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Partial Oxidation Reformer in a Plasma-Recuperative Burner (플라즈마-축열버너 부분산화 개질장치)

  • AN, JUNE;CHUN, YOUNG NAM
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.1
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    • pp.68-76
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    • 2021
  • Climate change problems occur during the use of fossil fuel and the process of biogas production. Research continues to convert carbon dioxide and methane, the major causes of climate change, into high-quality energy sources. in order to present the performance potential for the novel plasma-recuperative burner reformer, the reforming characteristics for each variable were indentified. The optimal operating condition of was an O2/C ratio of 1.0 and a total gas supply of 20 L/min. At this time, CH4 conversion was 64%, H2 selectivity was 39%, and H2/CO ratio was 1.13, which were the results applicable to the solid oxide fuel cell fuel stack for RPG, or Residential Power Generator. Recirculation of reformed gas increases the amount of H2 and CO, which are combustible gases, especially the amount of H2. As a result, the H2 selectivity is improved, and high-quality gas can be produced.

Mode 1 Fracture Toughness Test of CNT/Epoxy Composites with Different CNT Content (CNT 함량에 따른 CNT/Epoxy 복합재료 제작 및 모드 1 파괴 인성 평가)

  • KWON, DONG-JUN;YOO, HYEONGMIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.1
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    • pp.86-91
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    • 2021
  • In order to save the energy in vehicles using renewable energy, it is necessary to reduce the weight of parts with polymer matrix composites. Carbon nanotube (CNT) is the nano-scale reinforcement used to increase the interlaminar strength of fiber reinforced composites or enhance the fracture toughness of polymer. However, since the degree of improvement in mechanical properties varies according to the various experimental conditions such as shape of reinforcement, types of matrix and dispersion of reinforcement, research to find the optimal conditions is essentially needed. In this study, CNT/epoxy composites with different CNT concentration were fabricated under the same conditions, and the optimal CNT content (2 wt%) was found through Mode 1 fracture toughness test. Furthermore, through optical microscopy, it was confirmed that the fracture toughness was rather decreased due to the CNT aggregation when the CNT content exceeded 2 wt%.

Strategies of the Korea-UAE Cooperation for Hydrogen Station and Hydrogen Bus (한국과 UAE의 수소 충전소와 수소 버스 협력 전략)

  • KWON, YOUNG-IN;KIM, SEOLJOO;BAEK, YOUNGSUN;JUNG, BYUNGDO
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.431-441
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    • 2021
  • UAE is first country in Middle East to approve UN Paris Climate Agreement. Ministry of Climate Change and Environment of UAE announced National Climate Change Plan for carbon reduction to replace 24% by clean energy. Dubai open its first hydrogen station in UAE and Middle East in 2017, and Abu Dhabi planed to open second hydrogen station in 2019 but not realized. Korean government announced hydrogen economy roadmap in 2019 and various hydrogen cooperation are realized between UAE, Korea, Germany, USA, and Japan. MOU between Ministry of State of UAE and Ministry of Land, Infrastructure and Transport of Korea in 2019 for the cooperation of hydrogen city. This study propose strategies for the 'Hydrogen Based Public Transport in UAE' by the support of Korea government considering various stakeholder.

Ni Catalyst Properties for Ammonia Reforming: Comparison of Ni Content and Space Velocity (암모니아 개질에 대한 Ni 촉매 특성: Ni 함량과 공간속도 비교)

  • WOO, JINHYEOK;KIM, TAEYOUNG;KIM, JU EON;CHO, BYUNGOK;JUNG, SUKYONG;PARK, SAEMI;LEE, SOOCHOOL;KIM, JAECHANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.464-469
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    • 2021
  • A reforming catalyst for hydrogen production from ammonia is being studied. Non-novel metal based Ni catalysts for use in ammonia reforming processes are being developed. In this study, the ammonia reforming characteristics according to Ni content of the alumina pellet supported catalyst in the mid-temperature region were investigated under different space velocity. 20 Ni and 3,000 h-1 showed the best catalytic activity with ammonia conversion of 63% among all conditions.

A Study on the Thermal Characteristics of the Vacuum Jacket Valve for Transporting Liquefied Hydrogen According to the Degree of Vacuum (액화수소 수송용 진공자켓 밸브의 진공도에 따른 열적특성에 대한 연구)

  • OH, SEUNG JUN;JEON, KYUNG SOOK;YOON, JEONG HWAN;CHOI, JEONGJU
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.585-591
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    • 2021
  • Liquefied hydrogen have advantage which reduces the volume by about 800 times or more compared to hydrogen gas, so it is possible to increase the storage density. However, liquefied hydrogen produced by cryogenic cooling of 20 K or less at normal pressure has a problem of maximizing the insulation effect that blocks heat introduced from the outside. Representative insulation technologies include vacuum insulation and multi-layer insulation materials and in general, heat blocking is attempted by combining insulation technologies. Therefore, in this study, the pressure of the internal vacuum layer was changed to 10-1, 10-2, 10-3 and 10-4 Torr to confirm the thermal insulation performance of the vacuum jacket valve for transporting liquefied hydrogen. As a result, it was confirmed that the insulation performance improved as the degree of vacuum increased.

