• 한국염색가공학회지
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• 제32권1호
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• pp.19-26
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• 2020

The previous study reported that the quaternary copolymer of MMA, BA, MAA, and NEA was expected to be a good monomer composition for a binder polymer with good rubbing fastness for digital textile printing(DTP) pigment ink. However, the rubbing fastness of the dyed fabric with the quaternary copolymer binder containing pigment ink is not enough to be commercially used. Therefore, this study aims to optimize MMA:BA:MAA:NEA composition for improved rubbing fastness. And the binder polymer with various MMA:BA:MAA:NEA compositions were synthesized using miniemulsion polymerization. The particle size, viscosity, molecular weight, and Tg of the synthesized binder were evaluated. And the color strength and rubbing fastness of the black pigment ink dyed cotton fabrics with the prepared binders were also evaluated. Then, the stiffness of undyed and dyed cotton fabrics were evaluated to investigate the changes in touch as the binder structure changes.

• 한국염색가공학회지
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• 제17권2호
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• pp.1-9
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• 2005

Mixed dyeing were carried out ll"ing yellow, red and purple loess as mineral dyes verify their dyeability, color shade and fastness. The proper density of Chinese ink were 0.5, 1.0, 2.0, 2.5, $5\%$(o.w.b). The grinded chinese ink had better stainability compared with the general Chinese ink. The mixed dyeing improvement of stainability in the density of loess of $40\%$(o.w.b) among the yellow, red, and purple loess. The colors in the mixed dyeing with Chinese ink were $3.801\~8.13Y,\;0.128\~7.038Y\;and\;4.222\~9.304Y$. The colorfastness were 1-2 in the homogeneous dyeing with Chinese ink. It was improved 1-3 in the mixed dyeing. Light colorfastness of the homogeneous and mixed dyeing were excellent as a value of 5. The dry rubbing fastness in the homogeneous dyeing was 3-3.5, and 3 in the wet rubbing. As for the mixed dyeing, the dyes of Chinese ink showed poor diffusion into the fiber, resulting in low fastness due to the existence of the dyes on the surface.

• 복식
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• 제60권2호
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• pp.68-80
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• 2010

In order to get the information needed for the preservation and application of Korean traditional dyeing techniques to modern textiles products, the present study analyzed the color and color differences of dyed goods according to the contents of fabrics and the traditional techniques of dyeing the Buddhist priests' robes. A spectrophotometer was used to measure the differences in achromatic color according to dyeing techniques, dyestuff, kinds of dyed fabrics, and after-treatment methods. Through experiments based on the traditional dyeing techniques used by Korean Buddhist priests, a total of 144 pieces of dyed fabrics were made and all the colors of those 144 pieces were analyzed. Among three dyeing techniques tested; (1) dyeing with a dye-bath made of ink stick that was ground down with water, (2) dyeing with a dye-bath made by shaking a bag containing ink powder in water, and (3) dyeing with a dye-bath made by rubbing a boiled ink stick on a fabric, dyeing with a dye-bath made of ink stick that was ground down with water was shown to be the best technique in terms of coloring. For fabrics, ramie was the best of all three techniques in terms of making achromatic color. Starching and rubbing was the most effective after-treatment method used on both fabrics dyed with a grounded ink stick and on fabrics dyed by rubbing a boiled ink stick on them. As a whole, yangyeonmook, made from minerals' soot, is better than songyeonmook, which is made by burning old pine trees or yooyeonmook, which is made by burning oils from seeds. Therefore, yangyeonmook could help to preserve and utilize the traditional dyeing techniques of Korea in a practical way in modern life.

• 한국염색가공학회지
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• 제30권4호
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• pp.256-263
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• 2018

The binder polymers for digital textile printing(DTP) pigment inks were prepared using miniemulsion polymerization with various monomer compositions to study effects of monomer compositions on particle size distribution, average molecular weight, Tg, and color strength and rubbing fastness of the dyed fabrics with the prepared binder based pigment ink. The monomers used were MMA(Methyl methacrylate), BA(Butyl acrylate), MAA(Methacrylic acid), NMA(N-methylol acrylamide), NEA(N-ethylol acrylamide) and the ratios of the monomers were changed. The particle size was the smallest with 136nm when the MMA to BA weight ratio was 4:16 and the largest with 290nm when the MMA, BA, MAA, NEA ratio was 2.5:17:0.25:0.25. However, the glass transition temperature was lowest with $-41.90^{\circ}C$ and the color strength and rubbing fastness of the resulting sample were the best when the MMA, BA, MAA, NEA ratio was used. This suggested that the introduction of the NEA monomer to the binder polymer for the pigment ink could be an efficient way to enhance the rubbing fastness of the DTP pigment inks present.

• 한국염색가공학회지
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• 제31권2호
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• pp.77-87
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• 2019

To improve rubbing fastness of the printed fabrics, the binder polymers for Digital Textile Printing(DTP) pigment inks were synthesized with miniemulsion polymerization using various acrylic monomers, which are MMA(Methyl methacrylate), BA(Butyl acrylate), and Self-crosslinking monomers, such as NEA(N-Ethylol acrylamide) and MAA (Methacrylic acid). The acrylic monomer compositions were varied when synthesizing the binder polymers and their particle size distributions, average molecular weights, and Tgs were investigated. The prepared binder polymers were applied to prepare Cyan, Black, Yellow and Magenta pigment ink for DTP and the prepared inks were used to dye cotton fabrics. Then, color strength, and rubbing fastness were also investigated to study the effect of the comonomer compositions of the binder polymer on the color strength and rubbing fastness of the resulting pigment inks.

