• Title/Summary/Keyword: Inorganic scale

Search Result 150, Processing Time 0.027 seconds

Review on Reprocessing Techniques for Mineral Wastes (광산폐기물의 재활용 기술 동향과 전망)

  • 최우진
    • Economic and Environmental Geology
    • /
    • v.37 no.1
    • /
    • pp.113-119
    • /
    • 2004
  • Mineral wastes are generated by the minerals, mining, and metal industries. These are generally inorganic waste streams of mainly waste rock or residues from refining during extraction of metals or minerals from the ore. There are many plants where minerals are recovered in secondany circuits, treating tailings, where the feed grades are much lower than would be economic on a mined ore. The world is now becoming aware of the finite nature of its resources at a price, and of the ever-increasing development costs of large new mines. Reprocessing of old tailings on a large scale must be worth examining very seriously by those with access to sufficient material of this type. In the present paper, mineral separation techniques to recover valuable metals and resources from the old tailings are reviewed, and new trends for future developments are also discussed.

$C_a/C_c$ for Soft Clay at the Southern Port of Korea by Laboratory Consolidation Tests (실내압밀시험에 의한 남해안지역 연약점토의 $C_a/C_c$ 평가)

  • 김규선;임형덕;이우진
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 1999.02a
    • /
    • pp.70-77
    • /
    • 1999
  • Consolidation settlements on soft clay are often large and potentially damaging to structures. Currently, large-scale projects are in progress in Korea. These structures will be constructed on both thick and soft clay layers, and so the accurate evaluation of magnitude of settlement is required at every step in design and construction. Especially, secondary compression play an important role in consolidation settlements on soft clay. Generally, the magnitudes of secondary compression are evaluated by laboratory and in-situ consolidation tests or by empirical $C_{a/}$ $C_{c}$ relationships. The empirical $C_{a/}$ $C_{c}$ may not be only economical, but a fast and powerful tool in estimating secondary consolidation settlement. However, databases of the $C_{a/}$ $C_{c}$ relationship for sites in Korea are currently insufficient. The purpose of this study is to investigate the relationship of $C_{a/}$ $C_{c}$, on marine clay near the southern sea in Korea. In this study a series of incremental loading consolidation tests (measuring base pore water pressure) are performed. It was found that the $C_{a/}$ $C_{c}$ on undisturbed marine clay equaled 0.0397. This value is similar to the value proposed by Mesri and Castro(1987) for inorganic clay and silt. and silt. and silt.

  • PDF

Effects of applied voltages on nano-structures of anodized metal oixdes and their electrochromic applications (인가 전압에 따른 양극산화된 금속 산화물의 나노 구조 변화와 전기변색 응용)

  • Kim, Tae-Ho;Lee, Jae-Uk;Kim, Byeong-Seong;Jeon, Hyeong-Jin;Na, Yun-Chae
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2016.11a
    • /
    • pp.115.1-115.1
    • /
    • 2016
  • Electrochemical anodization has been interested due to its useful way for the nano-scale architecture of metal oxides obtained from a metal substrate. By using this method, it is easy to control the morphology of the oxide materials by controlling electrochemical conditions. Among oxide materials obtained from the transition metals such as Ti, V, W, etc., in this paper, the morphological study of anodized $TiO_2$ was employed at various voltage conditions in fluoric based electrolyte, and the effects of applied voltage (sweep rate and retention time) on the tube morphologies were investigated. Furthermore, by using anodization of tungsten substrate (W), we fabricated the porous structure of $WO_3$ and provided merits of tailored structure for the hybridization of inorganic and organic materials as electrochromic (EC) applications. The hybrid porous $WO_3$ shows multi-chromic properties during the EC reactions at specific voltage conditions. From these results, the anodization process with tailoring nano-structure is one of the promising methods for EC applications.

