• Title/Summary/Keyword: Ion-Migration

검색결과 191건 처리시간 0.03초

Research on chloride ion diffusivity of concrete subjected to CO2 environment

  • Zhang, Shiping;Zhao, Binghua
    • Computers and Concrete
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    • 제10권3호
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    • pp.219-229
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    • 2012
  • Carbonation is a widespread degradation of concrete and may be coupled with more severe degradations. An experimental investigation was carried out to study the effect of carbonation on chloride ion diffusion of concrete. The characteristic of concrete after carbonation was measured, such as carbonation depth, strength and pore structure. Results indicated that carbonation depth has a good linear relation with square root of carbonate time, and carbonation can improve compressive strength, but lower flexural strength. Results about pore structure of concrete before and after carbonation have shown that carbonation could cause a redistribution of the pore sizes and increase the proportion of small pores. It also can decrease porosities, most probable pore size and average pore diameters. Chloride ion diffusion of concrete after carbonation was studied through natural diffusion method and steady state migration testing method respectively. It is supposed that the chloride ion concentration of carbonation region is higher than that of the sound region because of the separation of fixed salts, and chloride ion diffusion coefficient was increased due to carbonation action evidently.

벤토나이트에 첨가한 은 이온에 의한 아이오딘 이동 저지 메커니즘 규명을 위한 X-선 흡수 스펙트라 분석 (X-ray Absorption Spectra Analysis for the Investigation of the Retardation Mechanism of Iodine Migration by the Silver Ion Added to Bentonite)

  • 김승수;김민규;백민훈;최종원
    • 방사성폐기물학회지
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    • 제8권3호
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    • pp.201-205
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    • 2010
  • 고준위방사성폐기물에서 유출되어 나오는 아이오딘의 이동을 저지하기 위하여 은을 흡착시킨 벤토나이트 블록에 NaI 용액을 흘려주었을 때 대부분의 아이오딘이 흡착되었다. 이 은이온에 의한 아이오딘의 저지 메커니즘을 상세히 조사하기 위하여 아이오딘과 접촉하기 전후의 은이 흡착된 벤토나이트의 X-ray Absorption Near Edge Structure (XANES)와 Extended X-ray Absorption Fine Structure (EXAFS) 스펙트 럼과 표준물질로서 AgO, $Ag_2O$, AgI의 스펙트럼을 비교하였다. 그 결과, 벤토나이트에 흡착되었던 은이 떨어져 나와 AgI 침전 클러스터를 형성함으로서 아이오딘의 이동이 지연되는 것으로 생각된다.

Performance of self-compacting concrete with manufactured crushed sand

  • Benyamina, Smain;Menadi, Belkacem;Bernard, Siham Kamali;Kenai, Said
    • Advances in concrete construction
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    • 제7권2호
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    • pp.87-96
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    • 2019
  • Self-compacting concretes (SCC) are highly fluid concrete which can flow without any vibration. Their composition requires a large quantity of fines to limit the risk of bleeding and segregation. The use of crushed sand rich in limestone fines could be an adequate solution for both economic and environmental reasons. This paper investigates the influence of quarry limestone fines from manufactured crushed sand on rheological, mechanical and durability properties of SCC. For this purpose, five mixtures of SCC with different limestone fines content as substitution of crushed sand (0, 5, 10, 15 and 20%) were prepared at constant water-to-cement ratio of 0.40 and $490kg/m^3$ of cement content. Fresh SCC mixtures were tested by slump flow test, V-funnel flow time test, L-box height ratio, segregation resistance and rheological test using a rheometer. Compressive and flexural strengths of SCC mixtures were evaluated at 28 days. Regarding durability properties, total porosity, capillary water absorption and chloride-ion migration were studied at 180 days. For the two test modes in fresh state, the results indicated compatibility between slump flow/yield stress (${\tau}_0$) and V-funnel flow time/plastic viscosity (${\mu}$). Increasing the substitution level of limestone fines in SCC mixtures, contributes to the decrease of the slump flow and the yield stress. All SCC mixtures investigated achieved adequate filling, adequate passing ability and exhibit no segregation. Moreover, the inclusion of limestone fines as crushed sand substitution reduces the capillary water absorption, chloride-ion migration and consequently enhances the durability performance.

금속 마이그레이션에 의한 화재 위험성 연구 (A Study on Fire Hazard by Metallic Migration)

  • 최경원;현병수;김선재;임규영;우승우;이동규;조영진;박종택;고재모;박남규
    • 한국화재소방학회논문지
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    • 제33권6호
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    • pp.114-119
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    • 2019
  • 우리는 LED등기구의 Printed circuit board (PCB)에서 화재의 원인으로 특정할 수 있는 금속 마이그레이션(Metallic migration) 현상을 발견하고, 본 연구를 진행하였다. 금속 마이그레이션 현상 가속화 실험인 물방울 시험을 소량의 물과 저전압(3 V)로 진행하고 절연되어있는 양극에서 직접적으로 금속 마이그레이션의 성장과 회로의 단락을 확인하였다. 그리고 전자주사현미경(SEM)을 통해 형태를 관찰하고 에너지 분산형 분광기(EDS)를 이용하여 성분을 분석한 결과, 절연된 부분에서 전극을 이루고 있는 구리의 성분을 검출하였다.

