• 제목/요약/키워드: Inorganic scale

검색결과 150건 처리시간 0.031초

Nano Fabrication of Functional Materials by Pulsed Laser Ablation

  • 윤종원
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 추계학술발표대회
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    • pp.6.2-6.2
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    • 2009
  • Nanostructured materials arecurrently receiving much attention because of their unique structural andphysical properties. Research has been stimulated by the envisagedapplications for this new class of materials in electronics, optics, catalysisand magnetic storage since the properties derived from nanometer-scalematerials are not present in either isolated molecules or micrometer-scalesolids. This study presents the experimental results derived fromthe various functional materials processed in nano-scale using pulsed laserablation, since those materials exhibit new physical phenomena caused by thereduction dimensionality. This presentation consists of three mainparts to consider in pulsed laser ablation (PLA) technique; first nanocrystallinefilms, second, nanocolloidal particles in liquid, and third, nanocoating fororganic/inorganic hybridization. Firstly, nanocrystalline films weresynthesized by pulsed laser deposition at various Ar gas pressures withoutsubstrate heating and/or post annealing treatments. From the controlof processng parameters, nanocystalline films of complex oxides and non-oxidematerials have been successfully fabricated. The excellentcapability of pulsed laser ablation for reactive deposition and its ability totransfer the original stoichiometry of the bulk target to the deposited filmsmakes it suitable for the fabrication of various functionalmaterials. Then, pulsed laser ablation in liquid has attracted muchattention as a new technique to prepare nanocolloidal particles. Inthis work, we represent a novel synthetic approach to directly producehighly-dispersed fluorescent colloidal nanoparticles using the PLA from ceramicbulk target in liquid phase without any surfactant. Furthermore, novel methodbased on simultaneous motion tracking of several individual nanoparticles isproposed for the convenient determination of nanoparticle sizedistributions. Finally, we report that the GaAs nanocrystals issynthesized successfully on the surface of PMMA (polymethylmethacrylate)microspheres by modified PLD technique using a particle fluidizationunit. The characteristics of the laser deposited GaAs nanocrytalswere then investigated. It should be noted that this is the first successfultrial to apply the PLD process nanocrystals on spherical polymermatrices. The present process is found to be a promising method fororganic/inorganic hybridization.

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생태계를 이용한 자원절약형 단지계획기법 개발에 관한 연구 - 주거단지를 중심으로- (A Study on development of Resourse - saving site Planning techniques based on utilization of Ecosystem - Focused on Housing site -)

  • 이영무
    • 한국조경학회지
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    • 제18권2호
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    • pp.111-125
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    • 1990
  • Korea is a nation with poor natural resources. There is a greats need to save resources that are running out in fast face. The purpose of this thesis is to bind the means to save rosources in housing site, especially in highrise apartment. The reason why the high-rise apartments are chosen as a case is 7hat the high-rise is becoming the major form of dwelling in most urban areas. As a tool of saving the ecological way is chosen because ecological energy is free, clean and unlimited. The resources to be saved are divided into two categories, namely energy and non - energy resources as water, land and food. The contents of the thesis are comprised of 4 chapters. The early chaspters are devoted to the understanding of the ecosystem and problems of current energy consumption in the apartment. It is fellowed by the introduction of the hypothesis that can possibly save reouruces. The hypothesis are then transformed into the actual theories through verification, to be established as the new techniques of the site planning. The ecosystem is the functional relationship between the living organisms and their physical surroundings. The living organisms are the plants that produce, animals that consume and bacterias that decompose. They live in the environment which consists of the three worlds of atmosphere, hydrosphere and lithosphere. The whole system is activated by the solar energy that turns the inorganic mallet- into the living organism and back to the inorganic. It is the recycling principle of the ecosystem. The elements of ecosystem that fan be unilimited as the tools of resources -saving are the sun, wind, water, soil, plant and waste. They are unlimited sources of energy. free of pollution and cheap in price. Each of these ecological elements Provide the opportunities that can save the heating fuel, air conditioning energy, water resource, land and food. The ecological approch should be pursued actively in this age of short resources and growing pollution. In the scale of total energy consumption the housing takes the second position next to the industrial use. It is followed by the transportation which shows for less consumption than former two.

