• Title/Summary/Keyword: Ion balance method

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Interpretation of Analytical Data of Ion Components in Precipitation, Seoul (서울 地域 降水中 이온成分 分析資料의 解析)

  • 강공언;이주희;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.3
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    • pp.323-332
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    • 1996
  • Precipitation samples were collected by the wet-only sampling method at Seoul from September 1993 to June 1995. Sample were analysed for the anions $(NO_3^-, NO_2^-, SO_4^{2-}, Cl^-, and F^-)$ and cations $(Na^+, K^+, Ca^{2+}, Mg^{2+}, and NH_4^+)$ in addition to pH and electric conductivity. In order to establish the chemical analysis data of high quality, the assurance checks for analytical data of precipitation were performed by considering the ion balance and by comparing the measured conductivity with the calculated conductivity. As we applied the various assurance checking methods by the ion balance used until recently to a data set measured in this study, the f value expressed as $\Sigma C/\Sigma A$ was found to be not appropriate for the data screening. Also, the scattering plot between cations and anions in each sample was found to show the general tendency of ion balance but was proved to not quantitate the standard of data screening at a data set of samples of various concentration levels. The h value defined as (A-C)/C for C $\geq$ A and (A-C)/A for C < A was used to check the ion balance. However, the standard of data screening by h value must very in response to total ion concentration of samples. In this study, the quality assurance of chemical analysis data was checked by considering both the ion balance of evaluating by h value and the conductivity balance. Further the quality control was achieved by these quality assurance methods. As the result, 67 samples among total 77 were obtained as valid. As the central tendency value for a statistical summary in the analytical parametr of samples, the volume-weighted mean value was found to represent more the general chemistry of precipitation rather than the arithmetic mean. The volume-weighted mean pH was 5.0 and 25% of samples was less than this mean. The concentrations of sufate and nitrate in precipitation were 90.4 ueq/L and 32.4 ueq/L which made up 59% and 21% of all anions. The raion of $SO_4^{2-}/(NO_3^- + NO_2^-)$ in precipitation was 2.7, which indicates that the contributions of $H_2SO_4$ and $HNO_3$ to the acidity of precipitation are 70% and 30%, respectively.

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Management of Spent Ion-Exchange Resins From Nuclear Power Plant by Blending Method

  • Kamaruzaman, Nursaidatul Syafadillah;Kessel, David S.;Kim, Chang-Lak
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.65-82
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    • 2018
  • With the significant increase in spent ion-exchange resin generation, to meet the requirements of Waste Acceptance Criteria (WAC) of the Wolsong disposal facility in Korea, blending is considered as a method for enhancing disposal options for intermediate level waste from nuclear reactors. A mass balance formula approach was used to enable blending process with an appropriate mixing ratio. As a result, it is estimated around 44.3% of high activity spent resins can be blended with the overall volume of low activity spent resins at a 1:7.18 conservative blending ratio. In contrast, the reduction of high activity spent resins is considered a positive solution in reducing the amount of spent resins stored. In an economic study, the blending process has been proven to lower the disposal cost by 10% compared to current APR1400 treatment. Prior to commencing use of this blending method in Korea, coordinated discussion, and safety and health assessment should be undertaken to investigate the feasibility of fitting this blending method to national policy as a means of waste predisposal processing and management in the future.

Adaptive State-of-Charge Estimation Method for an Aeronautical Lithium-ion Battery Pack Based on a Reduced Particle-unscented Kalman Filter

  • Wang, Shun-Li;Yu, Chun-Mei;Fernandez, Carlos;Chen, Ming-Jie;Li, Gui-Lin;Liu, Xiao-Han
    • Journal of Power Electronics
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    • v.18 no.4
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    • pp.1127-1139
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    • 2018
  • A reduced particle-unscented Kalman filter estimation method, along with a splice-equivalent circuit model, is proposed for the state-of-charge estimation of an aeronautical lithium-ion battery pack. The linearization treatment is not required in this method and only a few sigma data points are used, which reduce the computational requirement of state-of-charge estimation. This method also improves the estimation covariance properties by introducing the equilibrium parameter state of balance for the aeronautical lithium-ion battery pack. In addition, the estimation performance is validated by the experimental results. The proposed state-of-charge estimation method exhibits a root-mean-square error value of 1.42% and a mean error value of 4.96%. This method is insensitive to the parameter variation of the splice-equivalent circuit model, and thus, it plays an important role in the popularization and application of the aeronautical lithium-ion battery pack.

