• Proceedings of the Korean Society of Tobacco Science Conference
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• 2005.10a
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• pp.35-35
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• 2005

• Proceedings of the Korean Nuclear Society Conference
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• 2005.05a
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• pp.167-168
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• 2005

• Journal of the Korean Chemical Society
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• v.6 no.2
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• pp.117-121
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• 1962

The waters throughout Taegu area for 87 points were analysed and according to the analytical data, following unfavorable characteristics for industrial uses were given: (1)Shows strong hardness, (2)Has high ratio of ignition residue to evaporation residue, (3) pH value is over 7, (4) Contains considerable quntities of iron.And then investigated the exchange rate and regeneration level of iron ion using cation exchange resin, Lewatit KS.When the hard water containing 2.2 ppm of iron with 18.4 ppm of calcium and 6.2 ppm of magnesium was passed through the ion exchange resin under $3cc/cm^2/min$ in exhaustant flow rate, exchange rate of iron reached to 42% after 300 hours flow. The exchange efficiency shows abrupt decreasing in initial stage of flow up to 100 hours flow. The exchanger which contains iron was regenerated with 10% sodium hydroxide aqua solution under SV (space velocity) 4. By this method, 57% of iron was eliminated from exchanger while calcium and magnesium are removed as much as 85% and 87% respectively.

• Bulletin of the Korean Chemical Society
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• v.25 no.1
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• pp.79-84
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• 2004

The existing technological schemes for processing rhenium-containing raw materials involve the recovery of Re from solutions, which can be effectively achieved by anion exchange method. The application of anion exchange also allows to study rhenium state in aqueous solutions and to develop analytical control methods. The present work is focused on investigation of ion exchange equilibrium in the analytical system Re(VII)-HCl-$SnCl_2$-KSCN-anion exchanger by means of sorption-desorption method as well as by electron, IR- and diffuse reflection spectroscopy. It was shown that rhenium can be quantitatively recovered from this system. It is proposed to use the sorption-spectroscopic method for Re(VII) determination in aqueous solutions. The calibration curve is linear in the concentration range of 0.5-20.0 mg/L (sample volume is 25.0 mL) and the detection limit is 0.05 mg/L. The presence of Mo(VI), Cu(II), Fe(II, III), Ni(II), Zn(II) as well as $K^+,\;Na^+$ do not hinder the solid-phase determination of rhenium. Rhenium (VII) determination by diffuse reflection spectroscopy was carried out in model solutions as well as in samples of river-derived water and in solutions obtained after the dissolution of spent catalysts.

• Polymer(Korea)
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• v.26 no.1
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• pp.1-8
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• 2002

In this study, poly(arylene ether sulfone) (PAES) having thermal stability and excellent mechanical properties was synthesized to be useful for the matrix of anion exchange resin. $1^{\circ}$-Aminated poly(arylene ether sulfone) ($1^{\circ}$-APAES) was prepared by reduction reaction after lithiation of PAES. Then $3^{\circ}$-APAES was Prepared by alkylation of the amino group of $1^{\circ}$-APAES. The structures of PAES and APAESs were confirmed with FT-IR and $^1H-NMR$ spectroscopy. Also, thermal properties of the resins were characterized by DSC and TG analysis. The introduction of amine groups in PAES resulted in the increase of glass transition temperature and decrease of initial thermal degradation temperature. The ion exchange capacities of $1^{\circ}$-APAES and $1^{\circ}$-APAES were 1.19 and 1.45 meq/g, respectively.

• Journal of Applied Biological Chemistry
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• v.43 no.1
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• pp.18-24
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• 2000

A one-dimensional transport of displacing monovalent ion, $A^+$, and a trivalent ion being displaced, $B^{3+}^ in a porous exchange system such as soil was approximated using the Crank-Nicolson implicit finite difference technique and the Thomas algorithm in tandem. The variations in the concentration profile were investigated by varying the ion-exchange equilibrium constant (k) of ion-exchange reactions, the influent concentrations, and the cation exchange capacity (CEC) of the exchanger, under constant flux condition of pore water and dispersion coefficient. A higher value of k resulted in a greater removal of the native ion, behind the sharper advancing front of displacing ion, while the magnitude of the penetration distance of $A^+$ was not great. As the CEC increased, the equivalent fraction of $B^{3+}^ initially in the soil was greater, thus indicating that a higher CEC adsorbed trivalent cations preferentially over monovalent ions. Mass balance error from simulation results was less than 1%, indicating this model accounted for instantaneous charge balance fairly well.