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Wet/dry Repetitions of Centennial Scale Reconstructed by Inorganic Chemistry of the Mid-Holocene Hwayang Wetland in the West Coast of Korea

  • Yang, Dong-Yoon;Kim, Ju-Yong;Nahm, Wook-Hyun;Yi, Sang-Heon;Kim, Jin-Kwan;Kim, Jeong-Chan;Lee, Jin-Young
    • 한국제4기학회지
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    • 제21권2호
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    • pp.69-73
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    • 2007
  • Inorganic geochemical and mineralogical analyses from the trench sediments of the Hwayang wetland were carried out to verify the wet/dry conditions during 6000 - 5000 yr BP and abnormal event of 6300 yr BP of Korean west coast. Lithostratigraphy, mineralogy and major element concentrations of the sediments of the trench indicate that during 6000 - 5000 yr BP, a wet/dry conditions might be repeated at an interval of 200 years. Carbonate minerals precipitated with the decrease of water depth in the lake or wetland after about 6000 yr BP. On the other hand, the sediments coarser in mean grain size and larger in standard deviation were corresponded with periods of 6300 yr BP and 6230 yr BP. Especially, such a feature of grain size distribution of 6300 yr BP appears in other wetlands situated in the west coast, e.g., Hwangsan wetland and Cheollipo coastal wetland. During the period, the coarse sediments seem to have been delivered by a high energy like storming.

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Diphosil 이온교환수지에 의한 $^{137}Cs,\;^{60}Co$의 이온교환 거동 (Ion Exchange Behavior of $^{137}Cs,\;^{60}Co$ on Diphosil, a new ion exchange resin)

  • 김수정;이상진;양호연;신상운
    • Journal of Radiation Protection and Research
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    • 제29권1호
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    • pp.1-8
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    • 2004
  • ANL에서 개발한 유 무기 복합의 신이온교환수지인 Diphosil은 silica 물질에 diphosphonic acid 그룹을 결합시킨 구조를 가지고 있다. Diphosil을 원전 운영 중 발생되는 방사성폐액 처리에 적용하기 위해 주대상 핵종인 $^{137}Cs,\;^{60}Co$을 사용하여 흡착 평형과 컬럼 실험을 수행하였다. 흡착 평형 실험을 통하여 $^{137}Cs$$^{60}Co$의 제거율과 그 제거율에 미치는 다양한 조건에서 비방사성 이온의 영향을 조사하였다. 대상 핵종에 대한 파과곡선은 모의 방사성 폐액을 이용한 실험실 수준의 컬럼 실험을 통해 구하였고, Diphosil의 제거능력을 현재 원전에서 쓰이고 있는 Amberlite IRN 77 수지와 비교하였다.

고력볼트 접합부표면의 방식도장변수에 따른 체결력 평가 (Evaluation on Clamping Force of High Strength Bolts By Coating Parameters of Faying Surfaces)

  • 나환선;이현주
    • Corrosion Science and Technology
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    • 제11권2호
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    • pp.48-55
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    • 2012
  • Clamping force of a high strength bolt is reduced by a certain period of time after the initial set-up. In case of special treatments on faying surfaces such as protective coating, clamping force is relaxed more severely. Tests for slip critical joints subject to various faying surface parameters were conducted. Five different surface treatments were tested including mill scale surface, blast surface, rust surface and coated surfaces. Each specimen was composed of F10T M20 of high strength bolts and steel plates. Based on the result of slip coefficient test, blast treatment surface showed 0.59, rust treatment surface showed 0.54 and inorganic zinc treatment surface exhibited 0.44. Clean mill treatment surface and red lead paint treatment surface were 0.23, 0.21 respectively. It is identified that the slip coefficient in Korean structural design guide should be determined for various surface conditions. Subsequently from long term relaxation test of ASTM A 490 high strength bolts, relaxation of no-coated surfaces such as blast, clean mill, rust treatment, the loss of initial clamping load was 10.5%, 13.6% and 7.9% for 1,000 hours, while the loss of initial clamping force was reached as 15.0%, 18.7% more than the required redundancy 10% in case of inorganic zinc and red lead painted treatment. It is required that the limit of relaxation on coated faying surface should be established separately for various surfaces.

농촌지역 혼합건설폐기물의 중·소규모 배출현장용 이동식 분리선별기 개발을 위한 기초연구 (A Basic Study on the Mobile Separator and Sorter Development of Small and Medium-sized Discharge Site's Mixed Construction Waste in Rural Area)

