• 한국수소및신에너지학회논문집
• /
• 제32권4호
• /
• pp.245-255
• /
• 2021

Various studies about metallic bipolar plates have been conducted to improve fuel cell performance through flow field design optimization. These research works have been mainly focused on fuel cells for vehicle, but not fuel cells for building. In order to reduce the price and volume of fuel cell stacks for building, it is necessary to apply a metallic flow field, In this study, for a metallic flow field applied to a fuel cell for building, the effect of a change in the flow field shape on the performance of a polymer electrolyte membrane fuel cell was confirmed using a model and experiments with a down-sizing single cell. As a result, the flow field using a metal foam outperforms the channel type flow field because it has higher internal differential pressure and higher reactants velocity in gas diffusion layer, resulting in higher water removal and higher oxygen concentration in the catalyst layer than the channel type flow field. This study is expected to contribute to providing basic data for selecting the optimal flow field for the full stack of polymer electrolyte membrane fuel cells for buildings.

• 한국수소및신에너지학회논문집
• /
• 제30권3호
• /
• pp.220-226
• /
• 2019

Magnesium hydride has a high hydrogen storage capacity (7.6 wt.%), and is cheap and lightweight, thus advantageous as a hydrogen storage alloy. However, Mg-based hydrides undergo hydrogenation/dehydrogenation at high temperature and pressure due to their thermodynamic stability and high oxidation reactivity. MWCNTs exhibit prominent catalytic effect on the hydrogen storage properties of $MgH_2$, weakening the interaction between Mg and H atoms and reducing the activation energy for nucleation of the metal phase by co-milling Mg with carbon nanotubes. Therefore, it is suggested that combining transition metals with carbon nanotubes as mixed dopants has a significant catalytic effect on the hydrogen storage properties of $MgH_2$. In this study, Material life cycle evaluation was performed to analyze the environmental impact characteristics of Mg-CaO-10 wt.% MWCNTs composites manufacturing process. The software of material life cycle assessment (MLCA) was Gabi 6. Through this, environmental impact assessment was performed for each process.

• 한국수소및신에너지학회논문집
• /
• 제30권3호
• /
• pp.282-288
• /
• 2019

When liquefied natural gas (LNG) is vaporized to form natural gas for industrial and household consumption, a tremendous amount of cold energy is transferred from LNG to seawater as a part of the phase-change process. This heat exchange loop is not only a waste of cold energy, but causes thermal pollution to coastal fishery areas by dumping the cold energy into the sea. This project describes an innovative new design for reclaiming cold energy for use by cold storage warehouses (operating in the 35 to $62^{\circ}C$ range). Conventionally, warehouse cooling is done by mechanical refrigeration systems that consume large amounts of electricity for the maintenance of low temperatures. Here, a closed loop LNG heat exchange system was designed (by simulator) to replace mechanical or vapor-compression refrigeration systems. The software PRO II with PROVISION V9.4 was used to simulate LNG cold energy, gas re-liquefaction, and the vaporized process under various conditions. The effects on sensible and latent heats from changes to the array type of heat exchangers have been investigated, as well as an examination of the optimum.

• 한국수소및신에너지학회논문집
• /
• 제30권3호
• /
• pp.201-208
• /
• 2019

Recently, a fuel reforming plant for supplying high purity hydrogen is being applied to submarines. Since steam reforming is an endothermic reaction, it is necessary to continuously supply heat to the reactor. A fuel reforming plant for a submarine needs a multi-stage burner (MSB) to acquire heat and convert the combustion gas to $CO_2+H_2O$. The MSB has problems that the combustion imbalance occurs during start-up due to the temperature restriction of the combustion gas. This problems can be solved by burning $H_2O$ together with fuel and $O_2$. In this study, the simulation results of MSB were analyzed to determine the optimum flow rate of $H_2O$ supplied to the 6-stage burner. When the flow rate of $H_2O$ was low, combustion was concentrated on the burner#6 in comparison with the burner#1-#5. This combustion concentration improved as the supply amount of $H_2O$ increased. As a results, it was necessary to supply at least 4.9 kmol/h of $H_2O$ (per 1 kmol/h of fuel) to burner#1 in order to maintain the combustion gas temperature of each stage at $750^{\circ}C$ and to convert the final stage burner gas composition to $CO_2+H_2O$.

• 한국수소및신에너지학회논문집
• /
• 제30권1호
• /
• pp.83-94
• /
• 2019

LPG is increasingly being used as a clean energy source due to the continuous strengthening of environmental regulations. In addition, the demand of propane which is the basic compound for petrochemicals is increasing for propylene production. In the study, a divided wall column was used as de-propanizer and de-butanizer, which is expected to save large amount of energy among the four conventional distillation columns used for processing LPG. The simulation results showed a decrease of energy duty with ESI by 30.30% using two divided wall columns. Furthermore, simulation case studies were carried out with respect to design and operation condition. The main column tray and withdrawal tray were determined from the design case studies while the internal liquid flow and vapor flow were decided from the operating case studies. Also, ESI of 1.06% could be achieved from the case studies. According to the results, the simulation method used showed that it is greatly helpful to the design and evaluate a highly efficient divided wall column.

