• Title/Summary/Keyword: Ion Size

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Removal of Pb(II) and Cd(II) From Aqueous solution Using Oxidized Activated Carbons Developed From Pecan Shells.

  • Youssef, A.M.;EL-Khouly, Sahar M.;El-Nabarawy, Th.
    • Carbon letters
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    • v.9 no.1
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    • pp.8-16
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    • 2008
  • Oxidized activated carbons were prepared by reacting steam-activated carbon developed from pecan shells with nitric acid of varying strength (15, 30, 45 and 60%). The textural properties and the chemistry of the surface of the non-oxidized and of the oxidized carbons were determined from nitrogen adsorption and base neutralization capacities. The uptake of Pb(II) and Cd(II) from aqueous solution by these carbons was determined by kinetic and equilibrium experiments as well as by the column method. Treatment with nitric acid brought about drastic decrease in surface area and remarkable increase in the pore size of the carbon with these changes depending on the strength of nitric acid. Nitric acid increased the surface acidity by developing new surface oxygen functional groups of acidic nature. $HNO_3$-oxidized carbons exhibited high adsorption capacities for Pb(II) and Cd(II). The adsorption of these ions increased with the decrease of the surface pH of the carbon and with the increase of the solution pH from 2.5 to 6 and 7. The amount adsorbed from lead and cadmium was also related to the amount of surface acidity, the pH of the point of zero charge and on some metal ion parameters. Cadmium and lead uptake by the investigated carbons followed pseudo-second order model and the equilibrium sorption data fitted Langmuir adsorption model.

Dielectric and Piezoelectric Properties on Pb($Zn_{1/3}Nb_{2/3}}$)$O_3$-Pb($Ni_{1/3}Nb{2/3}$)$O_3$-PZT Ceramics (Pb($Zn_{1/3}Nb_{2/3}}$)$O_3$-Pb($Ni_{1/3}Nb{2/3}$)$O_3$-PZT계 세라믹스의 유전 및 압전특성)

  • 정형진;손정호;윤상옥
    • Journal of the Korean Ceramic Society
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    • v.27 no.6
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    • pp.713-720
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    • 1990
  • The effects of substituting Zn+2 for Ni+2 ion on dielectric and piezoelectric prooperties of Pb(Zn1/3Nb2/3)O3-Pb(Ni1/3Nb2/3)O3-PZT ceramics were investigated. With increasing Zn2+ contents the tetragonality was appreciably enhanced and the grain size decreased. Both Curie temperature and thermal stability were increased with increase in Zn2+ contents since the Zn+2 partial substition for Ni+2 could form solid solution in almost range of the composition investigated. Piezoelectric prooperties showed the maximum($\varepsilon$ T/$\varepsilon$0=5014, kp=0.56, d31=250$\times$10-12m/V) in 4.5Pb(Zn1//3Nb2/3)O3-40.5Pb(Ni1/3Nb2/3)O3-55PZT composition sintered at 125$0^{\circ}C$ and then decreased again due to the phase boundary movement for tetragonal phase of the solid solution of Zn2+ amount.

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3차원적 도핑 분포 측정을 위한 SCM 응용 방법 (The SCM Method for Three-Dimensional Dopant Profiles)

  • Lee Jun-Ha;Lee Hoong-Joo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.1
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    • pp.7-11
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    • 2006
  • Through SCM modeling, we found that the depletion layer in silicon was of a form of a spherical capacitor with the SCM tip biased. Two-dimensional (2D) finite differential method code with a successive over relaxation (SOR) solver has been developed to model the measurements by SCM of a semiconductor wafer that contains an ion-implanted impurity region. Then, we theoretically analyzed the spherical capacitor and determined the total depleted-volume charge Q, capacitance C, and the rate of capacitance change with bias dC/dV. It is very important to observe the depleted carriers' movement in the silicon layer by applying the bias to the tip. So, we calculated the depleted-volume charge, considering different factors such as tip size, oxide thickness, and applied bias (dc+ac), which have an influence on potential and depletion charges.

