• Title/Summary/Keyword: Inorganic matters

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Effect of Freshwater Discharge on the Seawater Quality (Nutrients, Organic Materials and Trace Metals) in Cheonsu Bay (여름철 천수만 해수에서 담수 대량 방류에 따른 영양염, 유기물 및 미량금속의 변화)

  • LEE, JI-YOON;CHOI, MAN-SIK;SONG, YUNHO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.24 no.4
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    • pp.519-534
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    • 2019
  • When the fresh water from the artificial lakes (Ganwolho and Bunamho) were discharged to Cheonsu Bay in summer to prevent the flood over the reclaimed farmland near the lakes, the impact on water qualities (nutrients, organic matters, trace metals) within the bay was investigated through four surveys (June, July, August and October, 2011). Dissolved inorganic nitrogen (DIN) increased about as much as 3-4 times over the whole water column when the freshwater was discharged. And the main species composition of DIN changed from ammonia to nitrate. Dissolved inorganic phosphorus (DIP) decreased as much as 2 times in surface waters, but increased as much as 1.5 times in deep waters, and also silicate concentrations increased as much as 3-4 times in deep waters of the inner bay. The N/P ratios in Chunsu bay seawaters were much higher (2 to 7 times) than the Redfield ratio when the freshwaters were discharged, which indicated the phosphorus limiting in the phytoplankton growth. Dissolved organic carbon (DOC) and nitrogen (DON) increased as much as about 2 times. In addition, particulate organic matters (POC, PON, POP, Bio-Si) increased as much as above 2 times in the surface waters of the inner bay. Trace metals (Fe, Mn, Co, Ni, Cu) increased in the surface waters of the inner bay, but dissolved Cd concentrations decreased as much as 2 times. Therefore, when the contaminated fresh waters from the artificial lakes were discharged into the bay, nutrients, organic matters and trace metals generally increased compared to normal period. Since the phytoplankton bloom occurred in the surface waters of the inner bay, dissolved oxygens at the surface waters were oversaturated and hence hypoxic in the deep waters. Highly enriched nutrients concentrations were found in deep waters of the inner bay, which was accompanied with the hypoxic condition. Finally, the water quality in the inner bay of the Chunsu bay was deteriorated from less than grade 3 in normal periods to grade 5 when the freshwaters from the artificial lakes were discharged in summer.

Advanced Water Treatment of High Turbidity Source by Hybrid Process of Multi-channels Ceramic Microfiltration and Activated Carbon Adsorption (다채널 세라믹 정밀여과 및 활성탄 흡착 혼성공정에 의한 고탁도 원수의 고도정수처리)

  • Park, Jin-Yong;Lee, Hyuk-Chan
    • Membrane Journal
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    • v.18 no.4
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    • pp.325-335
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    • 2008
  • In this study, we used multi-channels ceramic membrane having larger permeate volume per unit time rather than tubular membrane. The hybrid process for advanced drinking water treatment was composed of granular activated carbons (GAC) packing between module inside and outside of multi-channels microfiltration membrane. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, modified solution was prepared with humic acid and kaolin. Kaolin concentration was fixed at 30mg/L and humic acid was changed as $2{\sim}10\;mg/L$ to inspect effect of organic matters. As a result, both resistance of membrane fouling ($R_f$) and permeate flux (J) were highly influenced by concentration of humic acid. Also, in result of water-back-flushing period (FT) effect, the shorter FT was the more effective to reduce membrane fouling and to enhance permeate flux because of frequent water-back-flushing. However, the optimal FT condition was 8 min when operating costs were considered. Then, the hybrid process using multi-channels ceramic membrane and GAC was applied to lake water treatment. As a result, average treatment efficiencies in our experiment using the hybrid process were 98.02% for turbidity, 75.64% for $UV_{254}$ absorbance, 7.18% for TDS and 84.73% for $COD_{Mn}$.

A Study on the Periodical Variations of Water Quality under the Condition of Stagnation (저수조내에서 수질의 경시적 변화에 관한 연구)

