}$). The water contents of the reference materials were measured by K-F Coulometry by an oven-drying method. The total inorganic impurities contents were assayed from ash residues in TGA analysis with using air as a reagent gas. The final purities estimated from results of those analytical techniques were assigned as ($99.91{\pm}0.06$), ($97.09{\pm}0.17$) and ($91.85{\pm}0.17$)% (kg/kg) for enrofloxacin, norfloxacin and ciprofloxacin, respectively. The assigned final purities would be applied to the reference materials which will be used as calibrators for the certification of those compounds in matrix CRMs as starting points for the traceability of their certified values to SI units.

• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.531-538
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• 2013

A mass balance method established in this laboratory was applied to determine the purity of an endosulfan-II pure substance. Gas chromatography-flame ionization detector (GC-FID) was used to measure organic impurities. Total of 10 structurally related organic impurities were detected by GC-FID in the material. Water content was determined to be 0.187% by Karl-Fischer (K-F) coulometry with an oven-drying method. Non-volatile residual impurities was not detected by Thermal gravimetric analysis (TGA) within the detection limit of 0.04% (0.7 ${\mu}g$ in absolute amount). Residual solvents within the substance were determined to be 0.007% in the Endosulfan-II pure substance by running GC-FID after dissolving it with two solvents. The purity of the endosulfan-II was finally assigned to be ($99.17{\pm}0.14$)%. Details of the mass balance method including interpretation and evaluating uncertainties of results from each individual methods and the finally assayed purity were also described.

• Journal of the Korean Chemical Society
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• v.31 no.3
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• pp.258-270
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• 1987

A series of new thorium nitrate complexes with crown ethers have been synthesized from the reaction of the hydrated thorium nitrate, with the appropriate crown ethers of different cavity sizes in various solvents such as methanol, ethanol, butanol, methylacetate, acetone, tetrahydrofuran and acetylacetone. CHN elemental analysis, ICPAS, thermal analysis and Karl-Fischer method have been used to characterize their compositions, and the spectroscopic methods of IR, UV, $^1H-NMR$, and X-ray diffraction have been employed to determine the structures and solvolysis phenomena of these complexes. and the electrical conductances were measured in DMSO, and water solvent. The solvolysis have been observed only in the complexes synthesized in acetylacetone solvent. In the solvated complexes of 15-crown-5 and 18-crown-6, the mole ratio of $Th^{4+}$: ligand : acetylacetone is found to be 1:1:1, but in the non-solvated complexes of 12-crown-4 and 15-crown-5, the mole ratios of Th:L are 1:2 and 2:3, respectively, and that in the complexes of both 18-crown-6 and dicyclohexano-18-crown-6 is 1:1. All complexes which were not solvated have shown $n{\to}{\sigma}^{\ast}$ electronic transitions of crown ether whereas complexes solvated have exhibited both $n{\to}{\sigma}^{\ast}$ of crown ether and $n{\to}{\pi}^{\ast}$ transitions of acac. The dissociation mole ratio of $Th^{4+}$ and nitrate ion is found to be 1:1 in aprotic solvent, and 1:4 in protic solvent like water.