  • PDF

Inorgainc fouling and it fouling reduction in direct contact membrane distillation process (직접 접촉식 막 증발공정에서 무기 막오염 특성 분석 및 저감방법)

  • Lee, Tae-Min;Kim, Seung-Hyun
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.34 no.2
    • /
    • pp.115-125
    • /
    • 2020
  • This study was aimed to examine inorganic fouling and fouling reduction method in direct contact membrane distillation(DCMD) process. Synthetic seawater of NaCl solution with CaCO3 and CaSO4 was used for this purpose. It was found in this study that both CaCO3 and CaSO4 precipitates formed at the membrane surface. More fouling was observed with CaSO4(anhydrite) and CaSO4·0.5H2O(bassanite) than CaSO4·2H2O(gypsum). CaCO3 and gypsum were detected at the membrane surface when concentrates of SWRO(seawater reverse osmosis) were treated by the DCMD process, while gypsum was found with MED(multi effect distillation) concentrates. Air backwash(inside to out) was found more effective in fouling reduction than air scouring.

Effects of Potassium Sulfamate on Synthesis of Pottassium Dinitramide (포타슘디나이트라아마이드의 합성에 대한 술팜산칼륨의 영향 연구)

  • Kim, Woo-Ram;Huang, Shan;Kwon, Youn-Ja;Jo, Young-Min;Park, Young-Chul
    • Journal of the Korean Applied Science and Technology
    • /
    • v.30 no.1
    • /
    • pp.57-63
    • /
    • 2013
  • Ammonium dinitramide (AND) is one of the most promising oxidizers in propellants without chlorinated pollution to the atmosphere in these days. Potassium sulfamate (PS) is a key substance in ADN synthesis as forming nitrates such as $-N(NO_2)_2$. In this paper, potassium sulfamate as a starting material for ADN synthesis was prepared in a lab scale through crystallization with ethanol solvent, and observed the effects on the yield and purity of KDN. The prepared potassium sulfamates were analyzed using FE-SEM, XRD, BET and TGA-DSC. The lab-made PS, which was ground to $20{\mu}m$ showed more beneficial than a commercial product achieving high yield and purity of the synthesized KDN. It would be associated closely with crystallinity, porosity and pore size of prepared PS.

Preperation of CuInSe2 Nanoparticles by Solution Process Using Precyrsors

  • Choe, Ha-Na;Lee, Seon-Suk;Jeong, Taek-Mo;Kim, Chang-Gyun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.08a
    • /
    • pp.376-376
    • /
    • 2011
  • I-III-VI2 chalcopyrite compounds, particularly copper, indium, gallium selenide(Cu(InxGa1-x)Se2, CIGS), are effective light-absorbing materials in thin-film solar application. They are direct band-gap semiconductors with correspondingly high optical absorption coefficients. Also they are stable under long-term excitation. CIS (CIGS) solar cell reached conversion efficiencies as high as 19.5%. Several methods to prepare CIS (CIGS) absorber films have been reported, such as co-evaporation, sputtering, selenization, and electrodeposition. Until now, co-evaporation is the most successful technique for the preparation of CIS (CIGS) in terms of solar efficiency, but it seems difficult to scale up. CIS solar cells have been hindered by high costs associated with a fabrication process. Therefore, inorganic colloidal ink suitable for a scalable coating process could be a key step in the development of low-cost solar cells. Here, we will present the preparation of CIS photo absorption layer by a solution process using novel metal precursors. Chalcopyrite copper indium diselenide (CuInSe2) nanocrystals ranging from 5 to 20nm in diameter were synthesized by arrested precipitation in solution. For the fabrication of CIS photo absorption layer, the CuInSe2 colloidal ink was prepared by dispersing in organic solvent and used to drop-casting on molybdenum substrate. We have characterized the nanoparticless and CIS layer by XRD, SEM, TEM, and ICP.

  • PDF

Graphene for MOS Devices

  • Jo, Byeong-Jin
    • Proceedings of the Materials Research Society of Korea Conference
    • /
    • 2012.05a
    • /
    • pp.67.1-67.1
    • /
    • 2012
  • Graphene has attracted much attention for future nanoelectronics due to its superior electrical properties. Owing to its extremely high carrier mobility and controllable carrier density, graphene is a promising material for practical applications, particularly as a channel layer of high-speed FET. Furthermore, the planar form of graphene is compatible with the conventional top-down CMOS fabrication processes and large-scale synthesis by chemical vapor deposition (CVD) process is also feasible. Despite these promising characteristics of graphene, much work must still be done in order to successfully develop graphene FET. One of the key issues is the process technique for gate dielectric formation because the channel mobility of graphene FET is drastically affected by the gate dielectric interface quality. Formation of high quality gate dielectric on graphene is still a challenging. Dirac voltage, the charge neutral point of the device, also strongly depends on gate dielectrics. Another performance killer in graphene FET is source/drain contact resistance, as the contact resistant between metal and graphene S/D is usually one order of magnitude higher than that between metal and silicon S/D. In this presentation, the key issues on graphene-based FET, including organic-inorganic hybrid gate dielectric formation, controlling of Dirac voltage, reduction of source/drain contact resistance, device structure optimization, graphene gate electrode for improvement of gate dielectric reliability, and CVD graphene transfer process issues are addressed.