  • 박병윤
    • Journal of Environmental Science International
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    • v.4 no.1
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    • pp.81-90
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    • 1995
  • In order to provide the basic information for the water quality modeling, the water pollution indicators of Sin stream and Keumho river flowing through Taegu city were measured, and the Periodical variations of these indicators were studied under the condition of stagnating for 19 days. For this experiment, three sampling sites(Sungpook bridge, Mutae bridge and Gangchang bridge) were selected. Sungpook bridge is located most down the Sin stream, Mutae bridge and Gangchang bridge are located on the lower Keumho river. The results were as follows. 1. The values of water pollution indicators measured at Mutae bridge were pH 8.7, TSS 51mg/1, TS 383mg/1, Cl- 60.68mg/1, turbidity 32FTU, DO 8.58mg/1, oxygen deficit 2.02mg/1, COD 16.32mg/1, organic carbon 13.60mg/1. 2. At Gangchang bridge located down more than Mutae bridge, the values of these indicators were pH 8.0, TSS 26mg/1, TS 737mg/1, Cl- 90.59mg/1, turbidity 37FTU,DO 3.49mg/1, oxygen deficit 7.11mg/1, COD 28.02mg/1, organic carbon 14.28mg/1. 3. At Sungpook bridge, the values of these indicators were pH 8.3, TSS 145mg/1, TS 344mg/1, Cl- 32.51mg/1, turbidity 60FTU, DO 6.53mg/1, oxygen deficit 4.07mg/1, COD 43.79mg/1, organic carbon 11.03mg/1. 4. At Mutae bridge and Sungpook bridge of which initial DOs were high, DOs have decreased under the condition of stagnating for 7 days and increased after that time. On the contrary, at Gangchang bridge of which oxygen deficit was very high(7.11mg/l), DO have increased under the condition of stagnating for 13 days and decreased after that time 5. All the samples showed the quick decrease of CODs and organic carbons under the condition of stagnating for 19 days. Nevertheless, at Sungpook bridge ·of which initial COD was yeW high(43.79mg/1), the value of COD measured at the last day of experiment was still high(21.35mg/1) because of a large quantity of reducing inorganic matters. 6. All the samples didn't show the distinct decrease of turbidities because of a large quantity of nonbiodegradable inorganic solids.

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The Process of Hillslope Denudation Since the Last Glacial Maximum Near Tangjeong-myeon, Asan-si, Central Korea (아산시(牙山市) 탕정면(湯井面) 일대(一帶) 최종빙기(最終氷期) 최성기(最盛期) 이후(以後) 구사면(丘斜面)의 삭박과정(削剝過程))

  • PARK, Ji-Hoon;JANG, Dong-Ho
    • Journal of The Geomorphological Association of Korea
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    • v.15 no.2
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    • pp.67-83
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    • 2008
  • To find out the process of hillslope denudation since the Last Glacial Maximum in Asan area, we conducted the stratiform interpretation and carbon age measurements with the collected samples through trenching in the valley bottom of 'Agol' located in the lower stream of Magok stream. The results are as follows. 11 inorganic and 8 organic matter layers were confirmed at the point of trench MG1 in the subject area, 7 inorganic and 3 organic at the point of trench MG2, and 5 inorganic and 3 organic at the point of trench MG3, respectively. The frequency of hillslope denudation, hillslope mass movement, which had occurred in the unstable environment of back hillslope at the point of MG 1, was 11 times (8 times before about 2,900yrBP, twice in between about 2,900~1,900yrBP, and once after about 1,900yrBP) as a whole. The frequency of moor which had formed in the comparatively stable environment of back hillslope was 9 times (5 times before about 3,000yrBP, twice in between 3,000~2,800yrBP, and once in between 2,200~1,900yrBP) at minimum. The frequency of back hillslope denudation at the point of MG2 was totally 7 times (4 times before about 1,900yrBP and 3 times after about 1,900yrBP) and the moor formations were 3 times (twice before about 1,900yrBP and once after 1,900yrBP). The frequency of back hillslope denudation at the point of MG3 was totally 5 times (3 times before about 1,900yrBP and twice after about 1,900yrBP) and the moor formations were 3 times (twice before about 1,900yrBP and once after 1,900yrBP). The hillslope surrounded by valley bottom of 'Agol' was confirmed as the pile up of various inorganic matters by the mass movement such as sand or sandy gravel in the valley bottom of the subject area, formed not once but several times of denudation. We could know that the hillslope denudation cycle converged to the time period of $10^2{\sim}10^3$ years. These results will be an important basic data for restoring hillslope denudation process near Asan and changing climate of the Late Quaternary Period.

