• Carbon letters
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• v.25
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• pp.1-13
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• 2018

Gold functionalized graphene oxide (GOAu) nanoparticles were reinforced in acrylonitrile-butadiene rubbers (NBR) via solution and melt mixing methods. The synthesized NBR-GOAu nanocomposites have shown significant improvements in their rate of curing, mechanical strength, thermal stability and electrical properties. The homogeneous dispersion of GOAu nanoparticles in NBR has been considered responsible for the enhanced thermal conductivity, thermal stability, and mechanical properties of NBR nanocomposites. In addition, the NBR-GOAu nanocomposites were able to show a decreasing trend in their dielectric constant (${\varepsilon}^{\prime}$) and electrical resistance on straining within a range of 10-70%. The decreasing trend in ${\varepsilon}^{\prime}$ is attributed to the decrease in electrode and interfacial polarization on straining the nanocomposites. The decreasing trend in electrical resistance in the nanocomposites is likely due to the attachment of Au nanoparticles to the surface of GO sheets which act as electrical interconnects. The Au nanoparticles have been proposed to function as ball rollers in-between GO nanosheets to improve their sliding on each other and to improve contacts with neighboring GO nanosheets, especially on straining the nanocomposites. The NBR-GOAu nanocomposites have exhibited piezoelectric gauge factor (${GF_{\varepsilon}}^{\prime}$) of ~0.5, and piezo-resistive gauge factor ($GF_R$) of ~0.9 which clearly indicated that GOAu reinforced NBR nanocomposites are potentially useful in fabrication of structural, high temperature responsive, and stretchable strain-sensitive sensors.

• Journal of Information Display
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• v.12 no.4
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• pp.209-212
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• 2011

The threshold voltage shift (${\Delta}V_{th}$) under positive-voltage bias stress (PBS) of InGaZnO (IGZO) thin-film transistors (TFTs) annealed at different temperatures in air was investigated. The dramatic degradation of the electrical performance was observed at the sample that was annealed at $700^{\circ}C$. The degradation of the saturation mobility (${\mu}_{sat}$) resulted from the diffusion of indium atoms into the interface of the IGZO/gate insulator after crystallization, and the degradation of the subthreshold slope (S-factor) was due to the increase in the interfacial and bulk trap density. In spite of the degradation of the electrical performance of the sample that was annealed at $700^{\circ}C$, it showed a smaller ${\Delta}V_{th}$ under PBS conditions for $10^4$ s than the samples that were annealed at $500^{\circ}C$, which is attributed to the nanocrystal-embedded structure. The sample that was annealed at $600^{\circ}C$ showed the best performance and the smallest ${\Delta}V_{th}$ among the fabricated samples with a ${\mu}_{sat}$ of $9.38cm^2/V$ s, an S-factor of 0.46V/decade, and a ${\Delta}V_{th}$ of 0.009V, which is due to the passivation of the defects by high thermal annealing without structural change.

• Composites Research
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• v.15 no.6
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• pp.8-15
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• 2002

In this work, the effect of biodegradable poly(butylene succinate)(PBS) in difunctional epoxy(21:P) resin was investigated in terms of rheological properties, cure kinetics, thermal stabilities, and mechanical interfacial properties. Rheological properties of the blend system were measured under isothermal condition using a rheometer. Cross-linking activation energies($\textrm{E}_c$) were determined from the Arrhenius equation based on gel time and curing temperature. The $\textrm{E}_c$ was increased in the presence of 10 wt% PBS as compared with neat 2EP. From the DSC results of the blends, the cure activation energies($\textrm{E}_a$) showed a similar behavior with $\textrm{E}_c$ due to the increased intermolecular interaction between 2EP and PBS. The decomposed activation energies($\textrm{E}_t$) for the thermal stability derived from the integral method of Horowitz-Metzger equation, were also increased in 10 wt% PBS. In addition, 20 wt% PBS showed the highest critical stress intensity factor($\textrm{E}_{IC}$). which was explained by increasing the fracture toughness of the 2EP/PBS blend systems.

• Composites Research
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• v.25 no.6
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• pp.198-204
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• 2012

The objective of this study is to improve the mechanical properties in abaca fabric/epoxy composites produced using a VARTM process. The mechanical properties were improved by increasing the surface roughness of the fabric through plasma polymerization and improving the interfacial adhesion between the epoxy and the fabric through changing its hydrophilic properties to the hydrophobic properties. Plasma polymerization at atmospheric pressure and room temperature was used, and the optimal polymerization time to improve the mechanical properties was investigated. NaOH treatment on the fabric was also carried out for the comparison. The composite fabricated using the fabric polymerized for 10 seconds shows the highest tensile strength compared to that of none-polymerized or NaOH treated. Plasma polymerization for more than 20 seconds exhibits decrease in the tensile strength. As a result, the plasma polymerization for more than 20 seconds may have caused some damages on the surface of the fabrics. Also, the hydrophilic abaca represents a tendency of presenting the hydrophobic properties in absorption and sedimentation tests.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.4
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• pp.425-429
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• 2011

In the unlikely of nuclear reactor meltdown, the leaked core melt or corium must be contained in a device called core-catcher so that the corium can be cooled and stabilized. The ex-vessel behavior of corium involves complex physical and chemical mechanisms of flow propagation, heat transfer, and reactions with sacrificial substrates. In this study, the detailed characteristics of corium flow and heat transfer were investigated by using a commercial CFD code for VULCANO VE-U7 test reported in the literature. The volume-of-fluid (VOF) model was used to predict the interfacial surface formation of corium and the surrounding air, and the discrete ordinate model was adopted to calculate radiation between corium and the surroundings. It was found that cooling via radiation through the top surface of corium had a dominant effect on the temperature and viscosity profiles at the front of the corium flow.