Effect of Cathode/anode Weight Ratio in $LiCoO_2/MPCF$ Cell ($LiCoO_2/MPCF$전지에서 정$\cdot$부극 중량비의 영향)

  • Kim Sang-Pil;Cho Jeong-Soo;Kim Hee-Je;Park Jeong-Hu;Yun Mun-Soo
    • Journal of the Korean Electrochemical Society
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    • v.2 no.2
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    • pp.75-80
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    • 1999
  • Li-ion cells employ lithium transtion metal oxide as the cathode material and carbon as anode material. To manufacture Li-ion cell with higher capacity and better cycle life, the utilization of electrode materials should be as high as possible without lithium deposition onto the carbon surface during charging. A careful design of cell balance between cathode and anode materials as well as a proper charge method is a key factor to design Li-ion cell with long cycle life. In this study, we investigated the effect of cathode/anode weight ratio on the performance of $LiCoO_2/MPCF$ cell. First we evaluated the charge-discharge behaviours of half-cells. And cylindrical Li-ion cells were fabricated using graphitized MPCF anode and $LiCoO_2$ cathode. The voltage profiles for each half-cell in $LiCoO_2/MPCF$ cell were measured by using lithium metal as a reference electrode. Also, we evaluated the cyclic performance of $LiCoO_2/MPCF$ cells according to weight ratio. From the result of experiment $LiCoO_2$ cathode utilization was independent of weight ratio, but MPCF anode utilization was dependant on weight ratio. Also, the optimal weight ratio of $LiCoO_2/MPCF$ cell was found to be $2.0\~2.2$.

A Study on Neutral Atom Heating in Inductively Coupled Plasma

  • Seo, Byeong-Hun;Yu, Sin-Jae;Kim, Jeong-Hyeong;Seong, Dae-Jin;Jang, Hong-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.178-178
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    • 2012
  • Neutral atom temperature was measured by Laser Rayleigh scattering method using neutral depletion by neutral heating with ideal gas law in Inductively coupled plasma. We observed sudden pressure change when plasma is turned on and off. We analyzed mechanism of neutral heating by employing zero-dimensional neutral and ion energy balance model simultaneously. The results showed that neutral atom temperature increase with ion density. The mechanism of neutral atom heating and cooling is mainly dominated by ion-neutral collision including elastic and charge-exchange collision and by wall cooling respectively.

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Charge Equalization Converter with Parallel Primary Winding for Series Connected Lithium-Ion Battery strings (트랜스포머 1차측 병렬 구조를 가진 직렬 연결 리튬이온 배터리 전하 균일 컨버터)

  • Kim, Chol-Ho;Park, Hong-Sun;Kim, Chong-Eun;Moon, Gun-Woo;Lee, Joong-Hui
    • Proceedings of the KIPE Conference
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    • 2007.07a
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    • pp.256-258
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    • 2007
  • A charge equalization converter with parallel-connected primary windings of transformers is proposed in digest. The proposed work effectively balance the voltage among Lithium-Ion battery cells despite each battery cell has low voltage gap compared with its SOC. The principle of the proposed work is that the equalizing energy from all battery strings moves to the lowest voltage battery through the isolated dc/dc converter controlled by the corresponding bi-directional switch. In this digest, a prototype of four Lithium-Ion battery cells is optimally designed and implemented, and experimental results show that the proposed method has excellent cell balancing performance.

