• 보존과학연구
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• s.6
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• pp.48-57
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• 1985

This report described the corrosion structure of excavated iron artifacts in terms of simple model based on the knowledge of the corrosion process. (Fig.1)(Table 1,2)In storing the objects, there are basically three ways in which they either break in wedges, flakes and dish-shaped flakes. Completely mineralized objects or those with only a small iron core tend to break into wedges and more solid objects either split small dish-shaped flakes or large flat ones.(Fig. 2,3,4)There are two ways, therefore, to prevent this from happening. One is to keep the artifacts rigorously dried in Silica-gel, never allowing the relative humidity to rise. This is feasible which the artifacts are in store but causes great difficulty if they are wanted for museum display. Because they still contain $ FeCl _2$ they are always at risk ; they contain the seeds of their own destruction. The other alternative is to use of washing process to dissolve out the $ FeCl _2$. In this connection, many different methods to stabilize the artifact have been employed; boiling iron in frequent changes of water, soaking in Na-sesquicarbonate solution, soaking in alkaline Na-sulphite solution. In this report, introduced the alkaline sulphite method by the N.A. North and C.Pearson.Finally, Let me extend my thanks to Ancient Monument Lab., Museum of London Conservation Lab., British Museum Conservation Div. and National Maritime Museum Conservation Lab. who have helped me and made many valuable suggestions.

• Journal of Korea Foundry Society
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• v.3 no.3
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• pp.174-180
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• 1983

The matrix changes and graphite formation in high manganese cast iron (Fe-12Mn-3.5C) are studied with increasing nickel and silicon content. Also, the decomposition of carbides and graphite precipitation are studied by adequate heat treatment.The results obtained in this work are as follows. 1. In high manganese cast iron, fine flakes graphite appeared by adding 5 wt% nickel and A-type flakes graphite can be obtained by adding 7 wt% nickel. 2. Nodular graphite are obtained by graphite spheroidizing treatment with same melt. 3. In high manganese cast iron containing 7 wt% nickel, full austenitic matrix with nodular graphite can be achieved by water quenching after 10 hours' solution heat treatment at $1050^{\circ}C$ in case of containing 2.0 wt% silicon, and 6 hours' at the same temperature in case of containing 2.5 wt% silicon.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1999.11a
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• pp.57-61
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• 1999

The effect of the microstructure of gray cast iron on friction properties was investigated by using a pad-on-disk type friction tester. Cast iron samples used in this investigation were obtained from "step block" castings, which were designed to produce microstructure with different graphite flake morphologies from different cooling rate and solidification rate. Results of this work showed that the gray cast iron disks with long graphite flakes showed less fading. The rotors containing smaller amounts of ferrite showed higher friction coefficient and better fade resistance than others.an others.

• Journal of the Korean Magnetics Society
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• v.14 no.5
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• pp.174-179
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• 2004

Attenuation of conduction noise through microstrip line attached with the high lossy iron flakes-rubber composites has been investigated in GHz frequencies. Microstrip line was designed with characteristic impedance of 50 $\Omega$ and a length corresponding to the center frequency of 3 GHz. Iron flakes were fabricated by mechanical forging of spherical iron powders using an attrition mill. The fabricated microstrip line shows a ideal propagation characteristics of S$\sub$11/ < -60 dB and S$\sub$21/ = 0 dB. Attaching a noise absorbing sheet on the microstrip line, S$\sub$11/ increases to about -10 dB and S$\sub$21/ decreases to -20～-60 dB depending on the length of absorbing sheet. The calculated power loss is as high as 80% in the frequency range 2～8 GHz. It is suggested that the most critical material parameter is magnetic loss for the enhancement of noise attenuation.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 1999.06a
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• pp.240-246
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• 1999

The effect of microstructure of gray cast iron disk was investigated by using a pad-on-disk type friction tester. Three different rotors with different microstructures were studied in this work. They showed a pearlitic matrix, a ferritic matrix, and a martensitic structure, respectively. All of them have graphite flakes in common. Drag tests at different pressure and speed conditions were carried out to study friction stability, temperature rise during drags. The rotor containing pearlitic matrix showed lower values of friction coefficient, small amount of temperature rise, and less fading. The results showed that gray cast iron disk containing pearlitic matrix has good friction characteristics.

• Journal of the Korean Chemical Society
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• v.7 no.1
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• pp.51-57
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• 1963

It is well known that the graphite flakes become spherulite, when a suitable amount of nodulizing element, such as cerium or magnesium, is added to the cast iron. The change of graphite from flake to nodular shape improves not only the tensile strength but the ductility as well. However, the mechanism of spheroidization of graphite in cast iron has not yet been clearly understood, and various theories proposed by a number of investigators were such that it may be due to the special nucleation effect, prevention of flake formation by the adsorption of magnesium vapour on the graphite surface or file surface free energy difference between plain graphite and magnesium-adsorbed graphite. Regardless of the speculations of spheroidizing mechanism of the graphite in the cast iron, the final phenomenon comes to the conclusion that it may be due to the lack of wettability between graphite and iron matrix. In order to collaborate this fact through an experimental method, the authors have constructed a vacuum arc furnace for the wettability measurement as its first step. Our study and experiments were then directed to the comparison of the wettability between iron and graphite on the two cases (namely, the one where magnesium was preliminarily coated on the graphite surface and the other not coated), by means of contact angle measurements. The result was such that a significant difference of the contact angles has been shown between the above two cases. indicating the spheroidization of graphite which might have resulted from the lack of wettability between magnesium-adsorbed graphite and iron matrix.