• Applied Chemistry for Engineering
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• v.8 no.1
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• pp.76-83
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• 1997

Blends of thermotropic liquid crystalline polymer(TLCP) with poly(ethylene terephthalate) (PET) were prepared by the coprecipitation from a common solvent. The blends were processed through a capillary die at $287^{\circ}C$ to produce a monofilament. Morphology and mechanical, thermal properties of blends and composites were examined by differential scanning calorimetry(DSC), tensile test, optical microscopy and scanning electron microscopy. Crystallization kinetics of the blends were investigated by the isothermal DSC method. The Avrami analyses were applied to obtain the information on the crystal growth geometry and factors controlling the rate of crystallization. In the blends, liquid crystalline phase did not reveal any significant macrophase separation and thermal degradation at the processing temperature. From scanning electron micrographs of cryogenic fracture surfaces of extruded fibers, the TLCP domains were found to be more or less finely dispersed with $0.1{\mu}m$ to $0.2{\mu}m$ in size. Interfacial adhesion between the TLCP and matrix polymer was excellent. Tensile strength and modulus of TLCP/PET in-situ fiber composites were enhanced with increasing draw ratio and LCP content.

• Applied Chemistry for Engineering
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• v.8 no.1
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• pp.49-58
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• 1997

LCP/PA alloy was prepared by blending poly(${\varepsilon}-caprolactam$) (PA) with liquid crystal polyester, Vectra (LCP) having high elasticity and strength. The alloy prepared amorphous PA with more than 10 parts of thermotropic LCP had poor compatibility. To increase the compatibility of the alloy, compatibilizing agent, poly(glycinylmaleimide-co-methylmetacrylate)[poly(GMI-co-MMA)] copolymer was prepared by copolymerizing N-glycinylmaleimide(GMI) with methylmetacrylate(MMA). And then, it was blended with LCP and PA to produce LCP/PA alloy having an excellent compatibility. The compatibility characteristics of the alloy prepared from LCP and PA using the poly(GMI-co-MMA) was determined by measuring the thermal characteristics of glass transition temperature of nematic LCP, and rheological properties, and also high rate impact and flexual characteristics of the alloy were determined.

• Applied Chemistry for Engineering
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• v.7 no.1
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• pp.145-152
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• 1996

A fine oil-in-water (O/W) emulsion using nonaqueous emulsification technique was developed and the behaviors of POE(25)octyldodecyl ether in nonaqueous solvent/oil systems were studied by observing the surface tension, interfacial tension, turbidity and transition temperature. It was found that POE(25)octyldodecyl ether existed soluble in nonaqueous solvent while, in aqueous system, it formed micelles. So, when a solvent, like glycerine in which POE(25)octyldodecyl ether has poor solubility, was added, POE(25)octyldodecyl ether moved to the surface. After saturated at surface, POE(25) octyldodecyl ether began to precitate. The mean particle size of the final emulsion was 230nm. Also, the emulsion system was stable at 0, 25, 40, $50^{\circ}C$ and cycling test for a month, while the conventional emulsion system showed unstability. It is concluded that, by pertinent combination of solvents, the adsorption efficiency of surfactant could be improved.

• Applied Chemistry for Engineering
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• v.29 no.4
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• pp.399-404
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• 2018

This study compared the tackiness and adhesion of different tire tread compounds and rubber cements before and after vulcanization. The tackiness of natural rubber (NR) cement was the highest for all tread compounds before vulcanization, and the decrease in tackiness of NR cements over time was smaller than that of synthetic rubber cements. The tackiness before vulcanization was affected by the glass transition temperature of the rubber used in the cement and the decrease in tackiness over time of NR was smaller compared to that of using the synthetic rubber. The adhesion of NR-based cements after vulcanization was high for NR tread compounds but low for synthetic rubber tread compounds. On the contrary, the adhesion of emulsion (SBR) and solution SBR cements was high on all tread compounds which was shown to be higher when the rate of vulcanization of cement rubber was lower.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.429.2-429.2
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• 2014

ZnO nanowire is known as synthesizable and good mechanical properties. And, stimuli-responsive polymer is widely used in the application of tunable sensing device. So, we combined these characteristics to make precise tunable sensing devise. In this work, we investigate the dependence of ZnO nanowire alignment and morphology on si substrate using nanosphere template with various conditions via hydrothermal process. Also, pH-temperature dependant tuning ability of nanostructure was studied. The brief experimental scheme is as follow. First, Zno seed layer was coated on a si wafer ($20{\times}20mm$) by spin coater. And then $1.15{\mu}m$ sized close-packed PS nanospheres were formed on a cleaned si substrate by using gas-liquid-solid interfacial self-assembly method. After that, zinc oxide nanowires were synthesized using hydrothermal method. Before the wire growth, to specify the growth site, heat treatment was performed. Finally, NIPAM(N-Isopropylacrylamide) was coated onto as-fabricated nanostructure and irradiated by UV light to form the PNIPAM network. The morphology, structures and optical properties are investigated by FE-SEM(Field Emission Scanning electron Microscopy), XRD(X-ray diffraction), OM(Optical microscopy), and WCA(water contact angle).