• 한국수소및신에너지학회논문집
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• 제27권1호
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• pp.1-12
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• 2016

In this study, CFD model for a Heat Exchange Steam Reformer (HESR) used for a 10kW SOFC system is developed for the design optimization of the HESR. The model is used to explore the effect of design parameters on the performance of the HESR. In the HESR, heat is delivered from the hot gas channel to the fuel channel to supply the heat required for the fuel reforming. In the fuel channel where the fuel is reformed, thermo-fluid dynamics, heat transfer, and chemical reaction are considered to predict the performance of the reformer. The model is validated with experimental data within 2~3% error. The validated model is used for the parametric study of the HESR design. Channel length, channel diameter, and flow direction are selected as the design parameters. The effects of the HESR design parameters on the outlet temperature, outlet H2 mole fraction, and pressure drop across the reformer are presented using the model.

• 한국수소및신에너지학회논문집
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• 제27권2호
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• pp.201-210
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• 2016

To develop a pressurized chemical looping combustor, conceptual design of 0.5 MWth chemical looping combustor was performed by means of mass and energy balance calculations. Based on the conceptual design, reactivity of oxygen carrier and solid circulation rate were selected as key parameters. Sensitivity analysis of those key parameters were conducted with the change of oxygen carrier utilization percent from 5 to 50% and proper solid circulation rate and solid conversion rate to meet 98% of $CO_2$ selectivity were confirmed. Feasibility of 0.5 MWth pressurized chemical looping combustor was confirmed by experimental studies to find real solid circulation rate and $CO_2$ selectivity within the operating conditions based on the conceptual design. We could varied very wide range of solid circulation rate in two interconnected fluidized bed system. We also got enough $CO_2$ selectivity more than 98% in semi-continuous chemical looping combustor using OCN717 oxygen carrier. Consequently, feasibility of 0.5 MWth pressurized chemical looping combustor was confirmed.

• 한국수소및신에너지학회논문집
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• 제27권3호
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• pp.318-327
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• 2016

In order to improve the performance of temperature field measurements by CT-TDLAS (Computer Tomography Tunable Diode Laser Absorption Spectroscopy), a new reconstruction algorithm, named two-ratios-of-three-peaks method is proposed in this paper. Further, two methods for selecting appropriate initial values of the iterative calculation of CT-TDLAS are proposed. One is MLOS (multiplicative line of sight) method and the other one is ALOS (additive line of sight) method. Two-ratios-of-three-peaks (2R3P) algorithm combined with MART (multiplicative algebraic reconstruction technique) is finally developed for the enhancements of reconstructive calculations. The results have been compared with those obtained by the conventional one-ratio-of-two-peaks (1R2P) algorithm. In order to evaluate the performance of this algorithm, numerical test has been performed using phantom Gaussian temperature distributions with $11{\times}11$ square mesh. The performance of the constructed algorithm has been demonstrated by comparing the results obtained in actual burner experiments with those obtained by thermocouples. It has been verified that 2R3P algorithm with MART and MLOS showed best performance than that of 1R2P algorithm.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.503-512
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• 2012

There is a new power generation system such as direct coal fuel cell (DCFC) with a solid oxide electrolyte operated at relatively high temperature. In the system, it is of great importance to feed coal continuously into anodic electrode surface for its better contact, otherwise it would reduce electrochemical conversion of coal. For that purpose, it is required to improve the electrochemical conversion efficiency by using either rigorous mixing condition such as fluidized bed condition or just by recirculating coal particle itself successively into the reaction zone of the system. In this preliminary study, we followed the second approach to investigate how significantly particle recycle would affect the coal conversion efficiency. As a first phase, coal conversion was analyzed and evaluated from the thermochemical reaction of carbon with air under particle recirculating condition. The coal conversion efficiency was obtained from raw data measured by two different techniques. Effects of temperature and fuel properties on the coal conversion are specifically examined from the thermochemical reaction.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.559-571
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• 2012

Dimethyl ether (DME) is a new clean fuel as an environmentally-benign energy resource. DME can be manufactured from various energy sources including natural gas, coal, and biomass. In addition to its environmentally friendly properties, DME has similar characteristics to those of LPG. The aim of this article is to represent the development of new DME process with KOGAS's own technologies. KOGAS has investigated and developed new innovative DME synthesis process from synthesis gas in gaseous phase fixed bed reactor. DME has been traditionally produced by the dehydration of methanol which is produced from syngas, a product of natural gas reforming. This traditional process is thus called the two-step method of preparing DME. However, DME can also be manufactured directly from syngas (single-step). The single-step method needs only one reactor for the synthesis of DME, instead of two for the two-step process. It can also alleviate the thermodynamic limitations associated with the synthesis of methanol, by converting the produced methanol into DME, thereby potentially enhancing the overall conversion of syngas into DME. KOGAS had launched the 10 ton/day DME demonstration plant project in 2004 at Incheon KOGAS LNG terminal. In the mid of 2008, KOGAS had finished the construction of this plant and has successively finished the demonstration plant operation. And since 2008, we have established the basic design of commercial plant which can produce 3,000 ton/day DME.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.530-537
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• 2012

