• Title/Summary/Keyword: K-ToBI

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Microstructure of ZnO Varistors with Various Additives (다양한 첨가 성분을 함유한 ZnO 바리스터의 미세구조)

  • Lee, Hoon;Cho, Sung-Gurl;Kim, Chang-Jo;Kim, Hyung-Sik
    • Journal of the Korean Ceramic Society
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    • v.32 no.12
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    • pp.1323-1330
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    • 1995
  • The effects of various additives on the microstructures of sintered ZnO varistors were examined. Bi2O3, Sb2O3 and Cr2O3 were added to ZnO step by step to identify the effect of each component. The specimens were prepared by sintering at 110$0^{\circ}C$ and 120$0^{\circ}C$ in ambient atmosphere. In ZnO-Bi2O3-Sb2O3 ternary system, decrease of averge grain size due to antimony oxide addition depends on sintering temperature as well as Bi2O3 content. When Sb2O3 was partly or completely replaced by Cr2O3, grain size was further reduced. A significant amount of pyrochlore phase which was not transformed to spinel and Bi2O3-rich liquid phase seemed to remain during sintering at 110$0^{\circ}C$. Unlike ZnO-Bi2O3-Sb2O3 system, the $\alpha$-spinel phase containing significant amount of Cr did not transform to pyrochlore during furnace cooling. Fine spinel particles around 1${\mu}{\textrm}{m}$ size were ovserved within ZnO grains and grain boundaries, which were believed to be responsible for grain-growth inhibition in ZnO-Bi2O3-Sb2O3.

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Electrical properties of Si-based La-apatite ceramics with addition of Bismuth (Silicate계 La-아파타이트 산화물의 Bi 첨가에 따른 전기적 특성)

  • Kim, Dae-Young;Jo, Seo-Hyeon;Jeong, Gwang-Ho;Lee, Tae-Ho;Lee, Sung-Gap;Kim, Young-Gon;Lee, Young-Hee
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1440-1441
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    • 2011
  • Apatite-lanthanum silicate has attracted considerable interest in recent years due to its high oxide ion conductivity, In this paper, Bi-doped samples $La_8Bi_2(SiO_4)_6O_3$ were prepared by conventional solid-state method and the influences of Bi-dopant content on calcining temperature were reported. The Samples were characterized by X-ray diffraction (XRD) and scanning electron micrograph (SEM) and impedance analysis.

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Measurement of Peltier Heat at the Solid/Liquid Interface and Its Application to Crystal Growth II : Measurement and Application (고/액 계면에서의 Peltier 열 측정 및 결정성장에의 응용 II : 측정과 응용)

  • Kim, Il-Ho;Jang, Kyung-Wook;Lee, Dong-Hi
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1112-1116
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    • 1999
  • Thermoelectric effects on the temperature changes at the solid- and liquid-phase and its interface were studied by using the unidirectional solidification of $\textrm{Bi}_{2}\textrm{Te}_{3}$. Cooling or heating effects measured with current density. polarity and current passing time were quite different. By separating sole Peltier, Thomson and Joule heat theoretically and experimentally, the Peltier coefficient at the solid/liquid interface of $\textrm{Bi}_{2}\textrm{Te}_{3}$ was -1.10$\times\textrm{10}^{-1}$V, and the Thomson coefficients of solid- and liquid-phase were 7.31\times\textrm{10}^{-4}V/K, 5.77\times\textrm{10}^{-5}V/K, respectively. When D.C. passed from solid-phase to liquid-phase during the crystal growth of $\textrm{Bi}_{2}\textrm{Te}_{3}$ the crystal with more directionality was obtained owing to increase of the temperature gradient in liquid by the Peltier cooling. But in reverse current direction, the crystallinity was not changed significantly.