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The Image Resolution Compare to Having Lead Plate or Not Lumbar Lateral Projection

  • Kim, Hyun-Soo;Min, Jung-Whan;Dong, Kyung-Rae
    • Korean Journal of Digital Imaging in Medicine
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    • v.13 no.4
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    • pp.145-151
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    • 2011
  • The purpose of this study is to know some changes of resolution and image if we remove scattered ray using lead plate when doing lumbar lateral projection. Using 3 DR system(2 FD types, 1 CCD type) equipments and 2 film system equipments, we gain the image whether the phantom of abdomen equivalent sticking resolution chart has lead plate or not, whether we do collimation or not. Also, we use ion chamber, measure radiation exposure rate and change to entrance surface dose from it. we gain that images in the greatest condition of taking in clinic. 5 people in this group decoded resolution with our eyes, measured thickness of images and compared them from each equiments. Resolution has difference to size of collimation in DR FD type. Also there is no difference the original image with the new image which we abbreviated mAs. In DR CCD type, resolution didn't have difference whether lead plate is or not and whether we do collimation or not. In film type, existing or nonexisting of lead plate didn't influence on resolution. Lead plate makes the quality of image higher due to reducing scattered ray, it doesn't influence on resolution.

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Design of a 500W Class Micro Turbine Generator System as a Next Generation Military Power Source (차세대 군용전원용 500W급 마이크로 터빈 발전기 시스템 설계)

  • Choi, Sang-Kyu;Choi, Bum-Suk;Han, Yong-Shik;Woo, Byung-Chul;Song, In-Hyuck;Min, Seong-Ki;Lim, Jin-Sik
    • Journal of the Korea Institute of Military Science and Technology
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    • v.14 no.6
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    • pp.1192-1197
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    • 2011
  • Recent developments of small-size unmanned or manned mobile systems such as autonomous robots, exoskeleton or armored suits, micro air vehicles, and unmanned armored vehicles require long-lasting independent power sources of high energy and power density to support the systems' operation for up to 72 hours in the fields. Chemical batteries such as Ni-MH, Li-Ion, the current primary power sources for mobile devices, however, are not capable of providing enough power and energy density for the next generation high power mobile machines. For this reason, KIMM along with KERI and KIMS has been carrying out a 500W MTG development project under the DAPA's "Next generation military power source R&D program" since 2009. In this paper, a design process for a 500W MTG system currently being developed at KIMM is briefly described and the technical issues related to its development are addressed.

A Modularized Charge Equalizer Using the Magnetizing Energy of the Multi-Winding Transformer (다권선 변압기의 자화 에너지를 이용한 모듈화 전하 균일 장치)

  • Lim, Chang-Soon;Hyun, Dong-Seok;Kim, Rae-Young
    • The Transactions of the Korean Institute of Power Electronics
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    • v.17 no.5
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    • pp.393-400
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    • 2012
  • The modularized equalizers normally use additional components among the modules in the long series-connected lithium-ion battery string. In these approaches, the overall systems are heavy, bulky, and high-priced. Furthermore, the losses related to additional components decrease the system efficiency. To avoid these problems, a modularized equalizer, which has no additional components among the modules, is required. This paper proposes a novel control scheme using the magnetizing energy of the multi-winding transformer for the module equalization. In this scheme, the high duty cycle is applied to the module where the voltage is higher than the reference voltage and the low duty cycle is applied to the module where the voltage is lower than the reference voltage. Due to the different duty cycle, more electric charges are transferred from high voltage module to the low voltage module during the turn-off switching interval. Using the proposed control scheme, the equalizer system does not suffer from the size, cost, and loss related to the modularization. The experimental results are provided to verify the effectiveness of the proposed modularized equalizer.

Ni Coating Characteristics of High K Capacitor Ceramic Powders

  • Park, Jung-Min;Lee, Hee-Young;Kim, Jeong-Joo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.339-339
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    • 2007
  • Metal coating on ceramic powder has long been attracting interest for various applications such as superconductor where the brittle nature of high temperature ceramic superconductor was complemented by silver coating and metalloceramics where mechanical property improvement was achieved via electroless plating. More recently it has become of great interest in embedded passive device applications since metal coating on ceramic particles may result in the enhancement of the dielectric properties of ceramic-polymer composite capacitors. In our study, nickel ion-containing solution was used for coating commercial capacitor-grade $BaTiO_3$ powder. After filtering process, the powder was dried and heat-treated in 5% forming gas at $900^{\circ}C$. XRD and TEM were utilized for the observation of crystallization behavior and morphology of the particles. It was found that the nickel coating characteristics were strongly dependent on the several parameters and processing variables, such as starting $BaTiO_3$ particle size, nickel source, solution chemistry, coating temperature and time. In this paper, the effects of these variables on the coating characteristics will be presented in some detail.