  • 김병윤;박지선
    • 한국농촌건축학회논문집
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    • 제21권3호
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    • pp.17-24
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    • 2019
  • This study aimed to develop a mobile separating and sorting device for discharge sites to separate and sort mixed construction waste generated in small and medium scale in small provincial cities into inorganic materials and combustible materials. The study results can be summarized as follows: 1) As a result of analyzing the existing domestic technology for the separating and sorting mixed construction waste, a device sorting the waste by fusing the vibration screen, disc screen, air blowing methods and the separating and sorting the combustible waste is applied in Korea. 2) In foreign countries, the air blowing, screen, gravity sorters are used for separating and sorting combustible waste in the same way as in Korea. Especially German T Company suggests a construction waste separating and sorting system using an optical sorter. 3) As for the test device for separating and sorting mixed construction waste to be buried in landfill, the processing capacity was set as 16 tons per day. 4) For separating and sorting inorganic materials by granularity, this study set a trommel with two types of diameter as a basic. To operate the mobile all-in-one system, the device is designed to locate a conveyor, a combustible waste conveying device, inside of the trommel. 5) The device is designed in a mobile mode under the concept of primary separating and sorting device, and it can be transported using a 2.5-ton truck minimum. The diameter and length of the trommel are designed to be within 1500mm and 3000mm, respectively. In a further study, an optimized separating and sorting technology is planned to be presented through an experimental study for processing efficiency analysis at the mixed construction waste site by manufacturing the pilot experiment facility reflecting the design elements in the result of this study.

유무기 융복합 흡착제의 아세트알데하이드 제거 성능 평가 (Evaluation of acetaldehyde removal performance of a hybrid adsorbent consisting of organic and inorganic materials)

  • 안해영;이윤경;송지현
    • 실내환경 및 냄새 학회지
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    • 제17권4호
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    • pp.372-380
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    • 2018
  • To abate the problem of odor from restaurants, a hybrid adsorbent consisting of organic and inorganic materials was developed and evaluated using acetaldehyde as a model compound was deveioped and evaluated. Powders of activated carbon, bentonite, and calcium hydroxide were mixed and calcinated to form adsorbent structure. The surface area of the hybrid adsorbent was smaller than that of high-quality activated carbon, but its microscopic image showed that contours and pores were developed on its surface. To determine its adsorption capacity, both batch isotherm and continuous flow column experiments were performed, and these results were compared with those using commercially available activated carbon. The isotherm tests showed that the hybrid adsorbent had a capacity 40 times higher than that of the activated carbon. In addition, the column experiments revealed that breakthrough time of the hybrid adsorbent was 2.5 times longer than that of the activated carbon. These experimental results were fitted to numerical simulations by using a homogeneous surface diffusion model (HSDM); the model estimated that the hybrid adsorbent might be able to remove acetaldehyde at a concentration of 40 ppm for a 5-month period. Since various odor compounds are commonly emitted as a mixture when meat is barbecued, it is necessary to conduct a series of experiments and HSDM simulations under various conditions to obtain design parameters for a full-scale device using the hybrid adsorbent.

가축에서 시기별 혈액 성분과 도체 형질에 대한 표현형 상관에 관한 연구 (Phenotypic Correlation between Carcass Traits and Serum Profiles taken Before and After Slaughter of Hanwoo Bulls and Steers)