The Characterization of PM, PM10, and PM2.5 from Stationary Sources (고정배출원의 먼지 크기별 (PM, PM10, PM2.5) 배출 특성 연구)

  • Kim, JongHo;Hwang, InJo
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.603-612
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    • 2016
  • The objective of this study was to estimate the emission characteristics for PM, $PM_{10}$, and $PM_{2.5}$ in the various stationary sources. The particulate matters collected in the various stationary sources such as power plants (Coal and B-C oil), incinerators(municipal and industrial waste), and glass furnaces. The PM and $PM_{10}$, PM and $PM_{2.5}$, $PM_{10}$ and $PM_{2.5}$ samples were collected using the cyclone type $PM_{10}$, $PM_{2.5}$ samplers and 30 species(19 inorganic species, 9 ionic species, OC and EC) were analyzed by ICP, IC, and TOR/IMPROVE methods. The mass concentrations of PM, $PM_{10}$, $PM_{2.5}$ from nine stationary sources ranged $0.63{\sim}9.58mg/Sm^3$, $0.26{\sim}7.47mg/Sm^3$ and $0.13{\sim}6.34mg/Sm^3$, respectively. The level of $PM_{10}$, $PM_{2.5}$ portion in PM calculated 0.63~0.99, 0.38~0.94, respectively. In the case of emission trend for species, power plant showed high concentrations for Al, Mg, Na, Si, V and $SO_4{^{2-}}$, respectively. Also, Ca, Fe, K, Si, $Cl^-$, and $K^+$ showed high in incinerator. In the case of glass furnace, Na, Pb, K, Si, $Na^+$ and $SO_4{^{2-}}$ represented high concentrations. Power plant showed higher EC/OC concentrations than other sampling sites. These results suggest the possible role for complement establishment process of emission inventory and emission management for PM.

Electricity Generations in Submerged-flat and Stand-flat MFC Stacks according to Electrode Connection (침지 및 직립 평판형 MFC 스택에서 전극연결 방식에 따른 전기발생량 비교)

  • Yu, Jaecheul;Park, Younghyun;Lee, Taeho
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.4
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    • pp.589-593
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    • 2016
  • Microbial fuel cell (MFC) can produce electricity from oxidation-reduction of organic and inorganic matters by electrochemically active bacteria as catalyst. Stacked MFCs have been investigated for overcoming low electricity generation of single MFC. In this study, two-typed stacked-MFCs (submerged-flat and stand-falt) were operated according to electrode connection for optimal stacked technology of MFC. In case of submerged-flat MFC with all separator electrode assembly (SEA) sharing anode chamber, MFC with mixed-connection showed more voltage loss than MFC with single-connection method. And MFC stacked in parallel showed better voltage production than MFC stacked in series. In case of stand-flat MFC, voltage loss was bigger when SEAs sharing anodic chamber only were connected in series. Voltage loss was decreased when SEAs parallel connected SEAs sharing anodic chamber were connected in series.

Study on Optimum Conditions for the Composting of Industrial Wastewater Sludge (공단 폐수 슬러지의 퇴비화 최적조건)

  • Lee, Hong-Jae;Cho, Ju-Sik;Heo, Jong-Su
    • Journal of Environmental Science International
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    • v.7 no.1
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    • pp.96-103
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    • 1998
  • To study the optimum conditions of composting with industrial wastewater sludge, the variations of temperature and $CO_2$ generation amount during the composting periods were investigated. The conditions were that industrial wastewater added to bulking agents such as sawdust and rice hull was used, and differently treated with microorganism seeding or not, initial C/N ratios, air flow rate and initial moisture contents, respectively. The results were summarized as follows : Seeding 5% of microorganism was higher the temperature than not seeding. And using sawdust as bulking agents, and adjusting 30~40 of Initial C/N ratio, 200ml/l.min. of k flow rate and 67~68% moisture contents were higher the temperature than any other conditions. Seeding 5% of microorganisms was higher $CO_2$ generation amount than not seeding. And that was much in the order of 7~40, 30~34 and 22~23 of initial C/N ratio. Judging from the results, it should be considered that the optimum conditions in the composting of industrial wastewater sludge were seeding of 5% microorganisms, and adjusting 30~34 of Initial C/N ratio, 200ml/l min. of air flow rate and 67~68% of Intitial moisture contents. The contents of inorganic matters and C/N ratio during the composting periods at optimum condition were a little Increased. and heavy metals contents after composting were lower than standard for fortllizer.

