• Title/Summary/Keyword: Iron sample

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Preparation of Fe-ACF/TiO2 Composites and their Photocatalytic Degradation of Waste Water

  • Oh, Won-Chun;Bae, Jang-Soon
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.667-674
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    • 2008
  • In this study, we prepared Fe-activated carbon fiber(ACF)/$TiO_2$ composites with titanium (VI) n-butoxide (TNB) as the titanium source for ACF pre-treated with iron compounds through the impregnation method. In terms of textural surface properties, the composites demonstrate a slight decrease in the BET surface area of the samples and an increase in the amount of iron compounds treated. The surface morphology of the Fe-ACF/$TiO_2$ composites was characterized by means of SEM. The composites have a porous texture with homogenous compositions of Fe and titanium dioxide distributed on the sample surfaces. The phase formation and structural transition of the iron compounds and titanium dioxide were observed in X-ray diffraction patterns of the Fe-ACF/$TiO_2$ composites. The chemical composition of the Fe-ACF/$TiO_2$ composites, which was investigated with EDX shows strong peaks for the C, O, Fe and Ti elements. The photo degradation results confirm that the Fe-ACF/$TiO_2$ composites show excellent removal activity for the COD in piggery waste due to photocatalysis of the supported $TiO_2$, radical reaction by Fe species, and the adsorptivity and absorptivity of ACF.

Effects of Austenitization and Sn Addition on Processing Window of Austempered Cast-iron (오스템퍼드 구상흑연주철의 Processing Window에 미치는 오스테나이징 조건 및 주석의 영향)

  • Kwon, M.Y.;Baek, S.H.;Yoon, D.K.;Kim, M.J.;Kim, D.J.;Kwon, H.W.;Ko, Y.G.
    • Transactions of Materials Processing
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    • v.30 no.1
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    • pp.22-26
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    • 2021
  • The present study demonstrated the effects of processing variable and alloying elements on the processing window of austempered cast iron, one of the heat-treatable cast irons, in order to elucidate the relation between heat treatment and microstructure in terms of time and temperature. Such microstructure is strongly affected by austenitizing conditions and alloying elements. The size of processing window tends to increase initially with increasing austenitizing temperature from 1123 to 1173 K, followed by a decline in the reverse direction between 1173 and 1223 K. Thus, the optimized processing window with large frame was found at an austenitizing temperature of 1173 K. To determine the effect of Sn addition, the processing window in the sample was created by the addition of 0.08 wt.% Sn, which appeared larger than that without Sn and with 0.06 wt.% Sn.

Direct and Indirect Reduction of Cr(VI) by Fermentative Fe(III)-Reducing Cellulomonas sp. Strain Cellu-2a

  • Khanal, Anamika;Hur, Hor-Gil;Fredrickson, James K.;Lee, Ji-Hoon
    • Journal of Microbiology and Biotechnology
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    • v.31 no.11
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    • pp.1519-1525
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    • 2021
  • Hexavalent chromium (Cr(VI)) is recognized to be carcinogenic and toxic and registered as a contaminant in many drinking water regulations. It occurs naturally and is also produced by industrial processes. The reduction of Cr(VI) to Cr(III) has been a central topic for chromium remediation since Cr(III) is less toxic and less mobile. In this study, fermentative Fe(III)-reducing bacterial strains (Cellu-2a, Cellu-5a, and Cellu-5b) were isolated from a groundwater sample and were phylogenetically related to species of Cellulomonas by 16S rRNA gene analysis. One selected strain, Cellu-2a showed its capacity of reduction of both soluble iron (ferric citrate) and solid iron (hydrous ferric oxide, HFO), as well as aqueous Cr(VI). The strain Cellu-2a was able to reduce 15 μM Cr(VI) directly with glucose or sucrose as a sole carbon source under the anaerobic condition and indirectly with one of the substrates and HFO in the same incubations. The heterogeneous reduction of Cr(VI) by the surface-associated reduced iron from HFO by Cellu-2a likely assisted the Cr(VI) reduction. Fermentative features such as large-scale cell growth may impose advantages on the application of bacterial Cr(VI) reduction over anaerobic respiratory reduction.

