• Title/Summary/Keyword: Interfacial energy

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Effects of Thickness of Ferromagnetic Co Layer and Annealing on the Magnetic Properties of Co/IrMn Bilayers. (Co/IrMn 이층막의 자기적 특성과 Co 두께 및 어닐링의 영향)

  • Jung, Jung-Gyu;Lee, Chan-Gyu;Koo, Bon-Heun;Lee, Gun-Hwan;Hayashi, Yasunori
    • Korean Journal of Materials Research
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    • v.13 no.7
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    • pp.447-452
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    • 2003
  • Effects of annealing and thickness of Co layer in Co/IrMn bilayers on the magnetic properties have been investigated. The highest interfacial exchange coupling energy($J_{K}$ = 0.12 erg/$\textrm{cm}^2$) was obtained for 10 nm Co layer thickness. Exchange bias field is inversely proportional to the magnetization, the thickness of the pinned layer, and the grain size of antiferromagnetic layer. Also it is related to the interfacial exchange energy difference, which is expected to depend on the surface roughness. These results almost agree with the random-field model of exchange anisotropy proposed by Malozemoff. Exchange bias field decreased slowly with increasing annealing temperature up to X$300^{\circ}C$. However, exchange bias field increased above $300^{\circ}C$.

A model for Phase Transformation of Microalloyed Low Carbon Steel Combined with Nb Precipitation Kinetics (Nb 석출 거동을 고려한 저탄소강의 상변태 모델)

  • Kim, D.W.;Cho, H.H.;Park, S.;Kim, S.H.;Kim, M.J.;Lee, K.;Han, H.N.
    • Transactions of Materials Processing
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    • v.26 no.1
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    • pp.48-54
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    • 2017
  • The dissolution and precipitation of Nb, which has been known as strong carbide-forming element, play a key role in controlling phase transformation kinetics of microalloyed steels. In this study, we analyzed both numerically and experimentally the precipitation behavior of Nb-microalloyed steel and its effect on the austenite decomposition during cooling. Nb precipitation in austenite matrix could be predicted by the thermo-kinetic software MatCalc, in which interfacial energy between precipitate and matrix is calculated. The simulated precipitation kinetics fairly well agrees with the experimental observations by TEM. Austenite decomposition, which is strongly affected by Nb precipitation during cooling, was measured by dilatometry and was modeled on the basis of a Johnson-Mehl-Avrami-Kolmorgorov(JMAK) equation. It was confirmed that the dissolved Nb delays the austenite decomposition, whereas, the precipitated Nb accelerates phase transformation during the austenite decomposition.

Electrical Properties of p-GaAs Photoelectrode for Solar Energy Conversion (태양광 변환을 위한 p형 GaAs 광전극의 전기적 특성)

  • 윤기현;이정원;강동헌
    • Journal of the Korean Ceramic Society
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    • v.32 no.11
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    • pp.1262-1268
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    • 1995
  • Photoelectrochemical properties of p-GaAs electrode have been investigated. I-V characteristic shows that the cathodic photocurrent is observed at -0.7 V vs. SCE. The photoresponse at near 870~880nm wavelength indicates that the photogenerated carriers contibuted to the observed current. The maximum converson efficiency of 35% is obtained for a Xe lamp light source at 400nm. In C-V relation, capacitance peaks appeared at the frequencies of 100Hz and 300Hz due to the activation of the interfacial states which exist at the energy level corresponding to the one-third of the GaAs band gap. The difference of about 1.1V between flatband potential (Vfb) from the Mott-Schottky method and onset voltage from I-V curve is observed due to the trap of carriers at the interfacial states in the boundary between GaAs and electrolyte. In case of WO3 deposited p-GaAs electrode, higher positive onset current and photocurent density are obtained. This can be explained by the fact that carriers are generated by light penetrated into the WO3 thin flm as well as p-GaAs substrate and then move into the electrolyte effectively.

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Effects of Ar+ ion Beam Irradiation on the Adhesion Forces between Carbon fibers and Thermosetting Resins (Ar+ 이온 빔 조사가 탄소섬유와 열경화성 수지 간 계면결합력에 미치는 영향)

  • 박수진;서민강;김학용;이경엽
    • Polymer(Korea)
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    • v.26 no.6
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    • pp.718-727
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    • 2002
  • In this work, an Ar+ beam was irradiated on carbon fiber surfaces to improve the interfacial shear strength (IFSS) of the resulting composites using an ion assisted reaction (IAR) method h single fiber pull-out test was executed to investigate the basic characteristics of the single Carbon fiber/matrix interface. Based on Greszczuk's geometrical model, the debonding force for pull-out of the fiber from the resins was discussed with the applied ion beam energy as a result, it was known that an ion beam treatment produced the functional groups on fiber surface and etching lines along the fiber axis direction, resulting in increasing the adhesion forces between fibers and matrix, which caused the improvement of the IFSS in a composite system. And, it was also found that the maximum IFSS was shown at 0.8 keV ion beam energy in this system.