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Recipe Standardization and Nutrient Analysis of Local Foods of Cheollabuk-do Province(The First Report) (전라북도 향토음식의 조리법 표준화 및 영양분석 분석(제1보)-전주비빔밥, 콩나물국밥, 민물장어구이, 애저찜, 아귀찜-)

  • 주종재;신미경;권경순;윤계순
    • Korean Journal of Community Nutrition
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    • v.3 no.4
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    • pp.630-641
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    • 1998
  • As the incidence of diet-related diseases increase, much attention has been focused of traditional foods. Traditional foods are ultimately based on local foods. However, there has been little study looking into the recipes and nutritional value of local foods. Therefore, the present study was designed to standardize recipes and analyze the nutrients of some representative local foods of Cheollabuk-do Province. Their foods were Cheonju pibimpap, kongnamulgukpap, minmuljangokui, aejeotchim and aguytichim. Test recipes for each food were prepared, being based on various information obtained from personal interviews, literature surveys of restaurant recipes. Then test recepe was subjected to sensory evaluation. All characteristics of each food were judged as "satisfactory". The analysis of nutrient composition revealed that in general energy content was low whereas protein content was as high as recommended reguirement in all foods except for kongnamulgukpap. Vitamin content was generally high but contents of calcium and iron were relatively low in all foods. Cheonju pibimpap was rich in dietary fiber. Dietary fiber content of Cheonju pibimpap was 16.6g per serving size. All foods contained considerable amounts of essential amino acids. The major fatty acide were oleic acid, linoleic acid and glutamic acid, oleic acid being the highest in terms of composition ratio.ion ratio.

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Thermodynamics of 2, N-Dimethyl Pyridinium Iodide in Ethanol-Water Mixture under High Pressure

  • Jee, Jong-Gi;Lee, Young-Hwa;Woo, Eui-Ha;Lee, Kyung-Hee
    • Bulletin of the Korean Chemical Society
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    • v.4 no.3
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    • pp.115-119
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    • 1983
  • The ionic association constants (K) of 2, N-dimethyl pyridinium iodide (2NDMPI) in 95 volume percentage ethanol-water mixture were determined by a modified UV and conductance method at $20^{\circ}C{\sim}50^{\circ}C$ under 1 to 2000 bars. The K values increase with increasing pressure and decrease with temperature. The total partial molar volume change (${\Delta}V$) has relatively small negative value and the absolute ${\Delta}V$ value decrease with increasing pressure and temperature. The ion size (a) and solvation number (n) of 2NDMPI were about 5 $\AA$ and changed from 1 to 3 with decreasing temperature. Other thermodynamic parameters such as enthalpy (${\Delta}H^{\circ}$) and entropy (${\Delta}S^{\circ}$) for the equilibrium of the 2NDMPI were evaluated. From all the parameters mentioned above, we came to conclusion that the electrostriction effect of 2NDMPI in the ethanol-water mixture is enhanced with increasing pressure and decreasing temperature.

Ionization and Divalent Cation Complexation of Quinolone Antibiotics in Aqueous Solution

  • Park, Hyeong Ryun;Jeong, Gwang Yeong;Lee, Hyeong Cheol;Lee, Jin Gi;Baek, Gi Min
    • Bulletin of the Korean Chemical Society
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    • v.21 no.9
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    • pp.849-854
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    • 2000
  • The protonation and divalent cation complexation equilibria of several quinolone antibiotics such as nalidixic acid (NAL),flumequine (FLU), oxolinic acid (OXO), ofloxacin (OFL), norfloxacin (NOR) and enoxacin (ENO) have been examined by potentiome tric titration and spectrophotometric method. The antibacterial activity of these drugs depends upon the pH and the concentration of metal cations such as Mg2+ , Ca2+ in solu-tion. The apparent ionization constants of NAL, FLU, OXO, OFL, NOR and ENO in aqueous solution were found to be 6.33, 6.51, 6.72, 7.18, 7.26, and 7.53, respectively. In aqueous solution, NAL, FLU and OXO were found to be present mainly as two chemical species : molecularand anionic; but OFL, NOR and ENO were present mainly as three chemical species : anionic, neutral zwitterionic and cationic form, in equilibrium. The pKa1 and pKa2are found to be 6.10 and 8.28 for OFL; 6.23 and 8.55 for NOR; 6.32 and8.62 for ENO, respec-tively. The complex formation constants between OFL, NOR or FLU and some divalent cations are measured at pH 7.5. The 1 : 1 complexes are formed mainly by ion-dipole interaction. FLU has somewhat larger Kf values than OFL and NOR because its molecular size is small and the FLU is present asanionic form at pH 7.5.