• Journal of Environmental Science International
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• v.6 no.4
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• pp.399-407
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• 1997

The pyrolysis reactions of atomic hydrogen with chloroform were studied In a 4 cm 1.6. tubular flow reactor with low flow velocity 1518 cm/sec and a 2.6 cm 1.4. tubular flow reactor with high flow velocity (1227 cm/sec). The hydrogen atom concentration was measured by chemiluminescence titration with nitrogen dioxide, and the chloroform concentrations were determined using a gas chromatography. The chloroform conversion efficiency depended on both the chloroform flow rate and linear flow velocity, but 416 not depend on the flow rate of hydrogen atom. A computer model was employed to estimate a rate constant for the initial reaction of atomic hydrogen with chloroform. The model consisted of a scheme for chloroform-hydrogen atom reaction, Runge-Kutta 4th-order method for Integration of first-order differential equations describing the time dependence of the concentrations of various chemical species, and Rosenbrock method for optimization to match model and experimental results. The scheme for chloroform-hydrogen atom reaction Included 22 elementary reactions. The rate constant estimated using the data obtained from the 2.6 cm 1.4. reactor was to be 8.1 $\times$ $10^{-14}$ $cm^3$/molecule-sec and 3.8 $\times$ $10^{-15}$ cms/molecule-sec, and the deviations of computer model from experimental results were 9% and 12% , for the each reaction time of 0.028 sec and 0.072 sec, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.3
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• pp.241-247
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• 2010

The Effects of operating parameters such as initial pH, gaseous ozone concentration, supplied gas flow rate on dissolved ozone concentration and phenol degradation in ozone contact reactor were investigated. Dissolved ozone concentrations were saturated to constant values after a certain ozone contact time. The saturation values were influenced by experimental parameters. Dissolved ozone concentration decreased with the increase of initial pH because the ozone is unstable in high pH regions. The gaseous ozone concentration in a constant gas supply affected the saturation concentration of dissolved ozone and the injection rate of gas with a constant ozone concentration determined the rate to reach dissolved ozone saturation. Effects of operating parameters on phenol degradation were closely related with those of parameters on dissolved ozone concentration. Phenol degradation was enhanced by the increase of initial pH, because the degradation of dissolved ozone gave birth to free radicals which have much higher reactivity with phenol. Increase of gaseous ozone concentration and gas flow rate promoted the phenol degradation through the generation of dissolved ozone which plays the role in phenol degradation. The injection of methanol deteriorated the phenol degradation through the scavenging effect on OH radicals.

• The Korean Journal of Ecology
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• v.25 no.1
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• pp.41-44
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• 2002

Weight loss, N and P dynamics during decomposition of fine roots (<2mm) of alder(Alnus japonica), oak (Quercus acutissima) and pitch pine(Pinus rigida) were studied for 33 months in Kongju, Korea. After 33 months, remaining weight of fine roots of alder, oak and pitch pine was 29.2%, 47.7% and 53.4% of the initial weight, respectively. The decomposition rate constant (k) for alder, oak and pitch pine was 0.448 $yr^1$, 0.269 $yr^1$, 0.228 $yr^1$, respectively. Initial concentration of N and P in fine roots was 10.32mg/g and 0.69mg/g for alder, 6.20mg/g and 0.37mg/g for oak and 7.26mg/g and 0.44mg/g for pitch pine, respectively. Initial concentration of N and P in alder were higher than those in oak and pitch pine. After 33 months, remaining N and P in fine roots was 39.5$\%$ and 31.8$\%$ for alder, 59.4$\%$ and 57.8$\%$ for oak, 63.0$\%$ and 83.4$\%$ for pitch pine, respectively. Decomposition rate and the rate of N released from decomposing fine roots was positively correlated with the initial N concentration of the fine roots.

