• Title/Summary/Keyword: K3 surface

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Characterization of Atmospheric H2-Plasma-Treated LiNi1/3Co1/3Mn1/3O2 as Cathode Materials in Lithium Rechargeable Batteries (리튬이차전지에서 대기압 수소플라즈마 처리된 LiNi1/3Co1/3Mn1/3O2 양극 활물질의 특성분석)

  • Sun, Ho-Jung;Lee, Jae-Ho;Jeong, Hyun-Young;Seok, Dong-Chan;Jung, Yongho;Park, Gyungse;Shim, Joongpyo
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.2
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    • pp.160-171
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    • 2013
  • $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ powder for cathode materials in lithium rechargeable batteries was treated by atmospheric plasma containing hydrogen to investigate the relationship between charge/discharge performance and physical/chemical changes of materials. Hydrogen plasma at atmosphere pressure was irradiated on the surface of active materials, and the change for their crystal structure, surface morphology, and chemical composition were observed by XRD, SEM-EDS and titration method, respectively. The crystal structure and surface morphology of $H_2$ plasma-treated powders were not changed but their chemical compositions were slightly varied. For charge/discharge test, $H_2$ plasma affected initial capacity and rate capability of active materials but continuous cycling was not subject to plasma treatment. Therefore, it was observed that $H_2$ plasma treatment affected the surface of materials and caused the change of chemical composition.

Preparation of PET Nanocomposites: Dispersion of Nanoparticles and Thermal Properties

  • Her, Ki-Young;Kim, Dae-Heum;Lim, Soon-Ho
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.4
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    • pp.71-73
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    • 2008
  • The development of polymer/inorganic nanocomposites has attracted a great deal of interest due to the improved hybrid properties derived from the two different components. Various nanoscale fillers have been used to enhance polymer mechanical and thermal properties, such as toughness, stiffness, and heat resistance. The effects of the filler on the final properties of the nanocomposites are highly dependent on the filler shape, particle size, aggregate size, surface characteristics, polymer/inorganic interactions, and degree of dispersion. In this paper, we describe the influence of different $CaCO_3$ dispersion methods on the thermal properties of polyethylene terephthalate (PET)/$CaCO_3$ composites: i.e., the adsorption of $CaCO_3$ on the modified PET surface, and the hydrophobic modification of the hydrophilic $CaCO_3$ surface. We prepared PET/$CaCO_3$ nanocomposites using a twin-screw extruder, and investigated their thermal properties and morphology.

Effect of surface and heat treatment on the bond strength of veneering ceramics to zirconia(Y-TZP) (표면처리와 열처리가 전장도재와 지르코니아의 결합력에 미치는 영향)

  • Lee, Jung-Hwan;Ahn, Jae-Seok
    • Journal of Technologic Dentistry
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    • v.35 no.4
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    • pp.271-280
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    • 2013
  • Purpose: This study was to assess the effect of surface and heat treatment on the bond strength of veneering ceramics to zirconia. Methods: The specimens were divided into 7 groups according to surface treatment and heat treatment conditions prior to porcelain application. ten specimens from each group were subjected to a 3-point flexural test. In addition the influence of surface and heat treatment on surface roughness values and phase transformation of zirconia was evaluated. Statistical analysis was performed with one-way ANOVA and post hoc Tukey's test. Results: Bond strength ranged from $20.67{\pm}3.13MPa$ to $32.69{\pm}4.52$. Bond strength of surface treatment group was lower than that of control group but only $Al_2O_3$ sandblasting group was significant difference. Bond strength of heat treatment group was higher than that of surface treatment group but there was no statistical significance. Conclusion: Bond strength of veneering ceramics to zirconia was affected by surface and heat treatment.

