• Title/Summary/Keyword: Ion exchanger

Search Result 159, Processing Time 0.024 seconds

The Heavy Metal Adsorption Properties of Hydroxyapatite Powders Synthesized by Precipitation Reaction Method and Its Applicability for the Removal Agents of Noxious Metallic Ions in Waste Water (침전반응법으로 합성한 수산아파타이트 분말의 중금속 흡착 특성 및 폐수중의 유해 금속 제거제로서의 유용성)

  • Lee, Mu Seong;Na, Choon Ki;Lee, Mi Suk;Kim, Oak Bae;Kim, Moon Young
    • Economic and Environmental Geology
    • /
    • v.28 no.3
    • /
    • pp.231-241
    • /
    • 1995
  • It is well known that hydroxyapatite [$Ca_{10}(PO_4)_6(OH)_2$] have an exchangeability for various heavy metal ions in aqueous solution. To evalute the feasibility of employing the synthetic hydroxyapatites as an eliminatable exchanger for environmentally noxious caions in waste water, the adsorption properties, the removal capacities and the selectivity of the apatites for various cations were investigated in more detailed. The heavy metal cations have been exchanged in calcium part of hydroxyapatite. The order of the degree of amount exchanged of the investigated cations is $Pb^{2+}>Cd^{2+}>Zn^{2+}>Ba^{2+}$. The molar ratios between released $Cd^{2+}$ ions and remeved divalent metal cations in the reacted solution with hydroxyapatite are roughly close to an integer 1.0, suggesting that an ion-exchange reaction could have played a major role in the removal of heavy metals rather then an adsorption effect. The exchangeability of the hydroxyapatite powder of Ca/P molar ratio 1.67, which have specipic surface area of $104.5m^2g^{-1}$, appeared to be better then $237.6{\mu}g$ per g for $Pb^{2+}$ ions. The removal capacity of the heavy metal ions varies directly as particle size of hydroxyapatites. All evidences obtained indicate that the synthesized hydroxyapatite powders by precipitation reaction method can be employed as an effective cation exchanger for eliminating noxious ions in waste water even in some improvemental.

  • PDF

Recent Progress in Air-Conditioning and Refrigeration Research : A Review of Papers Published in the Korean Journal of Air-Conditioning and Refrigeration Engineering in 2012 (설비공학 분야의 최근 연구 동향 : 2012년 학회지 논문에 대한 종합적 고찰)

  • Han, Hwataik;Lee, Dae-Young;Kim, Sa Ryang;Kim, Hyun-Jung;Choi, Jong Min;Park, Jun-Seok;Kim, Sumin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.25 no.6
    • /
    • pp.346-361
    • /
    • 2013
  • This article reviews the papers published in the Korean Journal of Air-Conditioning and Refrigeration Engineering during 2012. It is intended to understand the status of current research in the areas of heating, cooling, ventilation, sanitation, and indoor environments of buildings and plant facilities. The conclusions are as follows : (1) The research works on thermal and fluid engineering have been reviewed as groups of fluid machinery, pipes and valves, fuel cells and power plants, ground-coupled heat pumps, and general heat and mass transfer systems. Research issues are mainly focused on new and renewable energy systems, such as fuel cells, ocean thermal energy conversion power plants, and ground-coupled heat pump systems. (2) Research works on the heat transfer area have been reviewed in the categories of heat transfer characteristics, pool boiling and condensing heat transfer, and industrial heat exchangers. Researches on heat transfer characteristics included the results for natural convection in a square enclosure with two hot circular cylinders, non-uniform grooved tube considering tube expansion, single-tube annular baffle system, broadcasting LED light with ion wind generator, mechanical property and microstructure of SA213 P92 boiler pipe steel, and flat plate using multiple tripping wires. In the area of pool boiling and condensing heat transfer, researches on the design of a micro-channel heat exchanger for a heat pump, numerical simulation of a heat pump evaporator considering the pressure drop in the distributor and capillary tubes, critical heat flux on a thermoexcel-E enhanced surface, and the performance of a fin-and-tube condenser with non-uniform air distribution and different tube types were actively carried out. In the area of industrial heat exchangers, researches on a plate heat exchanger type dehumidifier, fin-tube heat exchanger, an electric circuit transient analogy model in a vertical closed loop ground heat exchanger, heat transfer characteristics of a double skin window for plant factory, a regenerative heat exchanger depending on its porous structure, and various types of plate heat exchangers were performed. (3) In the field of refrigeration, various studies were executed to improve refrigeration system performance, and to evaluate the applicability of alternative refrigerants and new components. Various topics were presented in the area of refrigeration cycle. Research issues mainly focused on the enhancement of the system performance. In the alternative refrigerant area, studies on CO2, R32/R152a mixture, and R1234yf were performed. Studies on the design and performance analysis of various compressors and evaporator were executed. (4) In building mechanical system research fields, twenty-nine studies were conducted to achieve effective design of mechanical systems, and also to maximize the energy efficiency of buildings. The topics of the studies included heating and cooling, HVAC system, ventilation, renewable energy systems, and lighting systems in buildings. New designs and performance tests using numerical methods and experiments provide useful information and key data, which can improve the energy efficiency of buildings. (5) In the fields of the architectural environment, studies for various purposes, such as indoor environment, building energy, and renewable energy were performed. In particular, building energy-related researches and renewable energy systems have been mainly studied, reflecting interests in global climate change, and efforts to reduce building energy consumption by government and architectural specialists. In addition, many researches have been conducted regarding indoor environments.