• Journal of Environmental Science International
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• v.7 no.4
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• pp.559-564
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• 1998

The effects of temperature, initial $Pb^{2+}$concentration and initial sludge concentration on the initial $Pb^{2+}$ removal rate and maximal $Pb^{2+}$removal amounts in activated sludge, respectively, were investigated. The removal of $Pb^{2+}$ in activated sludge was proved to be temperature-dependent process. The initial $Pb^{2+}$ removal rate increased from 187.5 to 261.4 mg $Pb^{2+}$/g sludge dry weight min, in response to the promoted temperature from 1$0^{\circ}C$ to 6$0^{\circ}C$, while the maximal $Pb^{2+}$removal amount (78.5 mg $Pb^{2+}$/g sludge dry weight) occurred at 30t . As the initial $Pb^{2+}$concentration increased from 36 to 228 mg $Pb^{2+}$/L at the constant temperature of 30C and initial sludge concentration of 1.5 g sludge dry weight/L, the time to reach an equilibrium state was almost independent of the initial $Pb^{2+}$concentration and the equilibrium $Pb^{2+}$/removal amount was increased Irom 41.9 to 73.6 mg $Pb^{2+}$/g sludge dry weight. On the contrary, the equilbrium $Pb^{2+}$ emoval amount was decreased from 87.7 to 65.3 mg $Pb^{2+}$/g sludge dry weight as the in- crease of initial sludge concentration from 0.22 to 1.76 g sludge dry weight/L.

• Journal of the Korean Chemical Society
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• v.30 no.1
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• pp.3-8
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• 1986

The investigation of the effect of solvent structure on the first-order solvolysis of cis-$[Co(en)_2ClNO_2]^+$ion has been extended to water + co-solvent mixtures where the co-solvents are glycerol, ethylene glycol, isopropyl alcohol and t-butyl alcohol. Rates of solvolysis have been evaluated by spectrophotometric method at temperature 25∼30$^{\circ}$C. The polarity of solvent has influence on the variation of rate constant. The non-linear plot of the rate constant in log scale versus $\frac{D-1}{2D+1}$ implies that change in solvent structure with composition plays an important role in determining the variation of rate constant. The linearity of the plot of the rate constant in log scale versus the Grundwald-Winstein Y factor confirms that the solvolysis is an Id-type process with considerable extension of the metal chloride bond in the transition state. In the Kivinen equation the slope of the plot of log k versus $log(H_2O)$ suggests that the solvolysis is also an Id-type process. The application of free energy cycle shows that the effect of solvent structure is greater in the transition state than in the initial state.

• Biotechnology and Bioprocess Engineering:BBE
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• v.10 no.1
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• pp.9-15
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• 2005

A bioartificial liver (BAL) is a medical device entrapping living hepatocytes or immortalized cells derived from hepatocytes. Many efforts have already been made to maintain the functions of the hepatocytes in a BAL device over a long term. However, there is still some uncertainty as to their efficacy. and their limitations are unclear. Therefore, it is important to quantitatively evaluate the metabolic functions of a BAL. In previous studies on in vitro BAL devices, two test methods, an initial bolus loading and constant-rate infusion plus initial bolus loading, were theoretically carried out to obtain physiologic data on drugs. However, in the current study, the same two methods were used as a perfusion model and derived the same clearance characterized by an interrelationship between the perfusate flow rate and intrinsic clearance. The interrelationship indicated that the CL increased with an increasing perfusate flow rate and approached its maximum value, i.e. intrinsic clearance. In addition, to set up an in vivo BAL system, the toxic plateau levels in the BAL system were calculated for both series and parallel circuit models. The series model had a lower plateau level than the parellel model. The difference in the toxic plateau levels between the parallel and series models increased with an increasing number of BAL cartridges.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.5
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• pp.643-649
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• 2011

