• 제목/요약/키워드: Ion Transport

검색결과 469건 처리시간 0.03초

High Performance Wearable/Flexible Energy Storage Devices Based on Ultrathin $Ni(OH)_2$ Coated ZnO Nanowires

  • Shakir, Imran;Park, Jong-Jin;Kang, Dae-Joon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.597-597
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    • 2012
  • A simple solution-based method is developed to deposit crystalline ultrathin (2 nm) nickel hydroxide on vertically grown ZnO nanowires to achieve high specific capacitance and long-term life for flexible and wearable energy storage devices. Ultrathin crystalline $Ni(OH)_2$ enables fast and reversible redox reaction to improve the specific capacitance by utilizing maximum number of active sites for the redox reaction while vertically grown ZnO nanowires on wearable textile fiber effectively transport electrolytes and shorten the ion diffusion path. Under the highly flexible state $Ni(OH)_2$ coated ZnO nanowires electrode shows a high specific capacitance of 2150 F/g (based on pristine $Ni(OH)_2$ in 1 M LiOH aqueous solution with negligible decrease in specific capacitance after 1000 cycles. The synthesized energy-storage electrodes are easy-to-assemble which can provide unprecedented design ingenuity for a variety of wearable and flexible electronic devices.

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광바이오 수소제조 시스템에서의 쏠라셀 및 나노여과 멤브레인 활용 (Use of Solar Cell and Nanofiltration Membrane for System of Enzymatic $H_2$ Production Through Light-Sensitized Photoanode)

  • 심은정;배상현;윤재경;주현규
    • 한국수소및신에너지학회논문집
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    • 제18권2호
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    • pp.151-156
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    • 2007
  • Solar cell and nanofiltration membrane were utilized in a system of enzymatic hydrogen production through light-sensitized photoanode, which resembles photoelectrochemical(PEC) configuration. Solar cell uses no additional light energy to increase energy for electrons to reduce protons and for holes to oxidize water to oxygen, and nanofiltration membrane replaces a salt bridge successfully with increased ion transport capability. With this system configuration, optimized amount of enzyme(10.98 unit), and an anodized tubular $TiO_2$ electrode($5^{\circ}C$/1 hr in 0.5 wt% HF-$650^{\circ}C$/5 hr) hydrogen evolved at a rate of ca. $43\;{\mu}mol/(cm^2{\times}hr)$ in a cathodic compartment and oxygen generated at a rate of ca. $20\;{\mu}mol/(cm^2{\times}hr)$ in an anodic compartment. The stoichiometric evolution of gases indicated that water was splitted in the system.

FEM-FCT 기법을 이용한 AC PDP 2차원 시뮬레이션에 관한 연구 (A study on 2-dimensional simulation of AC PDP using FEM-FCT method)

  • 김용진;민웅기;이석현
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 추계학술대회 논문집 학회본부 C
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    • pp.565-567
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    • 2000
  • In this paper, the discharge characteristics of AC PDP, one of the leading technologies currently under development for large-area flat displays, is computed by using Finite Element Method(FEM) combined with Flux-corrected Transport(FCT) algorithm. Up to now, many simulations of AC PDP have been mainly done by Finite Difference Method(FDM). But we simulated the AC PDP by using FEM-FCT method which discretizes the region of interest with unstructured grids. FEM-FCT method can reduce the computational cost because of refining locally where the physical quantities have steep gradients and is more efficient in solving discharge problems, such as a AC PDP. Results are presented in Ne-Xe(4%) gas mixture for a gas pressure of 400 Torr and as the discharge proceeds, the space and time variations of the electron and ion densities, potential and wall charges on the dielectric are described. Results from our simulation by FEM-FCT are similar to those from simulation by FDM and are more efficient in computational cost reduction.

