• 한국자동차공학회논문집
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• 제8권4호
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• pp.141-148
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• 2000

As the steel plates used for automobile safety the TRIP-assisted multiphase steels are being introduced to automobile industry with respect to their remarkable mechanical properties for the combination of high strength and large elongation. This multiphase structure is generated by two stage heat treatment (intercritical annealing & isothermal treatment) The metastable retained austenite can be transformed to martensite when plastically deformed which results in TRIP effect. Actually the microstructure of TRIP-assisted steels consist of a fine dispersite. There present discussion deals with bainite reaction kinetics of austenite in the process o f two stage heat treatment. In relation to bainite transformation the characteristics of bainite reaction is found to be influenced by the bainite tempering temperature and also by the relative rate in which carbides precipitate within residual austenite.

• Ocean Systems Engineering
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• 제2권1호
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• pp.17-31
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• 2012

This study investigated the behavior of a non-isothermal $CO_2$ bubble formed through a leak process from a high-pressure source in a deep sea. Isenthalpic interpretation was employed to predict the state of the bubble just after the leak. Three modes of mass loss from the rising bubble were demonstrated: dissolution induced by mass transfer, condensation by heat transfer and phase separation by pressure decrease. A graphical interpretation of the last mode was provided in the pressure-enthalpy diagram. A threshold pressure (17.12 bar) was identified below which the last mode was no longer present. The second mode was as effective as the first for a bubble formed in deep water, leading to faster mass loss. To the contrary, only the first mode was active for a bubble formed in a shallow region. The third mode was insignificant for all cases.

• Food Science and Biotechnology
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• 제16권6호
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• pp.954-957
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• 2007

Gelation mechanism of xanthan-carob mixture (X/C) was investigated based on thermorheological behavior. Three X/C ratios (1:3, 1:1, and 3:1) were studied. Small amplitude oscillatory shear tests were performed to measure linear viscoelastic behavior during gelation. Temperature sweep ($-1^{\circ}C/min$) experiments were conducted. Using a non-isothermal kinetic model, activation energy (Ea) during gelation was calculated. At 1% total concentration, the Ea for xanthan fraction (${\phi}_x$)=0.25, 0.5, and 0.75 were 178, 159, and 123 kJ/mol, respectively. However, a discontinuity was observed in the activation energy plots. Based on this, two gelation mechanisms were presumed-association of xanthan and carob molecules and aggregation of polymer strands. The association process is the primary mechanism to form 3-D networks in the initial stage of gelation and the aggregation of polymer strands played a major role in the later stage.

• 청정기술
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• 제8권2호
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• pp.93-99
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• 2002

Adsorption dynamics for toluene and trichloroethylene with an isothermal fixed bed of activated carbon fiber were investigated. Equilibrium isotherms were measured by a static method for toluene and trichloroethylene onto activated carbon fiber at temperatures of 298, 323, and 348 K and pressure up to 3 kPa for toluene and 6 kPa for trichloroethylene, respectively. These results were correlated by the Toth equation. And dynamic experiments in an isothermal condition of 298 K were examined. Breakthrough curves reflected the effects of the experimental variables such as partial pressures for adsorbate and interstitial bulk velocities of gas flow. To present the column dynamics, a dynamic model based on the linear driving force (LDF) mass transfer model was applied.

• 폴리머
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• 제39권2호
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• pp.268-274
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• 2015

In this paper, the isothermal crystallization kinetics of a functional PP (FPP) with different grafting yields (GY)-methacryloxyethyltrimethyl ammonium chloride (DMC) grafted PP were investigated by differential scanning calorimetry (DSC). The results showed that the crystallization rate of FPP (GY=4.83%) was the highest for all of the studied samples. Furthermore, for the FPP with different GY, the value of $t_{1/2}$ became longer with increasing the grafting yield (GY). The possible explanation was that the quaternary ammonium groups introduced affected the crystallization process of the FPP in two opposite directions, i.e. promoting the nucleation and hindering the transport of the chain molecules towards the growing nuclei. Polarized optical micrographs showed that the DMC chains acted as nucleating agents, which accelerated the nucleation. In addition, the results showed the FPP had lower nucleation free energy than the PP. This study would be useful for designing the processing parameters of the grafted samples.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 추계학술대회 논문집
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• pp.60-63
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• 2007