Degradation of benzothiophene(BT) in the aqueous phase by potassium ferrate(VI) was investigated. Potassium ferrate(VI) was prepared by the wet oxidation method. The degradation efficiency of BT was measured at various values of pH, ferrate(VI) dosage and initial concentration of BT. BT was degraded rapidly within 30 seconds by ferrate(VI). While the highest degradation efficiency was achieved at pH 5, the lowest degradation efficiency was achieved at pH 9. Also, the initial rate constant of BT increased with decreasing of the BT initial concentration. In addition, the intermediate analysis for the reaction of BT and ferrate(VI) has been conducted using GC-MS. Benzene, styrene, benzaldehyde, formaldehyde, benzoic acid, formic acid, and acetic acid were identified as reaction intermediates, and ${SO_4}^{2-}$ was identified as an end product.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.1
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• pp.63-74
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• 2011

The degradation characteristics of 2-chlorophenol(2-CP) by Ferrate(VI) were studied. The degradation efficiency of 2-CP in aqueous solution was investigated at various values of pH, Fe(VI) dosage, initial concentration and aqueous solution temperature. The maximum degradation efficiencies of 2-CP were obtained at pH 7.0 and aqueous solution temperature of 25$^{\circ}C$. The degradation efficiency was proportional to dosage of Fe(VI). Also, the initial rate constant of 2-CP degradation increased with decreasing of the 2-CP initial concentration. In addition, the degradation pathway study for 2-CP was conducted with GC-MS analysis. Acetic acid, formic acid, benzaldehyde and benzoic acid were identified as reaction intermediates of the 2-CP degradation by Ferrate(VI).

• Journal of Advanced Marine Engineering and Technology
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• v.24 no.4
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• pp.427-434
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• 2000

In tradition, there have been two kinds of drying methods, which are sun drying and artificial drying. The sun drying method which has been adopted traditionally has been replaced by the hot-air drying method which is one of the most general methods of artificial drying, with its simple drying system, low initial cost of drying plant, and easy operating method. But the hot-air drying method has some defects; (1) much energy loss happens due to the discharge of hot air during the drying process, (2) control of drying rate is not easy on account of changing relative humidity of inlet air for uniform hot air temperature, (3) high temperature of foods in drying process brings about the production of low-grade drying products. Vacuum drying takes advantage of energy saving and mass production because it reduces the drying time by increasing the drying rate under low temperature condition. The aim of this paper is to develop the low temperature vacum dryer, with low initial investments and operating costs, easy operating method and trouble-free operation.

• Journal of environmental and Sanitary engineering
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• v.13 no.1
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• pp.185-194
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• 1998

Laboratory-scale investigation into initial anaerobic biofilm development was carried out by circulating mixed liquor from a steady-state anaerobic reactor through silicone tubing and then rerurning the mixed liquor to the reactor. The wall of the silicone tubing was the surface upon which anaerobic biofilm accumulation or development was monitored. Methanogenic bacteria accumulation was monitored by F$_{420}$ fluorescence (picomoles F$_{420}$/cm$^{2}$) of the extracted biofilm material. Biofilm accumulation was measured by the increase in COD of the extracted material ($\mu $g COD/cm$^{2}$). Experiments were conducted for 25 days, and biofilm analyses were performed at 5 days intervals. The results indicated that the initial rates of methangen and anaerobic biofilm accumulation increased with increasing organic loading rate and higher initial rates were observed for 15 days than 15 day liquid HRT or SRT. When the initial rates were plotted against the corresponding mixed liquor volatile suspended solids the difference between the results at the two HRT's became much less significant. Thus, the concentration of mixed liquor volatile suspended solids was found to be a very important parameter affecting initial anaerobic biofilm development. The ratio of methanogens to anaerobic biofilm was also investigated. The results showed that the ratio remained constant through the 25 days of each experiment and for high organic loading rates. Based on the results of this research, a reduction, a reduction of start-up period of anaerobic fixed film reactors might be achieved by maintaining a high organic loading and a large concentration of anaerobic microorganisms in the mixed liquor during the start-up period.