• Title/Summary/Keyword: Internal degradation

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The Effects of Grain Size on the Degradation Phenomena of PZT Ceramics (입자의 크기가 PZT 세라믹스의 열화현상에 미치는 영향)

  • 정우환;김진호;조상희
    • Journal of the Korean Ceramic Society
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    • v.29 no.1
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    • pp.65-73
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    • 1992
  • The effect of grain size on the time-dependent piezoelectrice degradation of a poled PZT of MPB composition Pb0.988Sr0.012 (Zr0.52Ti0.48)O3 with 2.4 mol% of Nb2O5 was studied, and the degradation mechanism was discussed. Changes in the internal bias field and the internal stress both responsible for the time-dependent degradation of poled PZT were examined by the polarization reveral technique, XRD and Vickers indentation, respectively. The piezoelectric degradation increased with increasing time and grain size, and the internal bias field due to space charge diffusion decreased with increasing grain size of poled PZT. The internal bias field, however, was almost insensitive to the degradation time regardless of the grain size. On the other hand, both the x-ray diffraction peak intensity ratio of (002) to (200) and the fracture behavior including the crack propagation support that the ferroelectric domain rearrangement of larger grain size showed rapid relaxation of the internal stress compared with smaller one, which is thought the origin of the larger piezoelectric degradation in the former. In conclusion, the contribution of space charge diffusion on the piezoelectric degradation of PZT is strongly dependent on both the grain size and the composition. Thus, the relaxation of internal stress due to the ferroelectric domain rearrangement as well as the amount and time-dependence of the internal bias field due to space charge diffusion should be considered simultaneously in the degradation mechanism of PZT.

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Degradation Comparison of Hydrogen and Internally Reformed Methane-Fueled Solid Oxide Fuel Cells

  • Kim, Young Jin;Lee, Hyun Mi;Lim, Hyung-Tae
    • Journal of the Korean Ceramic Society
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    • v.53 no.5
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    • pp.483-488
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    • 2016
  • Anode supported solid oxide fuel cells (SOFCs), consisting of Ni+YSZ anode, YSZ electrolyte, and LSM+YSZ cathode, were fabricated and constant current tested with direct internal reforming of methane (steam to carbon ratio ~ 2) as well as hydrogen fuel at $800^{\circ}C$. The cell, operated under direct internal reforming conditions, showed relatively rapid degradation (~ 1.6 % voltage drop) for 95 h; the cells with hydrogen fuel operated stably for 170 h. Power density and impedance spectra were also measured before and after the tests, and post-test analyses were conducted on the anode parts using SEM / EDS. The results indicate that the performance degradation of the cell operated with internal reforming can be attributed to carbon depositions on the anode, which increase the resistance against anode gas transport and deactivate the Ni catalyst. Thus, the present study shows that direct internal reforming SOFCs cannot be stably operated even under the condition of S/C ratio of ~ 2, probably due to non-uniform mixture (methane and steam) gas flow.

Partial Discharge Diagnosis of Thermal Degradated PVC Cable (열열화된 PVC 케이블의 부분방전 진단)

  • Song, Ki-Tae;Lee, Sung-Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.3
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    • pp.208-214
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    • 2011
  • In this thesis, the partial discharge according to applied voltage and variations of cross-sectional area and length of the conductor related to general condition for using cable was measured in order to study degradation diagnosis for 2-Core cable of the PVC insulator used in industrial fields for other safety installations. Also the thermal degradation conditions under various installation circumstances of cables were studied by assuming degradation conditions with each different degradation rate (50%, 67%, 100%) such as variation in degradated temperature, thermal exposure time, normal state, partially degradated state and overall degradated state for thermal degradation diagnosis. The quantity of electric discharge (V-Q) according to applied voltage was measured for measurement of inception voltage and extinction voltage. The quantity of electric discharge and the number of electric discharge (Q-N) were measured with applied voltage kept constantly. In addition, pictures were taken using SEM (scanning electron microscope) to compare the surface of external insulator to degradated state of internal insulator according to thermal degradation temperature and also compare the surface of external insulator to degradated surface state of internal insulator according exposure time of cables to thermal stress.

