• 제목/요약/키워드: K252a

검색결과 1,580건 처리시간 0.032초

Synthesis of Silver Nanocrystallites by a New Thermal Decomposition Method and Their Characterization

  • Lee, Don-Keun;Kang, Young-Soo
    • ETRI Journal
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    • 제26권3호
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    • pp.252-256
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    • 2004
  • We formed silver nanocrystallites by the thermal decomposition of a $Ag^{+1}$-oleate complex, which was prepared by a reaction with $AgNO_{3}$ and sodium oleate in a water solution. The resulting monodispersed silver nanocrystallites were produced by controlling the temperature (290$^{\circ}$C). Transmission electron microscopic (TEM) images of the particles showed a 2-dimensional assembly of the particles with a diameter of $9.5{\pm}0.7nm$, demonstrating the uniformity of these nanocrystallites. An energy-dispersive X-ray (EDX) spectrum and X-ray diffraction (XRD) peaks of the nanocrystallites showed the highly crystalline nature of the silver structure. We analyzed the decomposition of the $Ag^{+1}$-oleate complex using a Thermo Gravimetric Analyzer (TGA) and observed the crystallization process using XRD.

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Theoretical Studies on the Reactions of Acetate Esters with Substituted Phenolate Anion Nucleophiles$^1$

  • 임웅묵;김왕기;정학진;이익준
    • Bulletin of the Korean Chemical Society
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    • 제16권3호
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    • pp.252-256
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    • 1995
  • Semiempirical MO calculations using the PM3 method are performed on the reactions of acetate esters with substituted phenolate anions. The mechanistic change from rate-limiting formation to breakdown of the anionic intermediate is shown to occur in the gas-phase, especially for meta-nitrophenyl acetate. However the mechanistic change-over takes place at a lower basicity ($pK_0$) of the anion nucleophile than found for the corresponding formate. This lowering of $pK_0$ has been ascribed to the electron donating effect of the methyl group in the acetate. For the reactions involving rate-limiting breakdown of the intermediate, the large Bronsted coefficients, ${\beta}_X({\beta}_{nuc})$, are expected in general, but the magnitude increases to a larger value and the pK0 is lowered accordingly, when an electron-donating nonleaving group, like $CH_3$, is present. This type of nonleaving group effect provides a necessary condition for the carbonyl addition-elimination mechanism with rate-limiting breakdown of the intermediate.

Surface Passivation Method for GaN UV Photodetectors Using Oxygen Annealing Treatment

  • Lee, Chang-Ju;Park, Hongsik
    • 센서학회지
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    • 제25권4호
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    • pp.252-256
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    • 2016
  • Epitaxially grown GaN layers have a high surface state density, which typically results in a surface leakage current and a photoresponse in undesirable wavelengths in GaN optoelectronic devices. Surface passivation is, therefore, an important process necessary to prevent performance degradation of GaN UV photodetectors. In this study, we propose oxygen-enhanced thermal treatment as a simple surface passivation process without capping layers. The GaN UV photodetector fabricated using a thermal annealing process exhibits improved electrical and photoresponsive characteristics such as a reduced dark current and an enhanced photoresponsive current and UV-to-visible rejection ratio. The results of this study show that the proposed surface passivation method would be useful to enhance the reliability of GaN-based optoelectronic devices.

Comparative Genomic Analysis of Staphylococcus aureus FORC_001 and S. aureus MRSA252 Reveals the Characteristics of Antibiotic Resistance and Virulence Factors for Human Infection

  • Lim, Sooyeon;Lee, Dong-Hoon;Kwak, Woori;Shin, Hakdong;Ku, Hye-Jin;Lee, Jong-eun;Lee, Gun Eui;Kim, Heebal;Choi, Sang-Ho;Ryu, Sangryeol;Lee, Ju-Hoon
    • Journal of Microbiology and Biotechnology
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    • 제25권1호
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    • pp.98-108
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    • 2015
  • Staphylococcus aureus is an important foodborne pathogen that causes diverse diseases ranging from minor infections to life-threatening conditions in humans and animals. To further understand its pathogenesis, the genome of the strain S. aureus FORC_001 was isolated from a contaminated food. Its genome consists of 2,886,017 bp double-stranded DNA with a GC content of 32.8%. It is predicted to contain 2,728 open reading frames, 57 tRNAs, and 6 rRNA operons, including 1 additional 5S rRNA gene. Comparative phylogenetic tree analysis of 40 complete S. aureus genome sequences using average nucleotide identity (ANI) revealed that strain FORC_001 belonged to Group I. The closest phylogenetic match was S. aureus MRSA252, according to a whole-genome ANI (99.87%), suggesting that they might share a common ancestor. Comparative genome analysis of FORC_001 and MRSA252 revealed two non-homologous regions: Regions I and II. The presence of various antibiotic resistance genes, including the SCCmec cluster in Region I of MRSA252, suggests that this strain might have acquired the SCCmec cluster to adapt to specific environments containing methicillin. Region II of both genomes contains prophage regions but their DNA sequence identity is very low, suggesting that the prophages might differ. This is the first report of the complete genome sequence of S. aureus isolated from a real foodborne outbreak in South Korea. This report would be helpful to extend our understanding about the genome, general characteristics, and virulence factors of S. aureus for further studies of pathogenesis, rapid detection, and epidemiological investigation in foodborne outbreak.