Corrosion Tests for High Chromium Cast Iron Using Galvanostatic Polarization Technique in a Simulating Slurry Solution (모사 슬러리 용액에서 정전류 분극을 활용한 고크롬 주철 부식 시험)

  • Ochgerel Baasanjav;Jun-Seob Lee;Ye-Jin Lee;Jun-Seok Oh;Je-hyun Lee
    • Corrosion Science and Technology
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    • v.22 no.4
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    • pp.252-256
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    • 2023
  • The galvanostatic polarization technique was used to accelerate corrosion in high chromium cast iron (HCCI) immersed in a simulated slurry solution of 0.1 mol dm-3 H2SO4, 0.05 mol dm-3 HCl, and 10 wt% SiC. The HCCI contained 27 wt% of Cr and 2.8 wt% of C, and its microstructure mainly comprised austenitic and carbide phases. A two-electrode system using a dense carbon rod and the HCCI sample was employed for the galvanostatic polarization by applying an anodic current for 24 hours. The corrosion rate increased upon applying the anodic current, but the increase was not significant, particularly for current densities higher than 10 µA cm-2. Following polarization, the corrosion morphology revealed that the anodic current accelerated surface corrosion in the HCCI; however while the depth of the corroded area increased, the increase was not substantial. The propagation behavior of the anodic current and its impact on corrosion were further discussed.

Formation Fe2O3 Nanowalls through Solvent-Assisted Hydrothermal Process and Their Application for Titan Yellow GR Dye Degradation

  • Ahmed, Khalid Abdelazez Mohamed
    • Journal of the Korean Chemical Society
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    • v.58 no.2
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    • pp.205-209
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    • 2014
  • Hematite iron oxide (${\alpha}$-$Fe_2O_3$) nanowalls were fabricated on aluminum substrate by a facile solvent-assisted hydrothermal oxidation process. The XRD and EDS patterns indicate that the sample has a rhombohedral phase of hematite $Fe_2O_3$. FE-SEM, TEM, HR-TEM, SA-ED were employed to characterize the resulting materials. $N_2$ adsorption-desorption isotherms was used to study a BET surface area. Their capability of catalytic degradation of titan yellow GR azo dye with air oxygen in aqueous solution over $Fe_2O_3$ catalysts was studied. The result indicates that the as-prepared product has a high catalytic activity, because it has a larger surface area. Langmuir and Freundlich isotherms of adsorption dye on the catalysts surface were investigated and the decomposition of titan yellow GR follows pseudo-first order kinetic.

A Study on Bacterial Leaching of Low-Grade Copper Mineral(IV) (저품위 동광석의 세균침출에 관한 연구 4)

  • 박원구;이강순
    • Korean Journal of Microbiology
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    • v.11 no.4
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    • pp.189-195
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    • 1973
  • With the gradual expansion of copper demands, the utilization of enormous tonnages of waste copper mineral containig up to 0.5% copper becomes available. In order to investigate the possibilities on the application of bacterial leaching method to waste dumps or abandoned mines, the authors had carried out microbial leaching of copper minerals by F.ferrooxidans isolated from the Dalsung copper mine water. The results obtained were as follows : 1. The copper extraction rate from the Dalsung chalcopyrite has been a little accerelated by using flasks in place of percolators. 2. The percentage of copper extracted from the Dalsung chalcopyrite sample was 100% in 30 days in the presence of iron-oxidizing bacteria F.ferrooxidans while 9.27% in the absence of bacteria. 3. F.ferroxidans was capable of producing sufficient quantities of ferric sulfate and sulfuric acid from ferrous iron to bring about the dissolution of 100% of copper from the Dalsung chalcopyrite.

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Polycyclic Aromatic Hydrocarbons in the sediments of Kwangyang Bay on Korea (광양만 유역 퇴적토 중의 다환방향족탄화수소류)

  • Jeong, Heung Ho;Jeong, Ho Seung;Kim, Eun Yeong;Jo, Hwan Ik;Hwang, Ju Chan;Choe, Sang Won
    • Journal of Environmental Science International
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    • v.13 no.6
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    • pp.543-549
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    • 2004
  • Polycyclic aromatic hydrocarbons(PAHs) in sediments of Kwangyang bay on Korea, have been investigated by gas chromatography-mass spectrometery (GC/MS). The average content of total PAHs in all samples was 2,211ppb, and the range was from 36 to 22,699ppb. The higher concentrations were found in sediment sampled near Kwangyang iron processing plant, Taeindo. The resulting distributions of PAHs according to the number of aromatic ring and molecular ratios of specific aromatic compounds (phenanthrene, anthracene, fluoranthene and pyrene) have been discussed in terms of sample location, origin of the organic matter. Four, five and six rings of PAHs were mainly found near to Kwangyang iron processing plant, and three and four rings near to Yeosu chemical kombinat This result typically indicated the local characteristics, depending on the origin of PAHs.