The effect of process parameters on springback of AZ31B magnesium alloy sheet was investigated by performing 2D draw bending test at the elevated temperatures. And also the springback characteristics were studied different blank holding forces between 30 to 250 kgf. Springback was considerably reduced at higher temperatures than $200^{\circ}C$. The blank holding force in the range used, however, had little influence on springback in isothermal tests. For a given temperature, springback decreased with increasing blank holding force in non-isothermal tests.

• 소성∙가공
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• 제11권6호
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• pp.538-546
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• 2002

Hot deformation behavior of Udiment720Li was characterized by compression tests in the temperature range of 10$25^{\circ}C$ to 115$0^{\circ}C$ and the strain rate range of $0.0005 s^{-1};to;5 s^{-1}$. The combination of dynamic material model (DMM) and Ziegler's instability criterion was applied to predict an optimum condition and unstable regions for hot forming. A dynamic recrystallization model coupled with FEM results was used to interpret the evolution of microstructures. In order to verify the reliability of the present coupled model, isothermal forging was performed in the temperature range 1050~115$0^{\circ}C$ at strain rates of $0.05 s^{-1};and;0.005 s^{-1}$. The present model was successfully applied to the hot forming process of Udimet720Li.

• 소성∙가공
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• 제12권8호
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• pp.710-717
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• 2003

The implicit, finite element analysis program for analyzing the springback in the warm forming process of aluminum alloy sheets was developed. For the description of planar anisotropy in warm forming temperatures, Barlat's yield function is employed, and the power law type constitutive equation is used in terms of working temperatures for the depiction of work hardening in high temperatures. Also, Jetture's 4-node shell elements are introduced for reflecting the mechanical behavior of aluminum alloy sheet and the non-steady heat balance equations are solved for considering heat gain and loss during the forming process. For the springback evaluation, Newton-Raphson iteration method is introduced for overcoming the geometric nonlinearlity problem. In order to verify the validity of the FEM program developed, the stretching bending and springback processes are simulated. Though springback analysis results are slightly bigger than experimental ones, they have the same trend of the decreasing springback as the forming temperature increases.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 제4회 박판성형 심포지엄
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• pp.13-20
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• 2003

The implicit, finite element analysis program for analyzing the springback in the warm forming process of aluminum alloy sheets was developed. For the description of planar anisotropy in warm forming temperatures, Barlat's yield function is employed, and the power law type constitutive equation is used in terms of working temperatures fur the depiction of work hardening in high temperatures. Also, Jetture's 4-node shell elements are introduced for reflecting the mechanical behavior of aluminum alloy sheet and the non-steady heat balance equations are solved for considering heat gain and loss during the forming process. For the springback evaluation, Newton-Raphson iteration method is introduced for overcoming the geometric nonlinearlity problem. In order to verify the validity of the FEM program developed, the stretching bending and springback processes are simulated. Though springback analysis results are slightly bigger than experimental ones, they have the same trend of the decreasing springback as the forming temperature increases.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1329-1330
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• 2006

The effect of Cu on the hydrogen reduction of $MoO_3$ powders was investigated by measuring the humidity change during a non-isothermal process of hydrogen reduction. The presence of Cu induced a shift in the reduction temperature and strongly affected the reduction processes of $MoO_3\rightarrowMo_4O_{11}\rightarrowMoO_2$, which comprised the contained chemical vapor transport of $MoO_x(OH)_2$. This study suggests that the surface of the Cu grains acts as a nucleation site for the reduction of $MoO_x(OH)_2$ to $MoO_2$ particles from $MoO_3$ or $Mo_4O_{11}$. Such an activated reduction process results in the deposition of Mo and $MoO_2$ particles on the surface of the Cu.