• 한국수소및신에너지학회논문집
• /
• 제30권1호
• /
• pp.14-20
• /
• 2019

The power to gas (P2G) is one of the energy storage technologies that can increase the storage period and storage capacity compared to the existing battery type. One of P2G technologies produces hydrogen by decomposing water from renewable energy (electricity) and the other produces $CH_4$ by reacting hydrogen with $CO_2$. The objective of this study is the reaction of $CO_2$ methanation which synthesized methane by reacting carbon dioxide and hydrogen. The effect of $CO_2$ conversion and $CH_4$ selectivity on reaction temperature, pressure, and methane contents over 40% Ni catalyst was mainly investigated throughout this study. As a result, the activity of this catalyst appeared to be the highest in $CH_4$ yield at around $400^{\circ}C$ and the selectivity of $CH_4$ increased with increasing reaction pressure. The methane content was not significantly influenced below 3% of all componets. As the space velocity increases from 10,000 to 30,000/hr, the $CO_2$ conversion rate tends to decrease.

• 한국수소및신에너지학회논문집
• /
• 제29권6호
• /
• pp.570-577
• /
• 2018

Composite pressure vessels made through filament winding are widely used in various fields. Numerous studies regarding composite pressure vessels have been conducted in the automotive industry to improve the space efficiency of trunks as well as the fuel efficiency. Compared with steel liquefied petroleum gas (LPG) vessels used in the conventional LPG vehicles, the use of type 4 composite pressure vessels has advantages in terms of reduction of the weight of vehicles. This study focused on development of type 4 composite pressure vessels that can be installed in the spare tire well. Those type 4 composite pressure vessels are designed with torispherical dome shapes instead of geodecis dome shapes because of the space limitation. To reduce deformation due to the stresses in the axial direction of the vessels, thereby securing the safety of the container, the reinforcing bar concept was applied. A structural analysis software, ABAQUS, confirmed the effect of the reinforcing bar on the axial deformation through the type 4 composite pressure vessel. As a result, the final winding angle of the composite layer was analyzed by applying $26^{\circ}/28^{\circ}/26^{\circ}/28^{\circ}/26^{\circ}/88^{\circ}$ The tensile stress was 939.2 MPa and the compressive stress was 249.3 MPa.

• 한국수소및신에너지학회논문집
• /
• 제29권6호
• /
• pp.587-595
• /
• 2018

Recently, research is being conducted to use a fuel cell as a power source of unmanned aircraft. However, safety standards about applying fuel cells to unmanned aircraft are insufficient. In this paper, to improve the safety of the fuel cells for unmanned aircraft is experimentally studied. For this reason, standards for safety of fuel cells were analyzed. And influence of vibration among the evaluation items related to the safety of the fuel cell for unmanned aircraft was discussed. In order to, at constant intervals, vibration was applied to the fuel cell, then the performance was measured, the measurement items were gas tightness, polarization curve, frequency response analysis (FRA). A total of 220 hours was experimented at 20 hour intervals. the result of vibration test, gas leakage rate was a maximum of -0.04826 kPa/min and Polarization curve reached a maximum of 1.0103 times of the initial value, the charge transfer resistance reached a maximum of 1.0104 times of the initial value. This research indicate that performance of fuel cell is affected by vibration and this study is expected to contribute to the safety of fuel cell for unmanned aircraft.

• 한국수소및신에너지학회논문집
• /
• 제29권6호
• /
• pp.654-660
• /
• 2018

The dependence on global fossil fuels has been gradually reducing all over the world. Some countries which recognized the important of environmental values were joining to carry out international GHG goals. Our country has also participated with high targets (37% reduction compared to BAU 2030 years). So we need to supply materials of lower GHG value such as a bio-diesel. Bio-alcohol is one of the similar bio-fuels that can be reducing GHG. A lot of countries had tried to commercialize through various R&D for bio-alcohol. In this study, we analyzed the fuel characteristics of bio-alcohol fuel produced by domestic technology. And we evaluated a possibility to use as vehicle fuel through mixing of bio-alcohol and gasoline. The mixed fuels were satisfied with 2.3 wt% of oxygen content that is standard of the petroleum and petroleum alternative fuel business Act. We tried to evaluate a emission characteristic of vehicle by mixed fuel. In accordance with the results we tried to find a correlation between fuel and emission.

• 한국수소및신에너지학회논문집
• /
• 제29권6호
• /
• pp.661-667
• /
• 2018

Electric vehicles are taken a long time to charge and are restricted driving where charging infrastructure was not sufficiently constructed. The vehicle developed to solve these problems is a plug-in hybrid vehicle. It is possible to drive a certain distance by using electric motor and when the battery runs out, it operate the engine. Plug-in hybrid vehicle have a complicated structure and a lot of parts comparing a general vehicle because the electric parts and the internal combustion engine are installed together. Therefore, as the aging (mileage) of the plug-in hybrid vehicle, the influence which change of fuel consumption is expected to be larger than a general vehicle, but an experimental data are lacking. In this paper, we cumulate a mileage of the plug-in hybrid vehicle about 15,000 km and measured the fuel economy when the cumulated distance reached within 160 km, 6,500 km, 15,000 km respectively, by using domestic public test method. For measuring fuel economy of the vehicle, CD mode (driving distance on a single charge) which use only motor and the CS mode which operate motor and combustion engine were measured respectively. As a result, the fuel economy slightly increased at cumulated mileage of 6,500 km compared to the 160 km and the fuel economy of 15,000 km was similar to 160 km.