Acid Pickling/polishing of AZ31 Magnesium Alloy

  • Fazal, Basit Raza;Moon, Sungmo
    • Journal of the Korean institute of surface engineering
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    • v.49 no.3
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    • pp.231-237
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    • 2016
  • This article reports a new chemical bath for preparing a mirror-like surface of AZ31 Mg alloy. In order to find an appropriate chemical polishing solution, four different acidic solutions of sulphuric acid, nitric acid, acetic acid and a specially designed mixture of nitric acid and acetic acid were investigated in view of the changes in surface appearance, roughness and dissolution rate of AZ31 Mg alloy. The surface scales on AZ31 Mg alloy were readily removed by all the acidic solutions, but a reflective surface was produced only by etching in the specially designed solution, and only after a specific etching time. The surface roughness increased with etching time in sulphuric acid, nitric acid, and acetic acid, but it lowered after a specific etching time in the specially designed mixture of nitric acid and acetic acid. Dissolution rate of the alloy in the specially designed mixture of nitric acid and acetic acid appeared to be more than twice than that in separate nitric acid or acetic acid. In this work, we recommend the mirror-like surface of AZ31 Mg alloy obtained by polishing for an optimum time in a mixture of nitric acid and acetic acid for following surface finishings, chemical conversion coating, electroplating, electrophoretic painting and anodizing treatment.

Study on Infrared Image Generation for Different Surface Conditions with Different Sensor Resolutions (물체의 표면 상태와 센서의 해상도에 따른 적외선 영상 구현 연구)

  • Choi, Jun-Hyuk;Shin, Jong-Mook;Kim, Jung-Ho;Kim, Tae-Kuk
    • Journal of the Society of Naval Architects of Korea
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    • v.47 no.3
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    • pp.342-349
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    • 2010
  • This paper is a foundation work in developing a software for generating infrared images from a scene with various objects. The spectral radiance received by a remote sensor is consisted of the self-emitted, reflected and scattered components. In general, the self-emitted component is the most important part for generating Infrared signatures from the object. In this paper, the infrared image generation considering various surface temperature and optical surface property of a flat plate is demonstrated in MWIR($3{\sim}5{\mu}m$) and LWIR($8{\sim}12{\mu}m$) regions for different spatial resolutions of the images. Resulting spectral radiance values in the MWIR($3{\sim}5{\mu}m$) and LWIR($8{\sim}12{\mu}m$) regions arrived at the infrared sensor are compared numerically and graphically by recognizing that they are strongly dependent on the surface conditions such as the surface temperature and the surface emissivity. And these infrared images are also shown to be strongly dependent on the resolutions of the infrared imaging devices as well. This study reveals that the surface conditions are more dependent on the radiance level from the surface while the resolution of the imaging device is more responsible for identifying the shape of object.

SHEAR BOND STRENGTHS BETWEEN ABRASION-RESISTANT DENTURE TEETH AND COMPOSITE RESINS (의치용 레진치와 수복용 복합레진 간의 결합강도에 관한 연구)

  • Kim, Mee-Lee;Jeong, Chang-Mo;Jeon, Young-Chan;Lim, Jang-Seop
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.2
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    • pp.201-212
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    • 2002
  • This study investigated the shear bond strengths between abrasion-resistant denture teeth and composite resins according to surface treatments. Denture teeth for this study were Trubyte IPN teeth(Dentsply Inc., USA) with interpenetrating polymer network and Endura Posterio (Shofu Inc. Japan) of composite resin teeth, and restorative composite resins were Clearfil FII (Kuraray, Japan) of the self-cured composite resin and Z100(3M Dental Product, USA) of the light-cured composite resin. Five different surface treatments were evaluated: (1) $50{\mu}m\;A1_2O_3$ sandblasting: (2) #100 carbide paper; (3) chloroform; (4) retentive holes; and (5) no treatment. After surface treatments, denture teeth were examined by scanning electron microscopy(SEM), and the maximum shear bond strengths between abrasion-resistant denture teeth and composite resins were measured using Instron. The results were as follows; 1. IPN teeth treated with sandblasting had the highest shear bond strength, and Endura treated with sandblasting and carbide paper had significantly greater shear bond strength than with any other surface treatment. 2. Regardless or composite resins, the shear bond strength on Endura was greater than on IPN teeth. 3. Regardless of denture teeth, the shear bond strength of Clearfil FII was greater han of Z100. 4. In appearance of SEM, IPN teeth treated with sandblasting showed generalized roughness on the all of surface, however, carbide paper treatment resulted in partly rough. Endura treated with sandblasting and carbide paper showed similar surface characteristics. Wetting denture teeth surface with chloroform removed the debris and created a particle-free and smooth surface.