  • PDF

High-Temperature Oxidation Behavior of TiN-Ti5Si3 Ceramic Composites Manufactured by Polymer Pyrolysis (고분자 열분해 방법으로 제조된 TiN-Ti5Si3 세라믹 복합체의 고온 산화 거동)

  • Kim, Beom-Seob;Kim, Deug-Joong;Lee, Dong-Bok
    • Journal of the Korean Ceramic Society
    • /
    • v.43 no.8 s.291
    • /
    • pp.486-491
    • /
    • 2006
  • A new $TiN-Ti_5Si_3$ bulk composite was synthesized from preceramic, inorganic polymer (methylpolysilsesquioxane) and $TiH_2$ filler powders via polymer pyrolysis. Using this process, ceramics with high melting points can be produced relatively easily to a near net shape. The $TiN-Ti_5Si_3$ composite oxidized slowly during heating to $1000^{\circ}C$. During heating at the temperatures of at 700 and $800^{\circ}C$, TiN oxidized to Rutile-$TiO_2$ whereas $Ti_5Si_3$ resisted to oxidation. The oxide scale formed consisted primarily of $TiO_2$ containing $Ti_5Si_3$.

Heat transfer characteristics of Immersed Coil Type Latent Heat Storage Tank (내부코일형 잠열 축열조에서의 열전달 특성 연구)

  • Lee, W.K.;Han, G.Y.;Kang, Y.H.
    • Journal of the Korean Solar Energy Society
    • /
    • v.21 no.1
    • /
    • pp.83-91
    • /
    • 2001
  • The heat transfer experiment in a pilot scale latent heat storage tank as a solar energy storage system for the hot water supply was carried out. The latent heat storage tank was consisted of three parts; Outer shell for hot water from solar collector, PCM storage vessel in the middle of the tank and immersed coil in the PCM vessel for hot water recovery. The heat storage tank has the dimension of 115 cm in height and 32 cm outside diameter. Paraffin wax (m.p = 55.4C) and sodium acetate trihydrate (m.p = 58 C) were employed as the PCM this study. Experimental variables were inlet temperature and flow rate of the hot water for heat storage stage and cold water for heat recovery stage. Temperature profiles, heat transfer coefficient and the efficiency of heat storage $(Q/Q_{max})$ and heat recovery $(Q/Q_{max})$ were determined for the paraffin wax and inorganic salt respectively.

  • PDF

Accumulation of Food Wastes Liquid Fertilizer using Reverse Osmosis Membrane System (역삼투막을 이용한 음식폐기물 액비의 농축)

  • Cha, Gi-Cheol;Hwang, Myoung-Goo;Lee, Myung-Gyu;Tae, Min-Ho
    • Journal of Korean Society on Water Environment
    • /
    • v.18 no.2
    • /
    • pp.159-168
    • /
    • 2002
  • A lab-scale Reverse Osmosis(RO) membrane reactor was installed to investigate the membrane permeability, characteristics of membrane fouling at each conditions, and performance of elimination at different trans-membrane pressure(TMP) in the liquid fertilizer accumulated system. Experimental setup was divided to three different TMP conditions. As a result of experiment, permeability of RO membrane was proportional to the increase of TMP and temperature. After experiment was completed, two types chemical cleaning(remove the organic foulant and inorganic foulant) was done, and recover rate of permeability was each 99.8, 99.7 and 99.7%, respectively. From this experimental data, membrane fouling could be determined that the most of it was recoverable in this system, and major reason of fouling was concentration polarization. Elimination rate of solute substance in the liquid fertilizer indicated very stable(above 99%), except ammonia nitrogen, and the most stable elimination rate was investigated at the highest TMP condition (Run 3).