  • 전기준;최연호;조규호;김명직;김형철;최재관;이창우;황정미;김종복
    • 한국수정란이식학회지
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    • 제20권3호
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    • pp.239-253
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    • 2005
  • 한우의 혈액성분과 도체형질간의 상관관계를 구명하여 도체 품질을 예측하고 예견되는 능력에 따른 사양관리로 도체품질을 향상시키고자 한우에서 도축 2개월 전과 수송전 그리고 도살시 혈청성분 농도와 도체 형질간의 표현형 상관을 분석한 결과는 아래와 같다. 1. 거세우의 도살 2개월 전 혈청 성분 농도와 도체 형질간의 상관에서 육량지수는 total protein (0.23), albumin(0.26), calcium(0.31)과 정의상관이나 BUN (-0.30)과는 음의 상관관계가 있었으며, 배최장근단면적은 BUN(0.17), globulin(0.16)과 정의 상관이 있었다. 등지방두께는 BUN(0.42) 및 inorganig phosphorus (0.20)와 정의상관관계이나 total protein(-0.23), albumin(-0.33) 및 calcium(-0.33)과 음의 상관관계가 있었다. 그리고 근내지방도는 BUN (0.28)과는 정의 상관관계가 그리고 IGF-I 및 calcium과는 음의 상관관계가 있었다. 2 거세우의 수송전 혈청성분 농도와 도체형질간의 상관관계를 살펴보면, 배최장근단면적은 TP(-0.16) 및 BUN(-0.15)과 음의 상관이었고, 등지방두께는 IGF-I(-0.21), glucose (-0.21), creatinine(-0.19) 및 inorganic phosphorus (-0.18)와 음의 상관을 나타내었으며, 근내지 방도는 creatinine (-0.16)과 음의 상관관계가 있었다. 3, 거세우의 도살시 혈청 성분 농도와 도체형질간의 상관에서 육량지수는 연령을 보정한 calcium과 정의 상관(0.31)이었고, 생체중은 BUN(0.17)과 정의 상관이었으며, 배최장근단 면적은 albumin(-0.19)과 음의 상관을 나타내었고, 등지방두께는 연령으로 보정되어 calcium(-0.38)과 음의 상관이었고, 근내지방도는 연령으로 보정 한 calcium(-0.17)과 음의 상관을 나타내었다. 4. 도살 2개월 전 혈청 성분 농도와 도체 형질들간의 상관에서 육량지수는 testosterone 및 caicium과 0.71 및 0.67로 높은 상관이었고 inorganic phosphate와 -0.71의 높은 음의 상관을 보였다. 생체중은 calcium과 0.67의 높은 정의 상관이었으나, 도체중은 glucose와 -0.69의 음의 상관이었다. 등지방두께는 cortisol 및 inorganic phosphate(IP)와 0.29 및 0.69)로 정의 상관이었으며, 근내지방도는 creatinine과 -0.81로 높은 음의 상관이었으나 BUN과는 0.87로 높은 정의 상관관계를 나타내었다. 수송 감량은 albumin 및 inorganic phosphate와 0.77, 0.83로 높은 수준의 정의 상관관계를 나타내었다. 5. 비거세우의 수송전 혈청 성분 농도와 도체 형질들 간의 상관에서 육량지수는 testosterone과 0.66으로 정의 상관이었고, 도체율은 globulin과 0.73으로 높은 상관을 나타내었다. 등지방두께는 testosterone과 -0.60의 음의 상관이었고. 배최장근단면적은 testosterone과 0.40의 정의 상관이었고 근내지방도와 creatinine 농도간에는 -0.55의 비교적 높은 음의 상관계수가 추정되었으나 유의성은 인정되지 않았다. 6. 한우 비거세우의 도살시 혈청 성분 농도와 도체형질과의 상관에서 육량지수는 연령에 대해 보정한 HDLC 농도와 -0.71의 음의 상관이었으며, 도체율은 globulin과 0.70의 높은 정의 상관이었고, 등지방두께는 연령으로 보정된 HDLC와 0.69로 정의 상관관계를 보였다. 도체중은 triglyceride와 0.51의 정의 상관, 배최장근단면적은 testosterone과 -0.91, 근내지방도는 creatinine 및 glucose와 -0.58의 비교적 높은 상관을 보였으나 유의성이 인정되지 않았다.

침지형 MBR공정에서 파울링 특성과 파울링 완화제의 적용성에 관한 연구 (A Study on Fouling Characteristics and Applicability of Fouling Reducer in Submerged MBR Process)

  • 박준원;박홍준;김민호;오용걸;박철휘
    • 대한환경공학회지
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    • 제35권5호
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    • pp.371-380
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    • 2013
  • MBR공정의 여러 가지 장점에도 불구하고 현장적용에 있어서 가장 큰 제한요소로 작용하는 것은 운전이 지속됨에 따라 멤브레인 파울링이 발생하여 플럭스의 저하가 발생하는 것이다. 현재 멤브레인 파울링에 관한 수많은 연구가 진행되고 있으나, 여러 가지 원인들이 복합적으로 영향을 미치기 때문에 정확한 메커니즘을 밝히기 어려운 실정이다. 본 연구에서는 lab-scale의 생물반응조와 정밀여과 중공사 멤브레인의 성능을 평가하고, 멤브레인 성능에 영향을 미치는 오염물질들을 측정하여 파울링과의 상관관계를 규명하고자 하였다. 마지막으로 파울링을 일으키는 다양한 인자들과 파울링 완화제(Membrane Fouling Reducer, MFR)의 적용성을 평가하였다. 실험결과 88 LMH로 임계 플럭스가 결정되었으며, 그때의 한계압력은 0.32 bar로 나타났다. MLSS농도와 EPS농도의 상관관계에서는 MLSS농도가 6,000 mg/L 이하에서는 EPS농도의 변화 폭이 큰데 비하여 6,000 mg/L 이상에서는 변동폭이 줄어드는 것을 확인할 수 있었다. 또한 SEM/EDX를 이용하여 멤브레인 표면 상태와 원소분석을 측정한 결과 탄소와 불소가 멤브레인의 재질 특성상 가장 높은 비율을 차지하였으며 알루미늄, 마그네슘과 같은 무기물의 비율이 증가한 것으로 보아 운전이 지속됨에 따라 무기성 멤브레인 파울링이 발생한 것으로 판단된다. MFR주입량에 따른 혼합액의 특성 변화를 측정하기 위해 입도분석, 제타전위, SCODcr, EPS 및 MLSS농도를 비교분석한 결과 전반적으로 0.03 mg MFR/mg MLSS의 MFR을 주입하였을 때 가장 좋은 결과를 나타내었다.