Analysis of seawater desalination energy consumption based on changes in raw water characteristics and operating condition (원수 특성 변화 및 공정운영 조건에 따른 해수담수화 에너지 소비량 분석)

  • Yun, Seung-Hyeon;Woo, Dal-Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.33 no.4
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    • pp.281-289
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    • 2019
  • Desalination plants are generally studied with higher operating costs compared to water supply facilities. This study was conducted to reduce the cost of water production and to preserve existing water resources. Therefore, the purpose of this study was to utilize the control valves to increase maximum efficiency, thereby reducing the power of the pumps and operating costs. Specific energy consumption was shown to reduce the process operating power by up to 1.7 times from 6.17 to $3.55kWh/m^3$ based on seawater reverse osmosis 60 bar. In addition, the water intake process was divided into pre, inter, and post-according to the use method of blasting, and the water treatment process was divided into pre, inter, and post blending. In order to reduce power consumption, the blending process was combined to operate the facility, which resulted in the reduction of power consumption in the order post > pre-inter> inter blending.

A NONLINEAR CONVEX SPLITTING FOURIER SPECTRAL SCHEME FOR THE CAHN-HILLIARD EQUATION WITH A LOGARITHMIC FREE ENERGY

  • Kim, Junseok;Lee, Hyun Geun
    • Bulletin of the Korean Mathematical Society
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    • v.56 no.1
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    • pp.265-276
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    • 2019
  • For a simple implementation, a linear convex splitting scheme was coupled with the Fourier spectral method for the Cahn-Hilliard equation with a logarithmic free energy. However, an inappropriate value of the splitting parameter of the linear scheme may lead to incorrect morphologies in the phase separation process. In order to overcome this problem, we present a nonlinear convex splitting Fourier spectral scheme for the Cahn-Hilliard equation with a logarithmic free energy, which is an appropriate extension of Eyre's idea of convex-concave decomposition of the energy functional. Using the nonlinear scheme, we derive a useful formula for the relation between the gradient energy coefficient and the thickness of the interfacial layer. And we present numerical simulations showing the different evolution of the solution using the linear and nonlinear schemes. The numerical results demonstrate that the nonlinear scheme is more accurate than the linear one.

Experimental Study on Interfacial Bond Stress between Aramid FRP Strips and Steel Plates (아라미드 FRP 스트립과 강판 사이의 계면 부착응력에 관한 실험적 연구)

  • Park, Jai Woo;Ryoo, Jae Yong;Choi, Sung Mo
    • Journal of Korean Society of Steel Construction
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    • v.27 no.4
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    • pp.359-370
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    • 2015
  • This paper presents the experimental results for the interfacial bond behaviour between AFRP strip and steel members. The objective of this paper is to examine the interfacial behavior and to evaluate the interfacial bond stress between Aramid FRP strips and steel plates. The test variables were bond length and AFRP thickness. 18 specimens were fabricated and one-face shear type bond tests were conducted in this study. There were two types of failure mode which were debonding and delamination between AFRP strip and steel plates. From the test, the load was increased with the increasing of bond length and AFRP thickness, which was observed that maximum increase of 63 and 86% were also achieved in load with the increasing of bond length and AFRP thickness, respectively. Finally, bond and slip characteristics had the elastic bond-slip model and it was observed that bond strength and fracture energy were not affected by bond length and AFRP thickness.