Study of PD Location in Generators by PD Pulses Propagation

  • Cheng, Yang-Chun;Li, Cheng-Rong;Wang, Wei
    • Transactions on Electrical and Electronic Materials
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    • 제7권5호
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    • pp.252-256
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    • 2006
  • When a partial discharge takes place at the stator of a generator, the electrical pulse will propagate along the stator bars and the capacitor chains formed by the end part of the stator winds. On the first path, the pulse propagates as a travel wave at slow speed. On the second path, the pulse propagates at quick speed. Based on the data of the experiments on a real 50 MW steam generator, the author has found the pulses can propagate by magnetic field of the stator winding. It was studied that how to locating the partial discharge by signals coming from the different paths, including the features of signals on the two paths at time domain and frequency domain, the measurement frequency rang of the signals, the blind area, the advantage and disadvantage of this method.

Epithermal Neutron Flux Enhancement Using SMA in Designing a Cf-Based Neutron Beam for BNCT

  • Kim, Do-Heon;Kim, Jong-Kyung
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1995년도 추계학술발표회논문집(2)
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    • pp.937-942
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    • 1995
  • Great interest has prompted Boron Neutron Capture Therapy (BNCT) as a new treatment for brain tumors. The use of $^{252}$Cf as a neutron source for BNn makes the in-hospital treatments of tumors to be possible. Newly proposed subcritical multiplying assemblies (SMA) are explored to improve relatively tow neutron fluxes of the source and construct the feasibilities of $^{252}$Cf as a neutron source. The MCNP code has been used to evaluate the effective multiplication factor of the entire system and the intensities and percentages of epithermal neutron flux at the patient-end surface of the system. The neutron beam using SMA shows the epithermal neutron flux enhancement of about 13 times as large as the beam without using SMA. It is expected that the neutron beam proposed in this research will be more effective for treatment of tumors due to the increased therapeutic neutron fluxes.

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The Study of the Electroconductive Liquids Flow in a Conduction Magnetohydrodynamic Pump

  • Naceur, Sonia;Kadid, Fatima Zohra;Abdessemed, Rachid
    • Transactions on Electrical and Electronic Materials
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    • 제17권5호
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    • pp.252-256
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    • 2016
  • This paper deals the study of a linear MHD pump solution used to eliminate and to avoid the dangers of the mercury appearing through pollution and contamination. The formulation of the magnetohydrodynamic phenomena is derived from Maxwell and Navier-Stokes equations are solved using the finite volume method. Simulation results highlight the performance of the pump such as the electromagnetic force, the velocity, and the pressure, the application of Ansys-Fluent software validation these results.

K-SRI 에서의 방사성 중성자 선원교정 (Radioactive Neutron Source Calibration at the Korea Standards Research Institute)

  • 황선태;최길웅
    • Journal of Radiation Protection and Research
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    • 제10권1호
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    • pp.67-73
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    • 1985
  • 임의 중성자 선원의 중성자 방출율 측정과 경합핵종에 의한 중성자 포획, 열중성자 누출 및 선원자체의 중성자 흡수에 적용되는 보정을 포함하여 한국표준연구소에서의 중성자 선원교정을 위한 $MnSO_4$ 용액 방법을 기술한다. 본 보고서에서는 에너지가MeV 영역에서 사용되는 중성자 방사선 기기의 교정검사를 위하여 상용화되어 있는 중성자 선원 (Am-Be, $^{252}Cf$)을 고려하였다.

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전력전송구간을 분할하여 데이터 신호를 전송하는 전력선 통신방법 (Power Line Communication Method with Splitting of Power Transmission Interval)

  • 조재승;황일규
    • 전력전자학회논문지
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    • 제17권3호
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    • pp.252-258
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    • 2012
  • This paper studies the power line communication method with splitting of power transmission interval in the small DC power system using pulse width modulation. The method divides the entire interval for transmitting power and data into a power transmission interval where power is supplied to a load and a data transmission interval where power from the power supply to the load is disconnected. The circuit is designed for the implementation to separate the power line from the power supply and load. The results of tests show the feasibility of the proposed power line communication method.