• Composites Research
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• 제26권1호
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• pp.54-59
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• 2013

This study deals with effect of plasma treatment on the properties of unidirectional ligno cellulosic fabric Hildegardia Populofolia (HDP) fabric. Thermal stability of the fabric was determined by differential scanning calorimetry (DSC) and Thermo gravimetric analysis (DSC). Morphological properties was analyzed by SEM analysis and found that the surface was rough upon plasma treatment which provides good interfacial adhesion with matrix during composite fabrication. Thermal stability and mechanical properties of the plasma treated fabric slightly increases compare to alkali and untreated fabric. It was observed that tensile properties of the fabric increases upon plasma treatment due to the formation of rough surface. SEM analysis indicates formation of rough surface on plasma treatment which helps in increasing the interfacial interaction between the matrix (hydrophobic) and fabric (hydrophilic).

• Advanced Composite Materials
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• 제16권4호
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• pp.299-314
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• 2007

In the present study, natural fibers (jute, kenaf and henequen) reinforced thermoplastic (poly(lactic acid) and polypropylene) and thermosetting (unsaturated polyester) matrix composites were well fabricated by a compression molding technique using all chopped natural fibers of about 10 mm long, respectively. Prior to green composite fabrication, natural fiber bundles were surface-treated with tap water by static soaking and dynamic ultrasonication methods, respectively. The interfacial shear strength, flexural properties, and dynamic mechanical properties of each green composite system were investigated by means of single fiber microbonding test, 3-point flexural test, and dynamic mechanical analysis, respectively. The result indicated that the properties of the polymeric resins were significantly improved by incorporating the natural fibers into the resin matrix and also the properties of untreated green composites were further improved by the water treatment done to the natural fibers used. Also, the property improvement of natural fiber-reinforced green composites strongly depended on the treatment method. The interfacial and mechanical results agreed with each other.

• 멤브레인
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• 제8권1호
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• pp.29-41
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• 1998

수용상 MPD(m-phenylene diamine)와 유기상 TMC(trimesoyl chloride)를 사용하여 역삼투 복합막의 활성층 고분자인 aromatic polyamide 제조를 행하고 그 성능을 고찰하였다. 또한 polysulfone 다공성 지지막 위에 박막을 회분, 연속식으로 계면중합 제조한 후, 제조변수에 따른 역삼투 성능을 비교하였다. 회분식으로 복합막을 제조한 결과 유기상 용매의 종류, 단량체의 농도와 함침시간, 열처리 온도, 중화제, 알코올 후처리, 산 후처리 등에 의해 다양한 성능을 나타내었다. 이때, 투과량 향상에는 알코올 후처리 효과가, 또 선택도의 향상에는 단량체의 농도와 함침시간이 변수이었다. 최적조건에서 연속식 공정으로 막모듈을 제조하여 NaCl 5,000 ppm, $25kg_f/cm^2$에서 상용막과 비교할때, 투과량은 33% 증가하고 배제율은 5% 감소하였다.

• 열처리공학회지
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• 제7권3호
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• pp.169-174
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• 1994

The reaction layer formed at interface between matrix and fiber has significant effects on the mechanical properties and behaviors of deformation m FRM. In this study, the mechanical properties and interfacial behaviors according to surface finishing on the fibers and according to heat treatment in FRM were investigated. FRM was fibricated by diffusion bonding method. In W/Al alloy composite and W/Al composite, W of which was coated with $WO_3$, the heat treatment was carried out thermal cycling method from 373K to 673K. In W/Al composite, W of which was coated with $WO_3$, growth of interface layer was hardly occured in spite of the increasing various thermal cycles. It was exhibited that oxidized W/Al composite were higher strength than non-oxidezed W/Al composite with the increasing thermal cycles. The compounds of fiber/matrix interface were analyzed into $WAl_{12}$, $WAl_7$, and $AlWO_3$, respectivly. Therefore the interfacial compounds of fiber/matrix seriously affected the mechanical properties and behaviors of deformation in FRM.