A Study on the Effects of Contaminant Types on the Wear Degradation Characteristics in Internal Gear Pumps (불순물 입자의 유형에 따른 내접기어 펌프에서의 마모열화 특성 연구)

  • Shin, Jung-Hun;Ji, Kyung-Ryeol;Kim, Hyoung-Eui
    • Tribology and Lubricants
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    • v.27 no.3
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    • pp.134-139
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    • 2011
  • The mechanical equipments which are exposed to impure environment undergo significant reductions in their own lifetimes. Several environmental test procedures have been developed to analyze these phenomena. Moreover in the industry to require shorter development duration, accelerated life testers artificially add test containments into machines. In this research JIS Z 8901 test powder was added into internal gear pumps which are used as oil pumps in vehicles and thus the effects of the addition on the degradation of the pumps were examined. Three kinds of contaminants were selected. Two of the contaminants are identical in particle size but different in the composition of the ingredients. The other pair have identical ingredients and composition but different particle size. The quantity of contaminants was also an interesting factor in this study. The results show that each JIS contaminant caused notable degradation in the discharge flow characteristic of pumps while friction torque degradation did not have any tendency. Finally leakage rates were deduced and equivalent wear volume ratios were calculated.

Proteasome Inhibitor-Induced IκB/NF-κB Activation is Mediated by Nrf2-Dependent Light Chain 3B Induction in Lung Cancer Cells

  • Lee, Kyoung-Hee;Lee, Jungsil;Woo, Jisu;Lee, Chang-Hoon;Yoo, Chul-Gyu
    • Molecules and Cells
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    • v.41 no.12
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    • pp.1008-1015
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    • 2018
  • $I{\kappa}B$, a cytoplasmic inhibitor of nuclear factor-${\kappa}B$ ($NF-{\kappa}B$), is reportedly degraded via the proteasome. However, we recently found that long-term incubation with proteasome inhibitors (PIs) such as PS-341 or MG132 induces $I{\kappa}B{\alpha}$ degradation via an alternative pathway, lysosome, which results in $NF-{\kappa}B$ activation and confers resistance to PI-induced lung cancer cell death. To enhance the anti-cancer efficacy of PIs, elucidation of the regulatory mechanism of PI-induced $I{\kappa}B{\alpha}$ degradation is necessary. Here, we demonstrated that PI up-regulates nuclear factor (erythroid-derived 2)-like 2 (Nrf2) via both de novo protein synthesis and Kelch-like ECH-associated protein 1 (KEAP1) degradation, which is responsible for $I{\kappa}B{\alpha}$ degradation via macroautophagy activation. PIs increased the protein level of light chain 3B (LC3B, macroautophagy marker), but not lysosome-associated membrane protein 2a (Lamp2a, the receptor for chaperone-mediated autophagy) in NCI-H157 and A549 lung cancer cells. Pretreatment with macroautophagy inhibitor or knock-down of LC3B blocked PI-induced $I{\kappa}B{\alpha}$ degradation. PIs up-regulated Nrf2 by increasing its transcription and mediating degradation of KEAP1 (cytoplasmic inhibitor of Nrf2). Overexpression of dominant-negative Nrf2, which lacks an N-terminal transactivating domain, or knock-down of Nrf2 suppressed PI-induced LC3B protein expression and subsequent $I{\kappa}B{\alpha}$ degradation. Thus, blocking of the Nrf2 pathway enhanced PI-induced cell death. These findings suggest that Nrf2-driven induction of LC3B plays an essential role in PI-induced activation of the $I{\kappa}B$/$NF-{\kappa}B$ pathway, which attenuates the anti-tumor efficacy of PIs.

A Study of the Performance Degradation Factors of An Internal Network (내부 네트워크의 성능저하요인에 관한 연구)

  • Jeon, Jeon-Hoon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.36 no.1B
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    • pp.43-50
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    • 2011
  • Recently, Hacking Attacks are appearing as a various Attack techniques with evolution of the Network and most of the network through a various Security Systems are responding to an attack. In addition, it should be placed adding the Security Systems to protect the Internal Network's Information Assets from External attacks. But, The use of Security Systems and Network deployment inside the network makes a significant impact on Security and Performance. Therefore, In this paper, it will be to analyze the Performance Degradation Factors of the Internal Network according to the Security System's use and placement. In a future, This paper is expected to serve as a valuable information for the Network Performance and Security improvements.

Effect of Environmental Conditions on the Biodegradation of Cellulose Fibers - Effect of Humidity in Soil - (환경 조건에 따른 셀룰로스계 섬유의 생분해성 - 토양 수분율을 중심으로 -)

  • Kang, Yun-Kyung;Park, Chung-Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.7 s.144
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    • pp.1027-1036
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    • 2005
  • Based on the correlation analysis result of preceding research, the biodegradabilities of cellulose fibers were closely related to the moisture regain of the samples, which reflects the hydrophilicity and internal structure of the fibers. In addition to this factor, it was expected that the biodegradation conditions influence the biodegradability of fibers. In this study, widely used cellulose fibers including cotton, rayon, and acetate were used. The biodegradabilities of cellulose fibers were measured by soilburial test, and then the degradation behaviors based on each condition were compared. Moreover, the effects of degradation conditions such as humidity of the soil were investigated. Changes in the internal structure of samples were also observed by X-ray analysis according to the soil burial time. It was shown that humidity of soil facilitated the degradation of cotton, rayon, and acetate fibers, showing higher degradation rate with higher humidity in soil. This effect was shown to be much greater in the fibers of high moisture regain such as cotton and rayon. In respect of microstructure change, crystallinities and their crystal size of fibers decreased remarkably in the soil of higher humidity. It was revealed that degradation of crystalline area was more dependent on the soil humidity than that of amorphous area.