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The Development of the Bi-directionally Personalized Broadcasting and the Targeting Advertisement System Based on the User Profile Techniques (사용자 프로파일 기반의 맞춤형 광고 서비스 및 양방향 개인 맞춤형 방송 시스템 구축)

  • Shin, Sa-Im;Lee, Jong-Soel;Jang, Se-Jin;Lee, Soek-Pil
    • Journal of Broadcast Engineering
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    • v.15 no.5
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    • pp.632-641
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    • 2010
  • This paper shows the research about the personalized broadcasting system. The personalized broadcasting is the service that users only show the programs which they want to watch when they want to watch these. The purpose of the bi-directional broadcasting service is supporting more satisfied and more personalized services by permitting the bi-directional data transformation. This research also develops the user profiling system for the bi-directional and personalized broadcasting service. This system applied the TV-Anytime metadata specifications which is the standard for the personalized broadcasting services, the system supports the various functions for the bi-directionl and personalized broadcasting such as the user profiling, contents metadata and targeting advertisement services. The bi-directional and personalized broadcasting system increases the users' satisfaction with the recommendation and management of the personally favorite broadcasting contents and advertisements, the trial run results show that the services raise the users' satisfaction with the intelligent and discriminating broadcasting services.

A Combined Rietveld Refinement on the Crystal Structure of a Magnetoelectric Aurivillius Phase $Bi_5Ti_3FeO_{15}$ Using Neutron and X-ray Powder Diffractions

  • Ko, Tae-Gyung;Jun, Chang-Ho;Lee, Jeong-Soo
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.341-347
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    • 1999
  • An ambiguity on the correct room temperature structure of $Bi_5Ti_3FeO_{15}$ was resolved using a combined Rietveld refinement of neutron and X-ray diffraction. The structure of this compound has been reported to have a space group of F2mm (adopting 2-fold rotation symmetry along the c-axis) or A21am. However, our diffraction, study reveals that some reflections would violate F-centering and confirm that the belong to $A2_1$am. Out refinement with the space group of $A2_1$am converged at $R_p=6.85%, R_wp=9.23%$ and $\chi^2$=1.66 for an isotropic temperature model with 85 variables. The lattice constants are a=5.4677(1) $\AA$, b=5.4396(1) $\AA$, and c=41.2475(8)$\AA$. In structure, Ti/Fe atoms at the oxygen octahedral sites of the perovskite unit are completely disordered, resulting in that these atoms are transparent in neutron diffraction. The octahedra of the perovskite unit are relatively displaced along the a-axis against the Bi atoms, which contribute as a major component to the spontaneous polarization of $Bi_5Ti_3FeO_{15}$.

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A Study on the Properties of the Low Temperature Sintered Piezoelectrics for Actuator Application (압전 액츄에이터에 활용할 저온소결 압전 세라믹스에 관한 연구)

  • Ryu, Sung-Lim;Lee, Sang-Ho;Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.3
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    • pp.232-235
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    • 2008
  • In this study, in order to develop the composition ceramics for multilayer piezoelectric actuator, PMN-PNN-PZT ceramics were fabricated using $Li_2CO_3$, $Na_2CO_3$, ZnO as sintering aids and their piezoelectric and dielectric properties were investigated according to the Bi substitution, Bi substitution induced grain growth and increase of sinterablity, And also, Bi substitution suppress secondary phase due to the liquid phase sintering effect. Bi substitution enhanced electromechanical coupling factor ($k_p$) and dielectric constant ($\varepsilon_r$), However, mechanical quality factor($Q_m$) was deteriorated, At the sintering temperature of 870 $^{\circ}C$ and Bi substitution of 1 mol%, density, electromechanical coupling factor ($k_p$), mechanical quality factor ($Q_m$), Dielectric constant ($\varepsilon_r$) and piezoelectric constant ($d_{33}$) of specimen showed the optimum values of 7,878 $g/cm^3$, 0,608, 835, 1603 and 397 pC/N, respectively for multilayer piezoelectric actuator application.

Compensation of Unbalanced Phase Currents in Interleaved Bi-directional Converter with DC Link Current Sensed (직류링크 전류를 이용한 인터리브드 양방향 컨버터의 상전류 불균형 보상 방법)

  • Han, Jungho;Choi, Yuhyon;Song, Joongho
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.28 no.8
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    • pp.90-97
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    • 2014
  • This paper presents a compensation method of unbalanced phase currents in interleaved bi-directional converters. Phase currents in interleaved bi-directional converter are apt to be unbalanced due to circuit parameter error and switch operation difference. This problem causes the switch element failure and the reduced efficiency of the converter. Therefore, it is necessary that a certain balance control algorithm is provided in interleaved bi-directional converter system. In this paper, a balance control algorithm based on the circular chain control method is proposed. Further, in order to reduce the number of phase current sensors, this paper shows a simple method in which phase currents can be extracted indirectly through a DC-link current sensor in both charging and discharging modes. The validity and the effectiveness of the proposed phase currents balance control algorithm are illustrated through the simulation results.