• Carbon letters
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• v.6 no.2
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• pp.101-105
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• 2005

Like bamboo-sprouts after rains, numerous sub${\mu}m$-sized pyrocarbon whiskers growth on the Mullite ($3Al_2O_3{\cdot}2H_2O$) substrate could be observed through a looking glass during methane pyrolysis at the temperature of $1050^{\circ}C$ in this study. If the surface of substrate would be scrubbed strongly with iron metals, then finely sticked iron particles were more effective catalytic for nm-sized whisker growth. Numerous fine flakes of pyrolytic carbon were hanging by invisible nm-whiskers as like as small spiders hanging by a spiderweb. This is the identification of nm-sized whisker growth. Therefore if the pyrolysis would be stopped at the initial stage of the whisker growth, the primary lengthening growth was nm-sized whisker. So could we vary arbitrarily sizes of whisker from nm- to ${\mu}m$-sizes. But ${\mu}m$- and nm-whiskers grown with the different growth mechanism; the former was straight and the latter has twigs, The lengthening growth of whisker was depended on the flow pattern pyrolysis species on the active sites of substrate and on the growth duration. We could obtained straight whisker length of 10~20 ${\mu}m$/min during the primary growth and laboratory spiral whisker of 30~40 ${\mu}m$-diameter/hr during the secondary growth.

• Journal of Korea Foundry Society
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• v.24 no.6
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• pp.323-330
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• 2004

This study aims to investigate on the effects of the microstructures on the wear characteristics of the different grey cast iron(GC) and spheroidal ductile cast iron(DCI). Wear test using wear tester of pin-on-disc type was carried out under the conditions of load 47.2N , velocity 0.2m/s, distance 4000m. At the GC, Wear rates depend on graphite type and oxide layer formed at wear surface. Weak rosette graphites are easily broken and formed wear debris over 30 ${\mu}m$. This wear debris occurs scuffing at wear surface. As a result of surface deformation, Narrow regions of the matrix between the graphite flakes and the contact surface lead to the failure of the necks. Wear rate for the DCI depended on hardness of matrix more than size of graphite.

• Journal of the Korean Society for Heat Treatment
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• v.8 no.3
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• pp.169-181
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• 1995

This study has been performed to investigate some effects of the power density and traverse speed of laser beam on the optical microstructure, hardness and fatigue resistance of gray cast iron treated by laser surface hardening technique. Optical micrograph has shown that the dissolution of graphite flakes and the coarsening of lath martensite tend to increase with a small amount of retained austenite as the power density increases under the condition of a given traverse speed. Hardness measurements have revealed that as the power density increases, hardness values of outermost surface layer increases from Hv=620 to Hv=647 in case of traverse speed of 2.0m/min at gray cast iron. Fatigue test has exhibited that the fatigue strength of laser surface hardened specimen is superier compared to that of untreated specimen, showing that values for the fatigue strength at $N_f=10^7$ of gray cast iron laser-surface-hardened at a low power density of $4076w/cm^2$ and a high power density of $8153w/cm^2$ under the condition of a given traverse speed of 2.0m/min are $15kg_f/mm^2$ and $20kg_f/mm^2$, respectively, whereas the fatigue strength of untreated specimen is $11kg_f/mm^2$. Under high stress-low cycle condition a noraml brittleness fracture appears, whereas a ductile fracture with beach mark is observed in the specimen tested under low stress-high cycle condition.

• Proceedings of the Mineralogical Society of Korea Conference
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• 2003.05a
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• pp.66-66
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• 2003

King George island, Antarctica, is mostly covered by ice sheet and glaciers, but the land area is focally exposed for several thousand years after deglaciation. For a mineralogical study of chemical weathering in the polar environment, glacial debris was sampled at the well-developed patterned ground which was formed by long periglaclal process. As fresh equivalents, recently exposed tills were sampled at the base of ice cliff of outlet glaciers and at the melting margin of ice cap together with fresh bedrock samples. Fresh tills are mostly composed of quartz, plagioclase, chlorite, and illite, but those derived from hydrothermal alteration zone contain smectite and illite-smectite. In bedrocks, chlorite was the major clay minerals in most samples with minor illite near hydrothermal alteration zone and interstratified chlorite-smectite in some samples. Smectite closely associated with eolian volcanic glass was assigned to alteration in their source region. Blocks with rough surface due to chemical disintegration showed weathering rinds of several millimeter thick. Comparision between inner fresh and outer altered zones did not show notable change in clay mineralogy except dissolution of calcite and some plagioclase. Most significant weathering was observed in the biotite flakes, eolian volcanic glass, sulfides, and carbonates in the debris. Biotite flakes derived from granodiorite were altered to hydrobiotite and vermiculite of yellow brown color. Minor epitactic kaolinite and gibbsite were formed in the cleaved flakes of weathered biotite. Pyrite was replaced by iron oxides. Calcite was congruently dissolved. Volcanic glass of basaltic andesite composition showed alteration rim of several micrometer thick or completely dissolved leaving mesh of plagioclase laths. In the alteration rim, Si, Na, Mg, and Ca were depleted, whereas Al, Ti, and Fe were relatively enriched. Mineralization of lichen and moss debris is of much interest. They are rich of A3 and Si roughly in the ratio of 2:1 to 3:1 typical of allophane. In some case, Fe and Ti are enriched in addition to Al and Si. Transmission electron microscopy of the samples rich of volcanic glass showed abundant amorphous aluminosilicates, which are interpreted as allophane. Chemical weathering in the King George Island is dominated by the leaching of primary phyllosilicates, carbonates, eolian volcanic glass, and minor sulfides. Authigenesls of clay minerals is less active. Absence of a positive evidence of significant authigenic smectite formation suggests that its contribution to the clay mineralogy of marine sediments are doubtful even near the maritime Antarctica undergoing a more rapid and intenser chemical weathering under more humid and milder climate.