• Bulletin of the Korean Chemical Society
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• v.25 no.5
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• pp.711-714
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• 2004

Peroxynitrite enters erythrocytes through band 3 anion exchanger and oxidizes cytosolic proteins therein. As a protein associated with band 3, carbonic anhydrase II may suffer from peroxynitrite-induced oxidative damages. Esterase activity of carbonic anhydrase II decreased as the concentration of peroxynitrite increased. Neither hydrogen peroxide nor hypochlorite affected the enzyme activity. Inactivation of the enzyme was in parallel with the release of zinc ion, which is a component of the enzyme's active site. SDS-PAGE of peroxynitrite-treated samples showed no indication of fragmentation but non-denaturing PAGE exhibited new bands with lower positive charges. Western analysis demonstrated that nitration of tyrosine residues increased with the peroxynitrite concentration but the sites of nitration could not be determined. Instead MALDI-TOF analysis identified tryptophan-245 as a site of nitration. Such modification of tryptophan residues is responsible for the decrease in tryptophan fluorescence. These results demonstrate that peroxynitrite nitrates tyrosine and tryptophan residues of carbonic anhydrase II without causing fragmentation or dimerization. The peroxynitrite-induced inactivation of the enzyme is primarily due to the release of zinc ion in the enzyme's active site.

• YAKHAK HOEJI
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• v.45 no.1
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• pp.29-33
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• 2001

A method for the determination of anionic drug, mefenamate with ion-selective electrode using Fe(II)-1,10-phenanthroline chelate as a counter ion was developed. Benzyl nitrophenyl ether (BNPE) plasticized membrane was more selective and sensitive than the other tested membranes. This membrane electrode exhibits a linear response for 10$^{-2}$ M~5 $\times$ 10$^{-5}$ M of mefenamic acid with a slope of -61.4 mV/dec. in borate buffer solutions (pH 9.0). Potentiometric selectivity measurements revealed negligible interferences from various organic and ionorganic anions. Direct potentiometry and potentiometric titration method of mefenamic acid in capsule preparations are presented and compared.

• YAKHAK HOEJI
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• v.46 no.5
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• pp.320-323
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• 2002

A method for the determination of acidic drug, mefenamic acid and ibuprofen with ion-selective electrode(ISE) using Fe(II)-di-2-pyridyl ketone oxime complex as a counter ion were developed. Benzyl-2-nitrophenyl ether(BNPE) plasticized membrane was more selective and sensitive than the other tested membranes. The acidic drug selective electrode exhibits a linear response for 10$^{-2}$ M 510$^{-5}$ M of acidic drugs, mefenamic acid and ibuprofen with a slope of -55.9 and -56.3 mV/dec. in borate buffer solution (pH 8.9). Potentiometric selectivity measurements revealed negligible interferences from aromatic and aliphatic carboxylic acid salts. The electrodes were found to be useful for the direct determination of mefenamic acid and ibuprofen in pharmaceutical preparations.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.456-459
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• 2007

Thermal conductivities (TC) of 57 Jurassic muscovitic granite samples (KIGAM) and 149 porphyritic granite samples (Yeonki: BE-2, BE-3) were measured with LFA-447. Ranges of TC values are $2.429{\sim}3.878$ W/mK (KIGAM), $2.220{\sim}3.767$ W/mK (Yeonki, BE-2) and $2.019{\sim}3.990$ W/mK (Yeonki, BE-3); arithmetic means are 2.924 W/mK (KIGAM), 2.907 W/mK (Yeonki, BE-2), and 2.881 W/mK (Yeonki, BE-3), respectively. In this study, harmonic mean values were calculated to estimate the average value of TC. Harmonic mean values are 2.883 W/mK (KIGAM), 2.886 W/mK (Yeonki, BE-2), and 2.866 W/mK (Yeonki, BE-3), respectively. Heat extraction rates of a borehole heat exchanger strongly depend on TC values. Heat-extraction rates from re values are expected to be a little lower than 84 W/m in all sites. However, considering ground water flow, it is expected that actual heat extraction rate would be higher than the expected value.