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IGCC 플랜트에서 산소공급방식이 성능에 미치는 영향 (Influence of Oxygen Supply Method on the Performance of IGCC Plants)

  • 안지호;김동섭
    • 한국수소및신에너지학회논문집
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    • 제23권3호
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    • pp.264-273
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    • 2012
  • In this paper, two types of integrated gasification combined cycle (IGCC) plants using either an air separation unit (ASU) or an ion transport membrane (ITM), which provide the oxygen required in the gasification process, were simulated and their thermodynamic performance was compared. Also, the influence of adopting a pre-combustion $CO_2$ capture in the downstream of the gasification process on the performance of the two systems was examined. The system using the ITM exhibits greater net power output than the system using the ASU. However, its net plant efficiency is slightly lower because of the additional fuel consumption required to operate the ITM at an appropriate operating temperature. This efficiency comparison is based on the assumption of a moderately high purity (95%) of the oxygen generated from the ASU. However, if the oxygen purity of the ASU is to be comparable to that of the ITM, which is over 99%, the ASU based IGCC system would exhibit a lower net efficiency than the ITM based system.

Action of Mitochondrial Substrates on Neuronal Excitability in Rat Substantia Gelatinosa Neurons

  • Lee, Hae In;Chun, Sang Woo
    • International Journal of Oral Biology
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    • 제42권2호
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    • pp.55-61
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    • 2017
  • Recent studies indicate that mitochondria are an important source of reactive oxygen species (ROS) in the spinal dorsal horn. In our previous study, application of malate, a mitochondrial electron transport complex I substrate, induced a membrane depolarization, which was inhibited by pretreatment with ROS scavengers. In the present study, we used patch clamp recording in the substantia geletinosa (SG) neurons of spinal slices, to investigate the cellular mechanism of mitochondrial ROS on neuronal excitability. DNQX (an AMPA receptor antagonist) and AP5 (an NMDA receptor antagonist) decreased the malate-induced depolarization. In an external calcium free solution and addition of tetrodotoxin (TTX) for blockade of synaptic transmission, the malate-induced depolarization remained unchanged. In the presence of DNQX, AP5 and AP3 (a group I metabotropic glutamate receptor (mGluR) antagonist), glutamate depolarized the membrane potential, which was suppressed by PBN. However, oligomycin (a mitochondrial ATP synthase inhibitor) or PPADS (a P2 receptor inhibitor) did not affect the substrates-induced depolarization. These results suggest that mitochondrial substrate-induced ROS in SG neuron directly acts on the postsynaptic neuron, therefore increasing the ion influx via glutamate receptors.

다공성 매질에서의 착화하는 방사성핵종의 이동에 대한 이론적 접근 (A Theoretical Approach on the Migration of a Chelating Radionuclide in Porous Medium)

  • 백민훈;이건재
    • Journal of Radiation Protection and Research
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    • 제17권2호
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    • pp.49-59
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    • 1992
  • 이온 또는 착화된 상태의 방사성핵종의 이동에 대한 착화제의 영향을 조사하기 위하여 새로운 모델이 제시되었다. 착화된 방사성핵종의 이동거동은 착화제와 착화된 방사성핵종의 열화를 포함하는 대류-확산 이동방정식에 의해 해석되었다. 이 수학적 모델은 해석적인 방법 에 의해 구해졌으며 지연요소를 조사함으로써 분석되었다. 계산결과들은 감소된 지연요소에 의해 착화된 방사성핵종의 이동속도가 이온형태의 방사성핵종보다 매우 빠름을 보여주었다. 따라서 원자력발전소로부터의 착화제의 발생과 환경으로의 유출을 감소시킬 수 있는 새로운 구제책이 필요하다고 하겠다.

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A small-scale membrane electro-dialyser for domestic use

  • Chaalal, Omar;Hossain, Md.M.
    • Membrane and Water Treatment
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    • 제6권1호
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    • pp.43-52
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    • 2015
  • A small-scale electro-dialysis system was constructed for domestic use. It is composed of six compartments in which five special polystyrene ionic membranes are housed. A series of experiments on the transport of sodium and chloride ions through polystyrene membranes was performed and the effects of electric current and voltage on the pH of water were investigated. This electrodialyser could reduce the NaCl content to an acceptable level (5307 mg/L) when water containing 9945 mg/L of sodium chloride is fed to the electrodialyser. The reduction was by the action of direct current 60 mA/100 mA when a 15 V / 20 V potential is maintained across the membrane. The results showed that the pH of the treated water attained a value in the range of 7-8, with the chloride concentration of 5307 mg/L when the voltage was in the range of 20 volts. This was achieved when two of the small-scale electro-dialysers were placed in series and the solutions from the respective compartments were mixed. This is considered useful because this complies to the requirement of drinking water standard both in terms of chloride and pH. Therefore, this type electrodialyserhas the potential for domestic uses in isolated houses where potable water supply is not available.