Effect of Anodized Carbon Fiber Surfaces on Mechanical Interfacial Properties of Carbon Fibers-reinforced Composites (탄소섬유의 양극산화가 탄소섬유 강화 복합재료의 기계적 계면 특성에 미치는 영향)

  • 박수진;오진석;이재락
    • Composites Research
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    • v.15 no.6
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    • pp.16-23
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    • 2002
  • In this work, the effect of anodic oxidation on surface characteristics of high strength PAN-based carbon fibers was investigated in mechanical interfacial properties of composites. The surface properties of the carbon fibers were determined by acid-base values, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and contact angles. And their mechanical interfacial properties of the composites were studied in interlaminar shear strength (ILSS) and critical stress intensity factor ($K_{IC}$). As a result, the acidity or the $O_{ls}/C_{ls}$ ratio of carbon fiber surfaces was increased, due to the development of the oxygen functional groups. Consequently, the anodic oxidation led to an increase in surface free energy of the carbon fibers, mainly due to the increase of its specific (or polar) component. The mechanical interfacial properties of the composites, including ILSS and $K_{IC}$, had been improved in the anodic oxidation on fibers. These results were explained that good wetting played an important role in improving the degree of adhesion at interfaces between fibers and epoxy resin matrix.

Interfacial Evaluation and Nondestructive Damage Sensing of Carbon Fiber Reinforced Epoxy-AT-PEI Composites using Micromechanical Test and Electrical Resistance Measurement (Micromechanical 시험법과 전기저항 측정을 이용한 탄소섬유 강화 Epoxy-AT-PEI복합재료의 비파괴적 손상 감지능 및 계면물성 평가)

  • Joung-Man Park;Dae-Sik Kim;Jin-Woo Kong;Minyoung Kim;Wonho Kim
    • Composites Research
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    • v.16 no.2
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    • pp.62-67
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    • 2003
  • Interfacial properties and damage sensing for the carbon fiber/epoxy-amine terminated (AT)-polyetherimide (PEI) composite were performed using microdroplet test and electrical resistance measurements. As AT-PEI content increased, the fracture toughness of epoxy-AT-PEI matrix increased, and interfacial shear strength (IFSS) increased due to the improved fracture toughness by energy absorption mechanisms of AT-PEI phase. The microdroplet in the carbon fiber/neat epoxy composite showed brittle microfailure mode. At 15 phr AT-PEI content ductile microfailure mode appeared because of improved fracture toughness. After curing, the change in electrical resistance $\Delta\textrm{R}$) with increasing AT-PEI content increased gradually because of thermal shrinkage. Under cyclic stress, in the neat epoxy case the reaching time until same stress was faster and their slope was higher than those of 15 phr AT-PEI. The result obtained from electrical resistance measurements under curing process and reversible stress/strain was correspondence well with matrix toughness properties.

In2S3 Co-Sensitized PbS Quantum Dot Solar Cells

  • Basit, Muhammad Abdul;Park, Tae Joo
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.273-273
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    • 2014
  • Quantum-dot sensitized solar cells (QDSCs) are an emerging class of solar cells owing to their easy fabrication, low cost and material diversity. Despite of the fact that the maximum conversion efficiency of QDSCs is still far less than that of Dye-Sensitized Solar Cells (>12 %), their unique characteristics like Multiple Exciton Generation (MEG), energy band tune-ability and tendency to incorporate multiple co-sensitizers concurrently has made QDs a suitable alternative to expensive dyes for solar cell application. Lead Sulfide (PbS) Quantum dot sensitized solar cells are theoretically proficient enough to have a photo-current density ($J_{sc}$) of $36mA/cm^2$, but practically there are very few reports on photocurrent enhancement in PbS QDSCs. Recently, $Hg^{2+}$ incorporated PbS quantumdots and Cadmium Sulfide (CdS) co-sensitized PbS solarcells are reported to show an improvement in photo-current density ($J_{sc}$). In this study, we explored the efficacy of $In_2S_3$ as an interfacial layer deposited through SILAR process for PbS QDSCs. $In_2S_3$ was chosen as the interfacial layer in order to avoid the usage of hazardous CdS or Mercury (Hg). Herein, the deposition of $In_2S_3$ interfacial layer on $TiO_2$ prior to PbS QDs exhibited a direct enhancement in the photo-current (Isc). Improved photo-absorption as well as interfacial recombination barrier caused by $In_2S_3$ deposition increased the photo-current density ($J_{sc}$) from $13mA/cm^2$ to $15.5mA/cm^2$ for single cycle of $In_2S_3$ deposition. Increase in the number of cycles of $In_2S_3$ deposition was found to deteriorate the photocurrent, however it increased $V_{oc}$ of the device which reached to an optimum value of 2.25% Photo-conversion Efficiency (PCE) for 2 cycles of $In_2S_3$ deposition. Effect of Heat Treatment, Normalized Current Stability, Open Circuit Voltage Decay and Dark IV Characteristics were further measured to reveal the characteristics of device.

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