Recoil Effects of Neutron-Irradiated Metal Permanganates (중성자조사 금속 과망간산염의 반조효과)

  • Lee, Byung-Hun;Kim, Jung-Gwan
    • Nuclear Engineering and Technology
    • /
    • v.20 no.2
    • /
    • pp.105-111
    • /
    • 1988
  • The chemical effects resulting from the capture of the thermal neutron by manganese in various crystalline permanganates, that is, potassium permanganate ammonium permangante and barium permanganate, have been investigated. The effect of pH of solvent on the distribution of radioactive manganese chemical species, that is, cationic $^{56}$ Mn, $^{56}$ MnO$_2$ and $^{56}$ MnO$_4$$^{[-10]}$ produced in the permanganates by $^{55}$ Mn(n, r) $^{56}$ Mn reaction was studied by using various adsorbents and ion-exchanger, that is, zeolite A-3, kaolinite, alumina, manganese dioxide and Dowex-50 The distribution of radioactive MnO$_4$$^{[-10]}$ in kaolinite and alumina has higher than that in other adsorbents and ion-exchanger at a representative pH value of 4, 7 and 9, respectively. The yield of radioactive MnO$_4$$^{[-10]}$ is higher at pH 4 End pH 9 than at pH 7. The thermal annealing behavior of recoil manganese atoms produced in the permanganates by $^{55}$ Mn(n, r) $^{56}$ Mn reaction was also studied. The retention of MnO$_4$$^{[-10]}$ in the thermal annealing is increased as annealing temperature increases when it was treated at 10$0^{\circ}C$ and 13$0^{\circ}C$. The recoil effect of permanganates was explained by the hot zone model.

  • PDF

Preparation of Heterogeneous Bipolar Membranes Using Poly (phenylene oxide, PPO) Polyelectrolyte and Their Water Splitting Properties (Poly (phenylene oxide, PPO) 고분자 전해질을 이용한 불균질 바이폴라막 제조 및 물분해 특성)

  • Kim, In Sik;Hwang, Seong Yeon;Kang, Byung Gwan;Hwang, Taek Sung
    • Korean Chemical Engineering Research
    • /
    • v.57 no.1
    • /
    • pp.65-72
    • /
    • 2019
  • In this study, heterogeneous ion exchange membranes were prepared by casting method with various mixing ratios of PPO ion-selective solution and ion exchange resin. Then heterogeneous bipolar membranes were prepared by using this. The water content of heterogeneous cation and anion exchange membranes were 60~80% respectively, the ion exchange capacity was 2.81~3.26 meq/g, 2.31~2.74 meq/g and electrical resistances were $1.65{\sim}1.45{\Omega}{\cdot}cm^2$ and $1.55{\sim}1.05{\Omega}{\cdot}cm^2$. The tensile strength of heterogeneous bipolar membrane was lower than that of PPO resin before functionalization ($700Kg_f/cm^2$). The tensile strength of heterogeneous bipolar membrane with catalyst layer was lower than that of non-catalytic heterogeneous bipolar membrane. The water splitting voltage of the heterogeneous bipolar membrane with catalyst layer was low and stable at a minimum of 1.7~1.8 V, maximum 3.9~4.0 V, and the water splitting voltage of the non-catalytic heterogeneous bipolar membrane was constant at 3.8~4.0 V.