A Study on Influence of Seam Puckering by the Mechanical Properties of Polyester/Cotton Brended Fabrics (폴리에스테르/면 혼방직물의 역학특성이 Seam puckering에 미치는 영향)

  • Park, Chae-Ryun;Kim, Soon-Boon
    • Fashion & Textile Research Journal
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    • v.7 no.3
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    • pp.346-350
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    • 2005
  • In this study, to investigate the influence on the seam puckering by the mechanical properties of textiles, it was measured from 4 polyester/cotton samples. We reached the following conclusion in influences of the seam puckering by the thread, iron and laundry. Seam puckering is occurred several times by repeating the laundry. according to iron method, the seam puckering is stronger in order of T/C1> T/C2> T/C3> T/C4 by the samples and order of 40's/2> 60's/3> 50's/2> 60's/2 by the threads, the relation between sample's mechanical properties and seam strength and obtainment of formula. We can find that seam puckering is related with B, 2HB, G, 2HG5, RC, T among the mechanical properties and the estimated formulas which get from mechanical factors.

Magnetic Properties and Cation Distribution of Phosphorous-Doped $Co-{\gamma}-{Fe_2} {O_3}$ Particles

  • Na, J.G.;Han, D.H.
    • Journal of Magnetics
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    • v.1 no.1
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    • pp.51-54
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    • 1996
  • The effects of additional P-doping on the magnetic properties, thermal stability and cation distribution of Co-doped ${\gamma}-{Fe_2} {O_3}$have been investigated by means of magnetic annealing and measurements with vibration sample magnetometer and torque magnetometer. It is found that the P-doping promotes the coercivity and its magnetic-thermal stability, which may be attributed to increase of the cubic magneto-crystalline anisotropy constant, $K_1$ and the activation energy, E, for cation rearrangement, respectively. The cation distribution of P and Co-substituted iron oxide was calculated from the variation of the saturation magnetization with P-doping on the basis of the Neel model. It was found that the most of P ions in the iron oxides occupied the B-site of spinel lattice.

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Roles of Phospholipids in Flavor Stability of Soybean Oil (대두유 향미안정성에 있어서 인지방질의 역할)

  • Yoon, Suk-Hoo;Min, David-B.
    • Korean Journal of Food Science and Technology
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    • v.19 no.1
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    • pp.23-28
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    • 1987
  • The effects of phosphatidyl choline (PC), phosphatidyl ethanolamine (PE), phosphatidyl inositol (PI), phosphatidic acid (PA), phosphatidyl glycerol (PG), and cardiolipin (CL) on the flavor stability of purified soybean oil were studied. Purified soybean oil obtained from soybean oil by silicic acid chromatography does not contain measurable iron, tocopherols and phospholipids. Three hundred ppm of PC, PE, PI, PA, PG, or CL was added to the purified soybean oil, with and without 1ppm ferrous iron added. The flavor stability of sample, which was stored at $60^{\circ}C$ for 10 days in dark oven, was determined by a combination of volatile compounds formation and molecular oxygen disappearence in the headspace of air-tightly sealed serum bottle every 48 hrs. Results showed that, in general, phospholipids worked as prooxidant in the pufified soybean oil without ferrous iron added, and worked as antioxidant in the oil, when added 1ppm ferrous iron. The results also suggest that phospholipids work as prooxidant by increasing the solubility of oxygen on the surface of oil, and work as antioxidant in the oil containing 1 ppm ferrous iron by chelating iron. The results showed that PE and PA are better antioxidants than PC and PG. CL and PI showed the lest antioxidant activities in the oil will 1ppm ferrous iron added.

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