• 한국염색가공학회지
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• 제34권1호
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• pp.10-19
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• 2022

Humectants are chemical compounds which added to water based pigment inks for DTP (Digital Textile Printing) to prevent evaporation of water. The humectants usually have diol or triol type chemical structures and their -OH groups have possibility to react with functional groups of the binder polymers, such as ester, carboxylic acid, and urethane groups, acting as a crosslinking agent. The crosslinking reactions between polymer binders and humectants in inks can affect touch of the printed fabrics. In this regard, this study aims to investigate effect of chemical structures and added amounts of humectants in pigment ink on touch of dyed fabrics by using 1,6-hexanediol, ethylene glycol, diethylene glycol, and 1,4-buthanediol with various amounts added to the mixture of a black pigment and a polyurethane type binder. Then, color, rubbing strength, touch of the fabrics dyed with the prepared pigment inks were evaluated.

• 보존과학회지
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• 제34권6호
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• pp.525-538
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• 2018

2015년 유네스코 세계기록유산으로 등재된 미얀마 미야제디 석주는 미얀마의 역사, 종교, 문화에 관한 중요한 문자 기록물이며, 연대가 명확하게 표기된 오래된 유물 중에 하나이다. 미야제디 석주는 역사적으로도 중요한 만큼 명문의 해석이나 연구 행위를 하기 위해 수많은 탁본 제작을 하였고, 이로 인해 표면에 흑색오염물의 침착이 심각한 상태이다. 그래서 흑색오염물에 대한 분석학적 연구와 문제된 오염물의 제거 방법에 대한 보존처리 연구를 진행하였다. 특히 보존처리의 접근방식은 레이저 클리닝 기법과 화학적인 약품을 이용하였다. 대부분의 오염물은 탁본과정 중에서 표면에 잔류한 잉크가 원인이었다. 실험의 유사 환경 조건을 위해 가오염물을 도포한 의사시료를 제작하여 보존처리 조건별로 결과를 도출하였다. 의사시료들은 레이저 클리닝에 대해서는 대부분 조건에서 효율적인 결과를 보였으나, 화학 약품적용 방법에서는 선택적 양상을 나타냈고, 그중 에탄올을 활용한 물리적 마찰법에 대한 결과는 약품 활용기법 중 가장 효율적 이였다. 결과적으로 효율적인 방법론을 제시한다면 레이저 클리닝 세정법이 보편타당하지만 현지의 상황 조건을 고려한다면 차선책인 화학약품을 병행한 물리적인 적용방법이 합리적이라고 판단되었다.

• 한국염색가공학회지
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• 제22권2호
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• pp.88-93
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• 2010

Using extracted sepia melanin powder by repeated treatments with aqueous sodium hydroxide and acetic acid solutions, vat dyeing of wool and cotton fabrics was carried out under various dyeing conditions including concentration of melanin, alkali, reducing agent and salt, as well as dyeing time and temperature. A K/S of 25.3 for wool fabrics was obtained at the optimal dyeing condition with 9% owf melanin, 0.5g/L NaOH and 56g/L $Na_2S_2O_4$ without salt at $80^{\circ}C$ for 90minutes. The vat dyeing of sepia melanin was applicable to both cotton and wool fabrics but the wool showed higher dyeability. The color fastness properties of the dyed wool and cotton fabrics were excellent to washing, rubbing and light irradiation.

• 한국염색가공학회지
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• 제32권4호
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• pp.226-231
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• 2020

This study investigated effect of particle sizes of polymer binders for digital textile printing(DTP) pigment inks on touch of fabrics. The polymer binders were synthesized via miniemulsion polymerization of methyl methacrylate(MMA), butyl acrylate(BA), N-ethylolacrylamide(NEA) and methacrylic acid(MAA). The prepared binders were applied to black pigment inks and those black pigment inks were used to dye cotton fabrics. Then, color strength, rubbing fastness, stiffness, surface and bending properties of the dyed fabrics were investigated. Depending on the particle size of the polymer binder used, color strength, friction fastness, stiffness, surface and bending properties change. Generally, the larger the particle size of the polymer binder, the softer properties.

• 패션비즈니스
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• 제15권5호
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• pp.43-54
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• 2011

Digital Textile Printing(DTP) is appropriate for quick response system(QRS) and is closely connected with high value added fashion industry. Fashion products of high price are mainly silk and cotton. For high quality DTP products, it is important to optimize the parameters of media, pre and after-treatment, ink, printer, etc. DTP for these two fiber materials is also accompanied certainly with steaming as after-treatment process for coloration. Role of steam is like water in exhaustion dyeing. Steam can diffuse dye or ink in printing paste to fiber. Quality of DTP products depend on after-treatment processes such as steaming, washing, drying. Current production amount of DTP is smaller than one of conventional textile printing. However conventional after-treatment system has been using so far. This is mismatched with DTP in terms of process efficiency, spot work of small lot, quality control. In this study, continuous after-treatment system has been suitably designed for DTP that washing and drying are available after steaming. So, It is possible to improve efficiency of DTP process. Especially, the effects of after-treatment process, such as temperature of heat drum, steaming time on printability, color difference, color fastness were examined. Two types of samples(cotton knit and silk fabrics) were used. The results were obtained as follows : First, there is no a wide difference between the K/S values of cotton and silk treated with continuous after-treatment system and those of sample treated with conventional printing after-treatment method. So it is more effective to use the continuous after-treatment system than conventional printing after-treatment system in case of the daily throughput of 1,000 yards below. Second, after continuous after-treatment for DTP, K/S values were increased and lightness($L^*$) values were decreased. ${\Delta}E$ values were below 2.3. Third, DTP samples treated with continuous after-treatment system were tested for fastness(washing, light, rubbing). Grades of fastness(washing, light, rubbing) were above 3 grade.