Studies on Atomic Absorption Spectrophotometric Analysis of Hexavalent Chromium in Waste Water by Solvent Extraction (용매 추출법에 의한 폐수중 6가크롬의 원자흡수 분광분석에 관한 연구)

  • Eung-Pyo Kim;Young-Sang Kim
    • Journal of the Korean Chemical Society
    • /
    • v.30 no.5
    • /
    • pp.423-432
    • /
    • 1986
  • Atomic absorption spectrophotometric (AAS) determination of hexavalent chromium [Cr(VI)] in a waste water was studied. Cr(VI) was extracted with p-xylene from the wastewater, in the way of ion pair formation with anion exchanger aliquat-336(tri-caprylmethyl ammonium chloride). 100ml waste water, after organic materials were extracted out with toluene, was acidified with conc. HCl adjusting the medium to pH 0.5 and 20ml of p-xylene containing 0.01M aliguat-336 was used to extract Cr(VI) from the acidified solution. The absorbance of chromium was measured with air-acetylene flame at 357.9nm. Standard addition method was used in the determining concentration of Cr(VI) extracted. No interference has been found in the extraction of Cr(VI) by the Al(III), Fe(III) and Cr(III) ion presented. However, Fe(II) decreased the absorbance of Cr(VI), due to the fact Fe(II) reduces Cr(VI) to Cr(III). The contained organic material was removed prior to extracting process, since it may reduced the absorbance of Cr(VI). The recovery of added Cr(VI) was over 96%, which seems to be promising and the relative standard deviation was 3.95%

  • PDF

Determination of Mefenamic Acid with Fe(II)-Dipyridyl-Mefenamic Acid Ternary Complex as Ion-exchagner (철-디피리딜-메페남산 삼원착물을 이용한 메페남산의 정량)

  • Nam, Su Ja;Moon, Hyun Sook;Lee, Mi Na;Jung, Moon Mo;Hur, Moon Hye;Ahn, Moon Kyu
    • Analytical Science and Technology
    • /
    • v.14 no.1
    • /
    • pp.59-63
    • /
    • 2001
  • A PVC membrane electrodes based on Fe(II)-dipyridyl-mefenamic acid ternary complex as ion exchanger were prepared using o-nitrophenyl octyl ether as a plasticizer. The 2,2'-dipyridyl, 4,4'-dipyridyl and 4,4'-dipyridyl-2,2'-dipyridyl were used as dipyridyl derivative ligand. The electrode dxhibits a fast stable and linear response for $10^{-5}-10^{-3}mol/L$ mefenamate with an anionic slope of -55.98, -49.47, -59.35mV/decade in pH 8.9 borate buffer solution respectively. Potentiometric selectivity measurements revealed negligible interferences from aromatic and aliphatic carboxylic acid salts.

  • PDF

Synthesis of High Functionalized Anion Exchange Fibers Using Hybrid Polyolefine by $\gamma-Ray$ Mutual Radiation (방사선 동시조사법을 이용한 고관능성 Hybrid Polyolefine 음이온교환섬유의 합성)

  • Cho In-Hee;Kwak Noh-Seok;Kang Phil-Hyun;Nho Young-Chang;Hwang Taek-Sung
    • Polymer(Korea)
    • /
    • v.30 no.3
    • /
    • pp.217-223
    • /
    • 2006
  • Ion exchange fibers, high functionalized onto hybrid polyolefine fiber's surface, were synthesized by $\gamma-ray$ mutual radiation. Degree of grafting (DG) of copolymer increased with increasing GMA monomer concentration and the maximum rate of DG was 355% at 50 GMA. The graft reaction occurred in polar solvent and DG was 190% maximum value in $1.0\times10^{-3}$ Mohr's salt and 0.1 M sulfuric acid, respectively. The amination for graft copolymers varied depending on amine reagents, and the reactivity for copolymers was highest for methylamine, and that of triethylamine lowest. It was shown that water uptake and ion exchange capacities increased with increase in the rate of amination while surface area decreased rapidly as proceeding for graft reaction and amination.