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A Study on the Development of Improved Artificially Soiled Cloth and its Detergency (새로운 인공오염포의 제작과 그 세척성에 관한 연구)

  • Chung Doo Jin;Kim Mi Hyung
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.3 s.31
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    • pp.207-222
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    • 1989
  • New process for the preparation of the artificially soild cloth (ASC) used for detergency evaluation was developed and its detergency was also studied. ASC was prepared by the dipping of cotton cloth in the water in which oily soil, protein (gelatine), carbon black and clay had been dispersed. The clay used for this ASC was red yellowish soil around Mt. Kumjung and was a typical soil in Pusan area. Adhesive status of soil at prepared ASc was examined by an electron microscope, and crystallyzation and color change of used clay were evaluated with the determination of X-ray diffraction and surface reflectance. For the evaluation of detergency by the washing with commercial and model detergents, the behavior of soil removal from this ASC comparing with naturally soiled collar cloth was examined. Those results are summerized as followings; 1) Adhesive ststus of soil at prepared ASc was very similar to that of naturally soiled collar cloth. 2) A crystalline of clay calcined at $800^{\circ}C$ was disappeared in part and color of calcined clay changed into reddish yellow by the decomposition of organic matters. 3) More uniform ASc was prepared with clay calcined at $800^{\circ}C\;that\;200^{\circ}C$ however its detergency prepared from clay calcined at $800^{\circ}C$ was poor 4) A significant relationship between the content of inorganic matter in ASc and K/S value was found, however no significant result between the content of protein contaminated and K/S value was observed. 5) Detergency of prepared ASc had a very similar to that of naturally soiled collar cloh.

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Making Techniques and Provenance Interpretation for Molding Clay of Four-Guardian Statues in Songgwangsa Temple, Suncheon, Korea (순천 송광사 사천왕상 소조토의 제작기법과 원산지 해석)

  • Jo, Young-Hoon;Jo, Seung-Nam;Lee, Chan-Hee
    • Journal of Conservation Science
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    • v.26 no.1
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    • pp.43-60
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    • 2010
  • This study was investigated quantitative and objective making techniques for molding clay of Four-guardian statues in Songgwangsa temple. Also, basic data about the provenance of molding clay was acquired for the restoration using same materials when the conservation treatment is carried out. As a result, molding clay used the Four-guardian statues was identified the very similar soil regardless of layers and objects. But molding clay differed in particle sizes and contents of organic matters according to the first layer to finish layer in relatively thick parts. Also, it was used one kind of soil without the layer distinction in thin parts. The restoration soil was applied to genetically similar soil as molding clay of the Four-guardian statues, and showed a difference of careful selection degree according to the layers. As a result of the provenance interpretation, the soil distributing presumed provenance was confirmed the same origin as molding clay. Therefore, the soil is appropriate for the materials of conservation treatment. This result will contribute inorganic material research and conservation treatment for the clay molded Four-guardian statues in Korea.

Studies on the Chemical Compositions and Distributions of Ambient Sumicron Aerosols (Submicron 부유분진의 화학적 조성 및 분포에 관한 연구)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.1
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    • pp.11-23
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    • 1998
  • The purpose of this study was to survey chemical distribution of inorganic elements and ions in the submicron particles, to characterize qualitatively emitting sources by factor analysis, and finally to reveal existing patterns in terms of chemical compounds by a stepwise multiple regression analysis. Total of 141 samples were collected by a cascade impactor from 1989 to1996. Fifteen chemical species (Al, Ba, Cd, K, Pb, Cu, Fe, Ni, $Cl^-, NO_3^-, SO_4^{2-}, K^+, Mg^{2+}, Ca^{2+}, and Na^+$) were characterized by AAS and IC. The study showed that average seasonal levels of submicron particulate matters $(d_p<0.43 \mum)$ were 18.7 $\mug/m^3$ in spring, 15.5 $\mug/m^3$ in summer, 15.7 $\mug/m^3$ in fall, and 24.5 $\mug/m^3$ in winter, respectively. All of the anion concentrations in the particle were highest in the winter season. By applying a factor analysis, 5 source patterns were qualitatively obtained, such as sulfate related source, nitrate related source, oil burning source, calcium related source, and coal combustion source. Finally, when applying a stepwise multiple regression analysis, the results clearly showed that $Na^+ and Ca^{2+}, K^+ and Ca^{2+}, NO_3^-$ and relative humidity, $Cl^-$ and ambient temperature, $Ca^{2+} and Cl^-, Mg^{2+} and SO_4^{2-}, Na^+ and NO_3^-, and Ca^{2+} and NO_3^-$, respectively, are negatively contributed to each other. As a result of those statistical analysis, we could suggest that some chemical compounds in the submicron particles such as$NaNO_3, MgSO_4, Ca(NO_3)_2, and CaCl_2$ may not exist on the filter as final composing products; however, other compounds may possibly exist in the form of $Mg(NO_3)_2, CaSO_4, Na_2SO_4, K_2SO_4, MgCl_2, NaCl, and KCl$. Thus, it must be necessary to identify differences between the results of above statistical analysis and of the real world by laboratory experiments.

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