This work experimentally investigates that Diesel-DME blended fuel influences combustion characteristics and emissions (NOx, CO, HC, smoke) in a single-cylinder DI diesel engine. Diesel is used as a main fuel and DME is blended for the use of its quick evaporating characteristics. Diesel and DME are blended by the method of weight ratio. Weight ratios for Diesel and DME are 95:5 and 90:10 respectively and the both ratios have been used altogether in blended fuel. The experiments are conducted in this study single cylinder engine is equipped with common rail and injection pressure is 700 bar at 1200 rpm. The amount of injected fuels is adjusted to obtain the fixed input calorie value as 972.2 J/cycle in order to compare with the fuel conditions. DME is compressed to 15 bar by using nitrogen gas thus it can be maintained the liquid phase. In this study, different system compared others paper is common rail system, also there is combustion and emission about compared DME and diesel fuel. It is expected to be utilized about blended fuel.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.468-475
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• 2012

A proper stacking force and assembly are important to the performance of fuel cell. Improper assembly pressure may lead to leakage of fuels and high interfacial contact resistance, excessive assembly pressure may result in damage to the gas diffusion layer and other components. The pressure distribution of gas diffusion layer is important to make interfacial contact resistance less for stack performance. To analyze the influence of design parameter factors for pressure distribution, and to optimize stack design, DOE (Design of Experiment) was used for polymer electrolyte membrane fuel cell stack pressure test. As commonly known, the higher clamping force improves the fuel cell stack performance. However, non-uniformity of stress distribution is also increased. It shows that optimization between clamping force and stress distribution is needed for well designed structure of fuel cell stack. In this study, stack design optimization method is suggested by using FEM (Finite Element Methode) and DOE for light-weighted fuel cell stack.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.461-467
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• 2012

Multi-block sulfonated poly (arylene ether sulfone) (SPES) membranes were synthesized by post-sulfonation and its properties characterized. Two types of oligomers, F-terminated and OH-terminated telechelic oligomers, were synthesized by controlling the feed ratio of dihydroxyl- and difluoro-monomers. Their number of repeating unit (X and Y) was analyzed by GPC and $^1H$ NMR. Copolymerization with F-terminated and OH-terminated telechelic oligomers via nucleophilic aromatic substitution, gave high-molecular-weight multi-block PESs. Each block length was controlled to have different values with X5Y10, X10Y10, X20Y10 and X20Y20. Successful polymerization and its successful sulfonation was confirmed by GPC and $^1H$ NMR. RH dependence of proton conductivity of multi-block SPES membranes was comparable to that of Nafion 212 at high RH conditions.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.437-447
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• 2012

Ceria ($CeO_2$) was used to scavenge free radicals which attack the membrane in the polymer electrolyte membrane water electrolysis (PEMWE) circumstance and to increase the duration of the membrane. In order to improve the electrochemical, mechanical and electrocatalytic characteristics, engineering plastic of the sulfonated polyether ether ketone (SPEEK) as polymer matrix was prepared in the sulfonation reaction of polyether ether ketone (PEEK) and the organic-inorganic blended composite membranes were prepared by sol-gel casting method with loading the highly dispersed ceria and cesium-substituted tungstophosphoric acid (Cs-TPA) with cross-linking agent contents of 0.01 mL. In conclusion, CL-SPEEK/Cs-TPA/ceria (1%) membrane showed the optimum results such as 0.130 S/cm of proton conductivity at $80^{\circ}C$, 2.324 meq./g-dry-membrane of ion exchange capacity and mechanical characteristics, and 65.03 MPa of tensile strength which were better than Nafion 117 membrane.

• 한국수소및신에너지학회논문집
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• 제23권5호
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• pp.513-520
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• 2012

The electrochemical reaction of refuse derived fuel (RDF) and refuse plastic/paper fuel (RPF) was investigated in the direct carbon fuel cell (DCFC) system. The open circuit voltage (OCV) of RPF was higher than RDF and other coals because of its thermal reactive characteristic under carbon dioxide. The thermal reactivity of fuels was investigated by thermogravimetric analysis method. and the reaction rate of RPF was higher than other fuels. The behavior of all sample's potential was analogous in the beginning region of electrochemical reactions due to similar functional groups on the surface of fuels analyzed by X-ray Photoelectron Spectroscopy experiments. The potential level of RDF and RPF decreased rapidly comparing to coals in the next of the electrochemical reaction because the surface area and pore volume investigated by nitrogen gas adsorption tests were smaller than coals. This characteristic signifies the contact surface between electrolyte and fuel is restricted. The potential of fuels was maintained to the high current density region over 40 $mA/cm^2$ by total carbon component. The maximum power density of RDF and RPF reached up to 45~70% comparing to coal. The obvious improvement of maximum power density by increasing operating temperature was observed in both refuse fuels.