부산 구덕산 미세먼지의 금속성분 및 이온성분 농도 특성 (Characteristics of Metallic and Ionic Elements Concentration in PM10 at Guducsan in Busan)

  • 전병일
    • 한국환경과학회지
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    • 제25권5호
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    • pp.715-726
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    • 2016
  • This study investigates the characteristics of metallic and ionic elements concentration, concentration according to transport path, and factor analysis in $PM_{10}$ at Guducsan in Busan in the springtime of 2015. $PM_{10}$ concentration in Guducsan and Gwaebeopdong were $59.5{\pm}9.04{\mu}g/m^3$ and $87.5{\pm}20.2{\mu}g/m^3$, respectively. Contribution rate of water-soluble ions and secondary ion in $PM_{10}$ concentration in Guducsan were 37.0% and 27.8% respectively. [$NO_3{^-}/SO{_4}^{2-}$] ratio and contribution rate of sea salt of $PM_{10}$ in Guducsan and Gwaebeopdong were 0.91 and 1.12, 7.0% and 5.3%, respectively. The results of the backward trajectory analysis indicates that $PM_{10}$ concentration, total inorganic water-soluble ions and total secondary ions were high when the air parcels moved from Sandong region in China than non-Sandong and northen China to Busan area. The results of the factor analysis at Guducsan indicates that factor 1 was anthropogenic source effects such as automobile emissions and industrial combustion processes, factor 2 was marine sources such as sea salts from sea, and factor 3 was soil component sources.

탄소 나노튜브 채널을 이용한 전계효과 이온-전송 소자 연구 (A Study of Carbon Nanotube Channel Field-Effect Devices)

  • 이준하;이흥주
    • 한국산학기술학회논문지
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    • 제7권2호
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    • pp.168-174
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    • 2006
  • 본 연구는 분자동력학 시뮬레이션을 이용하여 탄소 나노튜브를 이용한 전계효과 이온-전송 소자를 분석하였다. 외부 전기장에 의해 단전자 전계효과 트랜지스터 및 나노크기의 데이터 저장 장치로 활용될 수 있는 원리를 규명하였다. 외부 전기장이 증가할수록 칼륨 원자는 채널을 빠르게 통과하였다. 낮은 외부 전계에서는 나노채널의 열적 파동이 칼륨 원자의 터널링에 영향을 주게 됨을 해석하였다. 이로서 외부 전계의 강도에 따라 칼륨원자의 채널을 터널링하는 효과를 제어할 수 있는 메커니즘을 도출하였다.

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Microflow of dilute colloidal suspension in narrow channel of microfluidic-chip under Newtonian fluid slip condition

  • Chun Myung-Suk;Lee Tae Seok;Lee Kangtaek
    • Korea-Australia Rheology Journal
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    • 제17권4호
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    • pp.207-215
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    • 2005
  • We present a finite difference solution for electrokinetic flow in rectangular microchannels encompassing Navier's fluid slip phenomena. The externally applied body force originated from between the nonlinear Poisson-Boltzmann field around the channel wall and the flow-induced electric field is employed in the equation of motion. The basic principle of net current conservation is applied in the ion transport. The effects of the slip length and the long-range repulsion upon the velocity profile are examined in conjunction with the friction factor. It is evident that the fluid slip counteracts the effect by the electric double layer and induces a larger flow rate. Particle streak imaging by fluorescent microscope and the data processing method developed ourselves are applied to straight channel designed to allow for flow visualization of dilute latex colloids underlying the condition of simple fluid. The reliability of the velocity profile determined by the flow imaging is justified by comparing with the finite difference solution. We recognized the behavior of fluid slip in velocity profiles at the hydrophobic surface of polydimethylsiloxane wall, from which the slip length was evaluated for different conditions.