Preparation of Solid Polymer Electrolytes of PSf-co-PPSS/Heterooolyacid [HPA] Composite Membrane for Hydrogen Production via Water Elecrolysis (PSf-co-PPSS/HPA를 이용한 수소제조 수전해용 고체 고분자 전해질 복합 막의 제조)

  • Jung, Yun-Kyo;Lee, Hyuck-Jae;Jang, In-Young;Hwang, Gab-Jin;Bae, Ki-Kwang;Sim, Kyu-Sung;Kang, An-Soo
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.16 no.2
    • /
    • pp.103-110
    • /
    • 2005
  • Proton conducting solid polymer electrolyte (SPE) membranes have been used in many energy technological applications such as water electolysis, fuel cells, redox-flow battery, and other electrochemical devices. The availability of stable membranes with good electrochemical characteristics as proton conductivity at high temperatures above 80 $^{\circ}C$ and low cost are very important for its applications. However, the presently available perfluorinated ionomers are not applicable because of high manufacturing cost and high temperature use to the decrease in the proton conductivity and mechanical strength. In order to make up for the weak points, the block copolymer (BPSf) of polysulfone and poly (phenylene sulfide sulfone) were synthesized and sulfonated. The electrolyte membranes were prepared with phosphotungstic acid (HPA)/sulfonated BPSf via solution blending. This study would be desirable to investigate the interaction between the HPA and sulfonated polysulfone. The results showed that the characteristics of SPSf/HPA blend membrane was a better than Nafion at high temperature, 100 $^{\circ}C$. These membranes proved to have a high proton conductivity, $6.29{\times}10-2$ S/cm, a water content, 23.9%, and a ion exchange capacity, 1.97 meq./g dry membrane. Moreover, some of the membranes kept their high thermal and mechanical stability.

A Study on the Release Characteristics of VOCs from Heat Recovery Ventilation System (폐열회수형 환기장치의 휘발성유기화함물 배출 특성에 관한 연구)

  • Kwak, Kyung-Min;Bai, Cheol-Ho;Kim, Jee-Yong;Chu, Euy-Sung
    • Clean Technology
    • /
    • v.13 no.4
    • /
    • pp.281-286
    • /
    • 2007
  • VOCs from the heat recovery ventilation system (total heat exchanger) are measured in this study. Two different types of element (L and M type) from heat recovery ventilating system are tested to study the intial release characteristics of VOCs under KS cooling and heating standard conditions. VOCs are measured for the various flow rates and different operating times. Considering errors in the test method and the measuring instrument, the tested heat recovery ventilating systems was found to release 6 major VOCs, such as acetic acid, 2-butanone (MEK), 2-(methylthio )ethylamine, toluene, styrene, and x-acids (Ion 57). The concentrations of released VOCs are not quite much affected by operating conditions. The results show much larger VOCs concentrations in the cooling mode than in the heating mode, due to the high operating temperatures.

  • PDF

Synthesis of Chelating Adsorbent (2,2'-Iminodibenzoic Acid-crosslinked Chitosan) and Adsorptivity of Pb(II), Cu(II), Cd(II) (킬레이트 흡착제(2,2'-Iminodibenzoic acid-가교 chitosan)의 합성과 Pb(II), Cu(II), Cd(II)의 흡착력에 관한 연구)

  • Shim, Sang-Kyun;Ryu, Jae-Jun
    • Analytical Science and Technology
    • /
    • v.11 no.6
    • /
    • pp.452-459
    • /
    • 1998
  • Crosslinked chitin was prepared from epichlorohydrin and chitin which was isolated from waste marin source. The crosslinked chitosan were prepared by the deacetylation of the crosslinked chitin with a strong base. 2,2'-Iminodibenzoic acid-crosslinked chitosan was prepared by reacting 2,2'-Iminodibenzoic acid salt with crosslinked chitosan-Cl which was obtained by chlorination of crosslinked chitosan. The adsorptivity of Pb(II), Cu(II), Cd(II) was studied as a synthetic adsorbent. Experimental results for the adsorption and the recovery characteristics showed that the more pH increase, the more amount of adsorbed metal ion increase. Optimum adsorption time was 1 hr, and adsorption capacity was increased in order of $Cu^{2+}$<$Cd^{2+}$<$Pb^{2+}$, and recovery capacity was increased in order of $Cd^{2+}$<$Cu^{2+}$<$Pb^{2+}$.

  • PDF