• Bulletin of the Korean Chemical Society
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• v.33 no.12
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• pp.4145-4149
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• 2012

A novel and simple method of luminescence enhancement effect for the determination of trace amounts of bile acid was proposed. The procedure was based on the luminescence intensity of the balofloxacin-europium(III) complex that could be strongly enhanced by bile acid in the presence of sodium dodecyl benzene sulfonate (SDBS). Under the optimum conditions, the enhanced luminescence intensity of the system exhibited a good linear relationship with the bile acid concentration in the range $5.0{\times}10^{-9}-7.0{\times}10^{-7}\;mol\;L^{-1}$ with a detection limit of $1.3{\times}10^{-9}\;mol\;L^{-1}$ ($3{\sigma}$). The relative standard deviation (RSD) was 1.7% (n = 11) for $5.0{\times}10^{-8}\;mol\;L^{-1}$ bile acid. The applicability of the method to the determination of bile acid was demonstrated by investigating the effect of potential interferences and by analyzing human serum and urine samples. The possible enhancement mechanism of luminescence intensity in balofloxacin-europium(III)-bile acid-SDBS system was also discussed briefly.

• Applied Chemistry
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• v.15 no.1
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• pp.37-40
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• 2011

A chemiluminescent method with silver nanoparticles for determination of L-alanine has been presented. The chemilumiscence intensity was further enhanced by silver nanoparticles in the luminol system by its catalytic role. The silver nanoparticles enhanced chemiluminescent method is applicable for the determination of an amino acid such as alanine. When alanine was introduced to the luminol system with silver nanoparticles, chemiluminescence intensity was reduced with the concentration of the added alanine. The effects of pH, concentrations of luminol, hydrogen peroxide and silver nanoparticles on the chemiluminescence intensity were investigated. The calibration curve for L-alanine was linear over the range from 6.60×10^-8 M to 4.00×10^-7 M, coefficient of correlation was 0.996 and detection limit was 3.5×10^-9 M under the optimal conditions of 4.0×10^-3 M, 4.0×10^-2 M, 4.0×10^-4 M, 12.8 for the concentration of luminol, H₂O₂, silver nanoparticles and pH, respectively.

• International Journal of Highway Engineering
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• v.13 no.1
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• pp.157-168
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• 2011

Recently, the cases of freeze-thaw distress on concrete pavement in domestic have been reported periodically. Hereupon, the necessity to establish the standard of spacing factor came to the fore. The test method for analyzing spacing factor is provided in the standard of ASTM C 457. Since researchers tend to judge study results subjectively, the results should be revised throughly. Image analysis program for determining the characteristics of air-void system on hardened concrete identify air void through the difference of a color. The pixel intensity values used in this program have a significant effect on the analysis results. This study compared the automated void count by varying pixel intensity values with the manual void count in order to determine the optimum range of pixel intensity values. Also, this study analyzed the air-void characteristics on eight kinds of concrete mixtures. In this study, it was confirmed that the variation of void counted manually was around 10% from the results of round robin test, and that the optimum range of pixel intensity values is around 80~90. And it was also confirmed that air content (as a whole) was increased generally and spacing factor was decreased by increasing air-entrainer content. But some concrete mixtures showed a tendency that air content was constant and spacing factor was decreased by increasing air-entrainer content. This causes the air entrained by air-entrainer has more influence on spacing factor than air content. Also, the deviation of spacing factor by cutting position of concrete specimen was about 30~100${\mu}m$ because of the limit of 2-D image analysis. The additional study about variation of spacing factor by cutting position of concrete specimen will be performed later.

• Journal of Korean Society of Forest Science
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• v.85 no.3
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• pp.396-408
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• 1996

The purposes of this study were to standardise the forest working system to design the intensity of working system in felling operation of the thinning forest in our country as well as to contrive the improvement of working method and the increase of productivity. For the purpose of investigating these, element working was classified by felling operation in softwood thinning forest, and a pulse rate were measured and analyzed. The results were as follow : 1. From the analysis of the pulse frequence measurment, the average pulse showed 108 pulse per minute for worker A in the total of pure working time, 130 pulse per minutes for worker B, 119 pulse per minute for worker C and 125 pulse per minute for worker D, respectively. 2. From the results of the pulse frequence analysis according to element working classification, the highest pulse frequence represented 115 pulse per minute for worker A in the circumference, 131 pulse per minute for worker B in the movement, 122 pulse per minute for worker C in the limbing operation and 128 pulse per minute for work D in hang-up. 3. If the original pulse frequence was 100% for workers, the working intensity showed as follow : worker A was 160%(original pulse frequence was 61=100%) for the total of the working intensity and 188% for the circumference among element working. Worker B was 220%(original pulse frequence was 57=100%) for the total of the working intensity and 229 for movement among element working. Worker C was 159%(original pulse frequence was 73=100%) for the total of the working intensity and 168% for limbing operation among the element working. Worker D was 156%(original pulse frequence was 70=100%) for the total of working intensity and 182% for hang-up among element working. 4. At the limit point of Labor performance rating, showing the total of working intensity, overtime pulse rate per minute was 30 for worker A, 207 for worker B, 14 for worker C and 67 for worker D. Worker B was highest in working intensity, and got physically a big load.