Application of Regularized Linear Regression Models Using Public Domain data for Cycle Life Prediction of Commercial Lithium-Ion Batteries (상업용 리튬 배터리의 수명 예측을 위한 고속대량충방전 데이터 정규화 선형회귀모델의 적용)

  • KIM, JANG-GOON;LEE, JONG-SOOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.592-611
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    • 2021
  • In this study a rarely available high-throughput cycling data set of 124 commercial lithium iron phosphate/graphite cells cycled under fast-charging conditions, with widely varying cycle lives ranging from 150 to 2,300 cycles including in-cycle temperature and per-cycle IR measurements. We worked out own Python codes which reproduced the various data plots and machine learning approaches for cycle life prediction using early cycles and more details not presented in the article and the supplementary information. Particularly, we applied regularized ridge, lasso and elastic net linear regression models using features extracted from capacity fade curves, discharge voltage curves, and other data such as internal resistance and cell can temperature. We found that due to the limitation in the quantity and quality of the data from costly and lengthy battery testing a careful hyperparameter tuning may be required and that model features need to be extracted based on the domain knowledge.

A Study on Anode Fuel Composition of Direct Borohydride/Hydrogen Peroxide Fuel Cell (직접 수소화붕소나트륨/과산화수소 연료전지의 산화극 연료 조성에 관한 연구)

  • LEE, TAE HOON;YU, SU SANG;OH, TAEK HYUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.514-523
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    • 2021
  • This study investigated the effect of anode fuel composition on the performance of direct borohydride/hydrogen peroxide fuel cells (DBHPFCs). The effect of sodium borohydride (NaBH4) and sodium hydroxide (NaOH) concentrations on fuel cell performance was determined through fuel cell tests. Fuel cell performance increased with an increase in the NaBH4 concentration, whereas it decreased with an increase in the NaOH concentration. The anode fuel composition was selected as 10 wt% NaBH4+10 wt% NaOH+80 wt% H2O based on the fuel viscosity, electrochemical reaction rate, and decomposition reaction rate. DBHPFCs were also tested to analyze the effect of operating temperature and operation time on fuel cell performance. The present results can be used as a reference basis to determine operating conditions of DBHPFCs.

A Numerical Analysis for High Performance on DME High Pressure Fuel Pump Using Taguchi Method (Taguchi Method 을 이용한 DME 고압 연료 펌프에 대한 고성능 수치 해석)

  • SAMOSIR, BERNIKE FEBRIANA;CHO, WONJUN;LIM, OCKTAECK
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.636-641
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    • 2021
  • Using numerical analysis, various factors influencing the performance development of high-pressure pumps for Dimethyl Ether (DME) engines were identified and the impact of each factor was evaluated using Taguchi method. DME fuels are more compressive than diesel fuels and have the lower heat generation, so it is necessary to increase the size of the plunger and speed (RPM) of the pump as well. In addition, it is necessary to change the shape and design of control valve to control the discharge flow and pressure. In this study, various variables affecting the performance and flow rate increase of high-pressure pumps for DME engines are planned using Taguchi method, and the best design method is proposed using correlation of the most important variables. As a result, we were able to provide the design value needed for a six-liter engine and provide optimal conditions. The best combination factors to optimize the flow rate at RPM 2,000 and diameter plunger with 20 mm. The regression equation can also be used to optimize the flow rate; -8, 13+0, 2552 RPM +54, 17 diam. Plunger.

Techno-Economic Analysis of Water Electrolysis System Connected with Photovoltaic Power Generation (태양광 발전 연계 수전해 시스템의 경제성 분석)

  • HWANG, SUNCHEOL;PARK, JIN-NAM
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.477-482
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    • 2021
  • Hydrogen production, hydrogen production cost, and utilization rate were calculated assuming four cases of hydrogen production system in combination of photovoltaic power generation (PV), water electrolysis system (WE), battery energy storage system (BESS), and power grid. In the case of using the PV and WE in direct connection, the smaller the capacity of the WE, the higher the capacity factor rate and the lower the hydrogen production cost. When PV and WE are directly connected, hydrogen production occurs intermittently according to time zones and seasons. In addition to the connection of PV and WE, if BESS and power grid connection are added, the capacity factor of WE can be 100%, and stable hydrogen production is possible. If BESS is additionally installed, hydrogen production cost increases due to increase in Capital Expenditures, and Operating Expenditure also increases slightly due to charging and discharging loss. Even in a hydrogen production system that connects PV and WE, linking with power grid is advantageous in terms of stable hydrogen production and improvement of capacity factor.

Construction and Characterization of Poly (Phenylene Oxide)-Based Organic/Inorganic Composite Membranes Containing Graphene Oxide for the Development of an Anion Exchange Membrane with Extended Ion Cluster (확장된 이온 클러스터를 갖는 음이온 교환막 개발을 위한 그래핀 옥사이드를 함유한 폴리(페닐렌 옥사이드) 기반 유·무기 복합막의 제조 및 특성분석)

  • CHU, JI YOUNG;YOO, DONG JIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.524-533
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    • 2021
  • In this study, a series of anion conductive organic/inorganic composite membranes with excellent ionic conductivity and chemical stability were prepared by introducing graphene oxide (GO) inorganic nanofiller into the quaternized poly(phenylen oxide (Q-PPO) polymer matrix. The fabricated organic/inorganic composite membranes showed higher ionic conductivity than the pristine membrane. In particular, Q-PPO/GO 0.7 showed the highest ionic conductivity value of 143.2 mS/cm at 90℃, which was 1.56 times higher than the pristine membrane Q-PPO (91.5 mS/cm). In addition, the organic/inorganic composite membrane showed superior dimensional stability and alkaline stability compared to the pristine membrane, and the physicochemical stability was improved as the content of inorganic fillers increased. Therefore, we suggest that the as-prepared organic/inorganic composite membranes are very promising materials for anion exchange membrane applications with high conductivity and alkaline stability.