• Elastomers and Composites
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• 제40권1호
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• pp.22-28
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• 2005

본 연구에서는 실리카/고무 복합재료의 기계적 계면 물성과 열안정성에 대한 산소플라즈마의 영향에 대하여 살펴보았다. 실리카의 표면특성은 XPS와 접촉각 측정을 통하여 살펴보았다. 실리카/고무 복합재료의 기계적 물성과 열안정성은 각각 인열에너지 ($G_{IIIC}$)와 열중량분석(TGA)를 통하여 관찰하였다. 실험결과, 플라즈마 처리시간이 증가함에 따라 실리카 표면에 산소가 함유된 극성 관능기의 도입량이 증가하였으며, 이에 따라 고무 복합재료의 인열에너지와 열안정성이 향상되었다. 이러한 결과는 NBR과 같은 극성고무가 산소가 함유된 관능기가 도입된 실리카와 상대적으로 높은 상호작용을 하기 때문으로 판단된다.

• 폴리머
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• 제27권4호
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• pp.299-306
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• 2003

유리 섬유와 고분자로 구성된 복합재료에서는 이종재료 간의 계면 상호작용과 접착력이 재료의 성능과 기능에 큰 영향을 미친다. 따라서 표면처리에 의한 섬유개질 및 계면층 제어는 우수한 복합재료를 제조하는데 있어 매우 중요하다. 본 연구에서는 복합재료 계면에서의 물리화학적 현상을 개선하기 위해 실란커플링제를 이용한 유리 섬유의 형태구조 표면처리방법을 조사하였다. 또한 표면처리조건 (사이징 재료, 농도 등)에 따른 계면 특성과 이와 연관된 미세구조 분석을 통하여 유리 섬유/폴리프로필렌 복합재료의 계면설계기법을 제시하였다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.249-251
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• 2002

It is well known that the interaction and adhesion between the glass fiber(GF) and polymer matrix has a significant effect in determining the properties of fiber-reinforced materials. Therefore, it is one of most important to modify the surface of GF with an appropriate sizing. We investigated the treatment method of GF with coupling agent to improve the interaction of the interfacial regions, and then the correlation between interfacial property and interphase microstructure was examined in an attempt to realize a proper morphology around the GF surface.

• 한국주조공학회지
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• 제35권6호
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• pp.141-146
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• 2015

Aluminum-based hybrid parts were fabricated through a compound casting process with Al or Cu inserts which can be used for applications requiring high conductivity. Because the interface stability between the insert and the aluminum matrix is important, the effects of process variables on the interfacial adhesion strength were investigated. Additions of Cu and Mg to Al melt were found to enhance the adhesion strength, though the melt fluidity was slightly deteriorated when a small amount of Mg was added. An isothermal heating process after casting further improved the strength. However AlCu intermetallic compounds formed and their thickness increased during the heating process. As a result, deterioration in the interfacial adhesion strength was observed after an excessive annealing treatment.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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• pp.115-117
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• 2009

Interface dipole energies between interfacial layers with different thicknesses coated on indium tin oxides (ITOs) and 4,4'-bis[N-(1-naphtyl)-N-phenyl-amino]biphenyl are determined. After $O_2$ plasma treatment on thick-metal (>4 nm) coated ITO, the work function and interface dipole energy increased. In thin-metal (< 2 nm) coated ITO, no change in the interface dipole energy was found though the work function increased. Thus, the $O_2$ plasma treated thin (< 2 nm) interfacial layer reduced the hole injection barrier.

• Carbon letters
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• 제18권
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• pp.1-10
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• 2016

Carbon blacks (CBs) have been widely used as reinforcing materials in advanced rubber composites. The mechanical properties of CB-reinforced rubber composites are mostly controlled by the extent of interfacial adhesion between the CBs and the rubber. Surface treatments are generally performed on CBs to introduce chemical functional groups on its surface. In this study, we review the effects of various surface treatment methods for CBs. In addition, the preparation and properties of CB-reinforced rubber composites are discussed.