• Structural Engineering and Mechanics
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• v.22 no.3
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• pp.293-310
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• 2006

In seismic prone areas it is possible to meet very different objects (equipment components, on shelf artefacts, simple architectural elements) that can be modelled as a rigid body rocking on a rigid foundation. The interest in their behaviour can have different reasons: seismological, in order to estimate the ground motion intensity, or more strictly mechanical, in order to limit the response severity and to avoid overturning. The behaviour of many rigid bodies subjected to twenty wide ranging acceleration recordings is studied here. The response of the blocks is described using kinematic and energy parameters. A condition under which a so called scale effect is tangible is highlighted. The capacity of the signals to produce overturning is compared to different ground motion parameters, and a good correlation with the Peak Ground Velocity is unveiled.

• Ceramist
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• v.10 no.3
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• pp.91-97
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• 2007

Femtosecond laser micro-processing received much attention in the past decade. The nature of ultra-short light-matter interaction permits femtosecond laser to overcome the diffraction limit and realize precise micro-processing. The ultrahigh light intensity of the femtosecond laser allows sapece-selective microscopic modifications to materials based on multiphoton processes. In this paper, we review our recent research development on space-selective precipitation and control of functional crystals in glasses by an infrared femtosecond laser. The technique will open new possibilities in the fabrication of micro-optical components with various optical functions.

• Journal of the korean Society of Automotive Engineers
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• v.3 no.3
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• pp.30-38
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• 1981

The fatigue characteristics of Si-Mn spring steel (AISI 9260-H, JIS SUP-6) were investigated on several heat treatment conditions. Repeated impact loads of 10kg-cm and 15kg-cm energy were applied with a cam roller drop hammer type impact fatigue testing machine. Specimens were oil-quenched, and tempered at 350.deg. C, 450.deg. C and 500.deg. C, respectively. Results obtained in these experiments are summarized as follows.; 1) The fatigue life of the specimen is decreased as the magnitude of constant impact energy is increased, regardless of heat treatment. 2) Generally, the fatigue life of the specimen is decreased as the tensile strength of the materials is increased. 3) Within the limit of these experiments, the fatigue life showed abrupt decrease at the tempering temperature of about 400.deg. C 4) The fatigue life is increased as the initial value of applied stress intensity factor(K$_{1}$) is decreased. This tendency is apparent for the low tensile strength materials.

• Journal of Ocean Engineering and Technology
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• v.5 no.2
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• pp.58-66
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• 1991

Not only difference of fatigue crack growth and propagation behavior resulted from the grain size, the hardness ratio and volume fraction in M.E.F. dual phase steel composed of martensite in hard phase and ferrite in soft phase, but also the effects of the plastic constraint were investigated by fracture mechanics and microstructural method. The main results obtained are as follows: 1) The fatigue endurance of M.E.F. steel increases with decreasing the grain size, increasing the ratio of hardness and volume fraction. 2) The initiation of slip and crack occures faster as the stress level goes higher. These phenomena result from the plastic constraint effect of the second phase. 3) The crack propagation rate in the constant stress level is faster as the grain size gets larger, the ratio of hardness lower and volume fraction smaller.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.6
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• pp.42-48
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• 1999

Engine misfire causes of the negative effect on exhaust emission such as HC, CO, and NOX . Moreover, it causes damage to the three-way-catalyst(TWC) system permanently. The crankshaft velocity fluctuation(CVF) method has been applied for the real cars as misfire detection system usually, which utilizes the crank angle sensor input to calculate the variation of the crankshaft rotational speed. But this approach has the limit due to the fact that three could be problem under certain engine condition like as deceleration or high speed condition . Therefore the development of new methods are requested today. This study introduced the new method of misfire detection using breakdown voltage(BDV) characteristics between spark plug electrouds.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.5
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• pp.421-432
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• 1998

Deposition processes limit the life time of pollutants in the atmosphere and control the distance travelled before deposition. Thus the understanding about atmospheric deposition processes is essential for a proper assessment of the environmental impacts due to the anthropogenic pollutants. The dry deposition velocities are related to surface types, atmospheric stabilities, friction velocities, air pollutants and so on. In this study we simulated the dry deposition velocities of O3 in Pusan region. The calculated deposition velocities compared to the observed O3 data obtained during the summer of 1988 over a deciduous forest in Canada. The comparison showed that the model somewhat overpredicted deposition velocities for the average diurnal variations with maxima in daytime and minima in nighttime mostly due to the turbulence intensity.