A multi-phase model for predicting the effective chloride migration coefficient of ITZ in cement-based materials

  • Yang, C.C.;Weng, S.H.
    • Advances in concrete construction
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    • 제1권3호
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    • pp.239-252
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    • 2013
  • Mortar microstructure is considered as a three-phase composite material, which is cement paste, fine aggregate and interfacial transition zone. Interfacial transition zone is the weakest link between the cement paste and fine aggregate, so it has a significant role to determine the properties of cementitious composites. In this study, specimens (w/c = 0.35, 0.45, 0.55) with various volume fractions of fine aggregate ($V_f$ = 0, 0.1, 0.2, 0.3 and 0.4) were cast and tested. To predict the equivalent migration coefficient ($M_e$) and migration coefficient of interfacial transition zone ($M_{itz}$), double-inclusion method and Mori-Tanaka theory were used to estimate. There are two stages to estimate and calculate the thickness of interfacial transition zone (h) and migration coefficient of interfacial transition zone ($M_{itz}$). The first stage, the data of experimental chloride ion migration coefficient ($M_s$) was used to calculate the equivalent migration coefficient of fine aggregate with interfacial transition zone ($M_e$) by Mori-Tanaka theory. The second stage, the thickness of interfacial transition zone (h) and migration coefficient of interfacial transition zone ($M_{itz}$) was calculated by Hori and Nemat-Nasser's double inclusion model. Between the theoretical and experimental data a comparison was conducted to investigate the behavior of interfacial transition zone in mortar and the effect of interfacial transition zone on the chloride migration coefficient, the results indicated that the numerical simulations is derived to the $M_{itz}/M_m$ ratio is 2.11~8.28. Additionally, thickness of interfacial transition zone is predicted from $10{\mu}m$, 60 to $80{\mu}m$, 70 to $100{\mu}m$ and 90 to $130{\mu}m$ for SM30, M35, M45 and M55, respectively.

이온 마이그레이션 발생에 대한 수분온도의 영향 (Effect of Water Temperature on Generation of Ion Migration)

  • 이덕보;김정현;강수근;김상도;장석원;임재훈;유동수
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제5권2호
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    • pp.261-272
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    • 2005
  • In evaluation of electronic reliability on the PCB(Printed Circuit Board), electrochemical migration is one of main test objects. The phenomenon of electrochemical migration occurs In the environment of the high humidity and the high temperature under bias through a continuous aqueous electrolyte. In this paper, the generating mechanism of electrochemical migration is investigated by using water droll acceleration test under various waters. The waters used in the water drop test are city water, distilled water and ionic water. It found that the generated velocity of electrochemical migration depended on the temperature of water and the electrolyte quantity which included in the various waters.

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다공성 매질에서의 착화하는 방사성핵종의 이동에 대한 이론적 접근 (A Theoretical Approach on the Migration of a Chelating Radionuclide in Porous Medium)

  • 백민훈;이건재
    • Journal of Radiation Protection and Research
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    • 제17권2호
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    • pp.49-59
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    • 1992
  • 이온 또는 착화된 상태의 방사성핵종의 이동에 대한 착화제의 영향을 조사하기 위하여 새로운 모델이 제시되었다. 착화된 방사성핵종의 이동거동은 착화제와 착화된 방사성핵종의 열화를 포함하는 대류-확산 이동방정식에 의해 해석되었다. 이 수학적 모델은 해석적인 방법 에 의해 구해졌으며 지연요소를 조사함으로써 분석되었다. 계산결과들은 감소된 지연요소에 의해 착화된 방사성핵종의 이동속도가 이온형태의 방사성핵종보다 매우 빠름을 보여주었다. 따라서 원자력발전소로부터의 착화제의 발생과 환경으로의 유출을 감소시킬 수 있는 새로운 구제책이 필요하다고 하겠다.

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이온 마이그레이션 발생에 대한 수분온도의 영향 (Effect of Water Temperature on Generation of Ion Migration)

  • 이덕보;김정현;강수근;김상도;장석원;임재훈;유동수
    • 한국신뢰성학회:학술대회논문집
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    • 한국신뢰성학회 2005년도 학술발표대회 논문집
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    • pp.339-348
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    • 2005
  • In evaluation of electronic reliability on the PCB(Printed Circuit Board),electrochemical migration is one of main test objects. The phenomenon of electrochemical migration occurs In the environment of the high humidity and the high temperature under bias through a continuous aqueous electrolyte. In this paper, the generating mechanism of electrochemical migration is investigated by using water drop acceleration test under various waters. The waters used in the water drop test are city water, distilled water and ionic water. It found that the generated velocity o of electrochemical migration depended on the temperature of water and the electrolyte quantity which included in the various waters.

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Effects of Electrohydrodynamic Flow and Turbulent Diffusion on Collection Efficiency of an Electrostatic Precipitator with Cavity Walls

  • 박석주;박영옥;김상수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집D
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    • pp.97-103
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    • 2001
  • The effects of the electrohydrodynamic (EHD) flow and turbulent diffusion on the collection efficiency of a model ESP composed of the plates with a cavity were studied through numerical computation. The electric field and ion space charge density were calculated by the Poisson equation of the electrical potential and the current continuity equation. The EHD flow field was solved by the continuity and momentum equations of the gas phase including the electrical body force induced by the movement of ions under the electric field. The RNG $k-{\varepsilon}$ model was used to analyze the turbulent flow. The particle concentration distribution was calculated from the convective diffusion equation of the particle phase. As the ion space charge increased, the particulate collection efficiency increased because the electrical potential increased over the entire domain in the ESP. The collection efficiency decreased and then increased, i.e. had a minimum value, as the EHD circulating flow became stronger when the electrical migration velocity of the charged particle was low. However, the collection efficiency decreased with the stronger EHD flow when the electrical migration of the particle was higher relatively. The collection efficiency of the model ESP increased as the turbulent diffusivity of the particle increased when the electrical migration velocity of the particle was low. However, the collection efficiency decreased for increasing the turbulent diffusivity when the electrical migration of the particle was higher relatively.

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