Surface Characteristics and Biocompatibility of Hydroxyapatite Deposited Ti alloys by Electrochemical Deposition

  • Lee, Kang;Choe, Han Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2015.11a
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    • pp.141-141
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    • 2015
  • In this study, a series of hydroxyaptite (HAp) are produced on Ti dental implant using electrochemical deposition. Based on the preliminary analysis of the coating structure, composition and morphology. In vitro studies were performed with MC3T3-E1 cell to investigate the effect of biological change on different surface conditions.

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Improving of Corrosion Resistance of Aluminum Alloys by Removing Intermetallic Compound

  • Seri, Osami
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.158-161
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    • 2008
  • It is well known that iron is one of the most common impurity elements found in aluminum and its alloys. Iron in the aluminum forms an intermetallic compounds such as $FeAl_3$. The $FeAl_3$ particles on the aluminum surface are one of the most detrimental phases to the corrosion process and anodizing procedure for aluminum and its alloys. Trial and error surface treatment will be carried out to find the preferential and effective removal of $FeAl_3$ particles on the surfaces without dissolution of aluminum matrix around the particles. One of the preferable surface treatments for the aim of getting $FeAl_3$ free surface was an electrochemical treatment such as cathodic current density of $-2kAm^{-2}$ in a 20-30 mass% $HNO_3$ solution for the period of 300s. The corrosion characteristics of aluminum surface with $FeAl_3$ free particles are examined in a $0.1kmol/m^3$ NaCl solution. It is found that aluminum with free $FeAl_3$ particles shows higher corrosion resistance than aluminum with $FeAl_3$ particles.

Adsorption Characteristics of Benzene and MEK on Surface Oxidation Treated Adsorbent -Surface Oxidation by HNO3, H2SO4 and (NH4)2S2O8- (표면산화 처리된 흡착제의 Benzene 및 MEK 흡착 특성 - HNO3, H2SO4 및 (NH4)2S2O8에 의한 표면산화-)

  • Shim, Choon-Hee;Lee, Woo-Keun
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.1
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    • pp.25-33
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    • 2006
  • The objective of this research is to improve the adsorption capacity of adsorbent made from MSWI (Municipal Solid Waste Incinerator) fly ash by surface oxidation. Used oxidation agents were $HNO_{3}$, $H_{2}SO_{4}$ and $(NH_{4})_{2}S_{2}O_{8}$. These agents can modify the surface property of an adsorbent such as specific surface area, pore volume, and functional group. The surface structure was studied by BET method with $N_{2}$ adsorption. The acid value and base value were determined by Boehm's method. The adsorption properties were investigated with benzene and MEK (Methylethylketone). According to the results, the specific surface area of the adsorbent was increased from 309.2 $m^{2}$/g to 553.2 $m^{2}$/g by $HNO_{3}$ oxidation. But $H_{2}SO_{4}$ and $(NH_{4})_{2}S_{2}O_{8}$ oxidation was decreased slightly. After Oxidation, surface acid value increased, but base value decreased. FAA-N shows the highest acid value. The content of oxygen increased greatly and oxygen group was created on the adsorbent surface. The surface oxidation improved the adsorbing capacity for MEK. The amount of adsorbing MEK was increased from 189 $m^{2}$/g to 639 $m^{2}$/g by $HNO_{3}$ oxidation.

An Analysis on the Inquiry Activities of Quadratic Surface throughout Mathematically Gifted Students' Analogical Inference (수학영재학생들의 유추를 통한 이차곡면의 탐구활동 분석)

  • Yang, Ki-Yeol;Lee, Ui-Jin
    • Journal of Gifted/Talented Education
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    • v.21 no.2
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    • pp.269-286
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    • 2011
  • The purpose of this thesis is to examine difficulties students face in the inquiry activities of quadratic surface throughout mathematically gifted students' analogical inference and the influence of Cabri 3D in students' inquiry activities. For this examination, students' inquiry activities were observed, data of inferring quadratic surface process was analyzed, and students were interviewed in the middle of and at the end of their activities. The result of this thesis is as following: First, students had difficulties to come up with quadratic surfaced graph in the inquiry activity of quadratic surface and express the standard type equation. Secondly, students had difficulties confirming the process of inferred quadratic surface. Especially, students struggled finding out the difference between the inferred quadratic surface and the existing quadratic surface and the cause of it. Thirdly, applying Cabri 3D helped students to think of quadratic surface graph, however, since it could not express the quadratic surface graph in a perfect form, it is hard to say that Cabri 3D is helpful in the process of confirming students' inferred quadratic surface.