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Water Soluble Ionic Components in Precipitation at ChungNam West-Coast Area (충남 서해안지역 강수 중 수용성 이온 성분의 변화특성)

  • 정진도;이천호
    • Journal of Environmental Science International
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    • v.12 no.12
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    • pp.1285-1292
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    • 2003
  • This study was compared each ingredient's local/seasonal change characteristics by analyzing anions and cations, watersoluble ionic components, from the precipitation of Dangjin and Anmyeon-do areas. The samples were collected for 8 months from both spots between the period of April 1, 2002 to November 31, 2002. The precipitation samples were collected continuously through the entire duration of precipitation by using the wet-only automatic samplers. When rain continues to fall over 24 hours or occasionally, we considered those collected from 9 o'clock in the morning for 24 hours as the day's samples. As a method to verify for the reliability of the analyzed data is concerned, we use the ion balance method and the electricity conductance method, was used widely as a way of watching the atmosphere by the WMO(World Meteorological Organization)/GAW (Global Atmosphere Watch). Also, Dangjin and Anmyun-do area confirmed that contains artificial pollutants by analysis of ion concentration data.

Development of a Fast Charging System Utilizing Charge Profile and Cell Balance Control Technology for Large Capacity Lithium-ion Batteries (충전 프로파일 및 셀 밸런스 제어기술을 활용한 대용량 리튬이온 배터리 고속충전시스템 개발)

  • Yunana, Gani Dogara;Ahn, Jae Young;Park, Chan Won
    • Journal of Industrial Technology
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    • v.40 no.1
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    • pp.7-12
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    • 2020
  • Lithium-ion cells have become the go-to energy source across all applications; however, dendritic growth remains an issue to tackle. While there have been various research conducted and possible solutions offered, there is yet to be one that efficiently rules out the problem without, however, introducing another. This paper seeks to present a fast charging method and system to which lithium-ion batteries are charged while maintaining their lifetime. In the proposed method, various lithium cells are charged under multiple profiles. The parameters of charge profiles that inflict damage to the cell's electrodes are obtained and used as thresholds. Thus, during charging, voltage, current, and temperature are actively controlled under these thresholds. In this way, dendrite formation suppressed charging is achieved, and battery life is maintained. The fast-charging system designed, comprises of a 1.5kW charger, an inbuilt 600W battery pack, and an intelligent BMS with cell balancing technology. The system was also designed to respond to the aging of the battery to provide adequate threshold values. Among other tests conducted by KCTL, the cycle test result showed a capacity drop of only 0.68% after 500 cycles, thereby proving the life maintaining capability of the proposed method and system.

A Study on Chemical Features of Fog Sample in Summer at Mt. Sobaek (하계 소백산 안개의 화학적 특성에 관한 연구)

  • 최재천;이민영;이선기;남재철
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.4
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    • pp.399-406
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    • 1996
  • Acidic fog is catastrophic to aviation and potentially affect materials, vegetation, crops and public health. This paper was carried out to investigate the chemical features of fog sample at Mt. Sobaek (mean sea level : 1, 340m) from June to August 1995. Each sample was analyzed for pH, electrical conductivity and major ions (anion : $Cl^N)_3^-, SO_4^{2-}, cation : Na^+, NH_4^+, K^+, Mg^{2+}, Ca^{2+}$) by ion chromatography. The quality analysis of fog sample data was performed based on ion balance and electrical conductivity method. The wind directions are subdivided into the northerly and southerly wind according to the wind direction data at the Sobaek-san meteorological observation station. Statistical analyses were performed on the complete set of results in order to obtain a description of fog sample. All the statistical treatment was carried out using the SPSS/PC + software package. The major ion concentration of fog samples was higher for the northwesterly wind cases than sourtheasterly wind cases. The pH of fog sample varied between 2.95 and 6.08. The average pH and electrical conductivity of total sample (n=210) were 4.39 and 113.0 $\mu$S/cm, respectively. It may be noted that in nearly all the cases, the dominant major ions in the fog sample at Mt. Sobaek were $SO_4^{2-}, NO_3^-, H^+ and NH_4^+$.

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