Synthesis of Bi2WO6 Nanometer Sheet Shaped and Approach to the Photocatalysis

  • Kim, Dong-Young;Kim, Su-Jung;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.30 no.3
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    • pp.630-635
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    • 2009
  • For use as a photocatalyst, bismuth tungsten oxide, $Bi_2WO_6$, was successfully synthesized by hydrothermal treatment at pH = 11 and heating at 200 ${^{\circ}C}$ for 24h, and samples were subsequently thermal treated at 400, 600, and 800 ${^{\circ}C}$ to increase crystallinity. TEM results revealed that the initial untreated particles were sheet‐shaped, grain size was below 80 nm, and it increased with treated temperatures. These $Bi_2WO_6$ samples absorbed at around 400 nm in the visible light range and the intensity of absorption was particularly strongest in samples thermal treated at 600 ${^{\circ}C}$. Their photoluminescence abilities, related to the recombination between the excited electrons and holes, were overall small for other general photocatalysts such as TiO2, and the smallest in the case of thermal treatment at 600 ${^{\circ}C}$, as reversible result of UV‐visible absorbance. Methyl orange of 5.0 ppm aqueous solution was almost completely removed after 2 h when treated over the $Bi_2WO_6$ thermal treated at 600 ${^{\circ}C}$.

A Study on the Gravity Segregation in Monotectic Al Alloys.(I);The Effect of Melting Treatment on the Distribution of Pb, Bi Particles. (Al계 편정합금의 중력 편석에 관한 연구 (I);Pb, Bi 입자의 분산에 미치는 용탕처리의 영향)

  • Hwang, Ho-Eul;Lee, Jai-Ha;Jung, Sung-In;Choe, Jeong-Cheol;Yoon, Eui-Park
    • Journal of Korea Foundry Society
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    • v.10 no.4
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    • pp.316-323
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    • 1990
  • To improve free-cutting property, fine Pb, Bi particles is necessary to be distributed evenly in Al-Cu alloy. The control of added element size and distribution are very difficult because of the insolubility and gravity segregation of Pb, Bi in the matrix. Therefore, in this study, mechanical stirring of the melt, inert gasbubbling, the addition of degasser are used for the fine distribution of Pb, Bi particles. The best distribution are obtained by stirring with 500 rpm for 10min., Ar gas bubbling with 600cc/min for 5min. and degassing with 0.8wt% degasser. As increasing cooling rate, fine grain size and finely dispersed particles were observed. The optimum pouring temperature was $650^{\circ}C$.

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The Preparation and Growth Mechanism of the Recovered Bi2Te3 Particles with Respect to Surfactants (회수된 Bi2Te3의 계면활성제에 따른 합성 및 성장 거동)

  • So, Hyeongsub;Song, Eunpil;Choa, Yong-Ho;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.24 no.2
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    • pp.141-146
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    • 2017
  • $Bi_2Te_3$ powders are recovered by wet chemical reduction for waste n-type thermoelectric chips, and the recovered particles with different morphologies are prepared using various surfactants such as cetyltrimethylammonium bromide (CTAB), sodium dodecylbenzenesulfonate (SDBS), and ethylenediaminetetraacetic acid (EDTA). When citric acid is added as the surfactant, the shape of the aggregated particles shows no distinctive features. On the other hand, rod-shaped particles are formed in the sample with CTAB, and sheet-like particles are synthesized with the addition of SDBS. Further, particles with a tripod shape are observed when EDTA is added as the surfactant. The growth mechanism of the particle shapes depending on the surfactant is investigated, with a focus on the nucleation and growth phenomena. These results help to elucidate the intrinsic formation mechanism of the rod, plate, and tripod structures of the $Bi_2Te_3$ recovered by the wet reduction process.