Bi-layer Electrolyte for Preventing Solid Oxide Fuel Cell Stack Degradation (고체산화물 연료전지 스택 열화 방지를 위한 전해질 기술)

  • Park, Mi Young;Bae, Hongyeul;Lim, Hyung-Tae
    • Journal of the Korean Ceramic Society
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    • v.51 no.4
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    • pp.289-294
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    • 2014
  • The stability of a solid oxide fuel cell (SOFC) stack is strongly dependent on the magnitude and profile of the internal chemical potential of the solid electrolyte. If the internal partial pressure is too high, the electrolyte can be delaminated from the electrodes. The formation of high internal pressure is attributed to a negative cell voltage, and this phenomenon can occur in a bad cell (with higher resistance) in a stack. This fact implies that the internal chemical potential plays an important role in determining the lifetime of a stack. In the present work, we fabricate planar type anode-supported cells ($25cm^2$) with a bi-layer electrolyte (with locally increased electronic conduction at the anode side) to prevent high internal pressure, and we test the fabricated cells under a negative voltage condition. The results indicate that the addition of electronic conduction in the electrolyte can effectively depress internal pressure and improve the cell stability.

Effect of Prunetin on TNF-${\alpha}$-Induced MUC5AC Mucin Gene Expression, Production, Degradation of $I{\kappa}B$ and Translocation of NF-${\kappa}B$ p65 in Human Airway Epithelial Cells

  • Ryu, Jiho;Lee, Hyun Jae;Park, Su Hyun;Sikder, Md. Asaduzzaman;Kim, Ju-Ock;Hong, Jang-Hee;Seok, Jeong Ho;Lee, Choong Jae
    • Tuberculosis and Respiratory Diseases
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    • v.75 no.5
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    • pp.205-209
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    • 2013
  • Background: We investigated whether prunetin significantly affects tumor necrosis factor-${\alpha}$ (TNF-${\alpha}$)-induced MUC5AC mucin gene expression, production, inhibitory kappa B ($I{\kappa}B$) degradation and nuclear factor kappa B (NF-kB) p65 translocation in human airway epithelial cells. Methods: Confluent NCI-H292 cells were pretreated with prunetin for 30 minutes and then stimulated with TNF-${\alpha}$ for 24 hours or the indicated periods. MUC5AC mucin gene expression and mucin protein production were measured by reverse transcription polymerase chain reaction and enzyme-linked immunosorbent assay, respectively. The effect of prunetin on TNF-${\alpha}$-induced degradation of $I{\kappa}B$ and translocation of NF-${\kappa}B$ p65 was investigated by western blot analysis. Results: We found that incubation of NCI-H292 cells with prunetin significantly inhibited mucin production and down-regulated the MUC5AC gene expression induced by TNF-${\alpha}$. Prunetin inhibited TNF-${\alpha}$-induced degradation of $I{\kappa}B$ and translocation of NF-${\kappa}B$ p65. Conclusion: This result suggests that prunetin inhibits the NF-${\kappa}B$ signaling pathway, which may explain its role in the inhibition of MUC5AC mucin gene expression and production regulated by the NF-${\kappa}B$ signaling pathway.

Compressive strength degrdation model of Ultra high strength under high temperature (고온가열을 받는 초고강도 콘크리트의 압축강도저하 모델 제안)

  • Choe, Gyeong-Choel;Kim, Gyu-Yong;Yoon, Min-Ho;Lee, Young-Wook;Lee, Bo-Kyeong;Kim, Hong-Seop
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.26-27
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    • 2014
  • Study on high temperature properties of concrete and internal force estimation of structural member subjected to high temperature mainly applied high temperature strength model based on experimental results with concrete under 40MPa. However, it is reported that degradation of internal force at high temperature and spalling of ultra high strength concrete are higher than that of normal strength concrete. Therefore, this study attempts to propose compressive strength degradation model which is suitable to ultra high strength concrete comparing to existing model by evaluating high temperature properties of ultra high strength concrete.

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