• Journal of Soil and Groundwater Environment
• /
• v.11 no.6
• /
• pp.83-91
• /
• 2006

Reduction kinetics and the behaviour of intermediate of three high explosives (HMX, RDX, and TNT) were studies in batch reactors using nano- or micro- size zero valent iron(nZVI or mZVI) as reducing agent. The kinetic constants normalized by the mass of iron ($k_M$) or by the surface area ($k_{SA}$) were measured and compared along with the changes in the concentrations of intermediates. Results showed that $k_M$ and $k_{SA}$ values were not suitable to fully explain the behaviour of mother compounds and reduced intermediates in the batch reactor. The concentrations of initial explosives degradation products, such as nitroso-RDXs, nitroso-HMXs, and hydroxylamino-TNTs, were higher in mZVI treated reactor than in nZVI treated reactor, whereas more reduced polar intermediates such as TAT were accumulated in the nZVI reactor. Therefore, a new parameter, which accounted for the intermediates reduction, needs to be developed.

• Applied Chemistry for Engineering
• /
• v.27 no.6
• /
• pp.590-598
• /
• 2016

In this study, the adsorption behavior from aqueous solution as well as kinetic and thermodynamic parameters of Acid Black 1 were investigated through batch reaction using coconut shell based granular steam activated carbon. The effects of various adsorption parameters such as pH, initial concentration, contact time, temperature were studied. To confirm the effect of pH, pHpzc measurements were analyzed followed by measuring removal efficiencies of Acid Black 1 at the pH range from 3 to 11. Experimental equilibrium adsorption data were fitted using Langmuir, Freundlich, Temkin and Dubinin-Radushkevich adsorption isotherm. The conformity of adsorption reaction for pseudo first and second order model were evaluated through kinetic analysis. Values of enthalpy change and activation energy were also investigated through thermodynamic analysis and it was confirmed that the adsorption process was endothermic. The spontaneity of adsorption process was evaluated using the values of entropy and Gibbs free energy changes.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
• /
• v.34 no.1
• /
• pp.79-90
• /
• 2016

The study has purposed in evaluating experiences for achievable accuracy and precision of time series at 3-D coordinates. It has been estimated from the kinematic medium-range baseline processing of Continuously Operating Reference Stations (CORS) for the potential application of crustal displacement analysis during an earthquake event. To derive the absolute coordinates of local CORS, it is highly recommended to include some of oversea country references, since it should be compromised of an observation network of the medium-range baselines within the length range from tens of kilometers to about 1,000 kilometers. A data processing procedure has reflected the dynamics of target stations as the parameter estimation stages, which have been applied to a series of experimental analysis in this research at the end. From the analysis of results, we could be concluded in that the subcentimeters-level of positioning accuracy and precision can be achievable. Furthermore, the paper summarizes impacts of satellite ephemeris, data lengths and levels of initial coordinate constraint into the positioning performance.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.19 no.3
• /
• pp.1-9
• /
• 2015

Due to the increasing number of deteriorated bridges worldwide, the importance of maintenance and replacement of existing bridges are being emphasized. Cast-in-place concrete deck which is mainly applied to deck replacement of existing bridges have problems such as deterioration concerns by initial crack, labor cost increase, difficulties of maintenance and replacement, construction time increase, and indirect cost increase by traffic congestion. On the contrary, a precast concrete deck is considered as an effective alternative because of its quality assurance and accelerated construction. The connection method ensuring the required strength and durability is especially important, because the connection part of the precast concrete deck is vulnerable to cracks and leakage. Therefore, this study proposes precast bridge decks with ribbed connection which are more improved than existing bridge deck joints, and flexural performance is verified through various parameter tests.

• Structural Engineering and Mechanics
• /
• v.37 no.6
• /
• pp.671-684
• /
• 2011

Deciding on an optimal sensor placement (OSP) is a common problem encountered in many engineering applications and is also a critical issue in the construction and implementation of an effective structural health monitoring (SHM) system. The present study focuses with techniques for selecting optimal sensor locations in a sensor network designed to monitor the health condition of Dalian World Trade Building which is the tallest in the northeast of China. Since the number of degree-of-freedom (DOF) of the building structure is too large, multi-modes should be selected to describe the dynamic behavior of a structural system with sufficient accuracy to allow its health state to be determined effectively. However, it's difficult to accurately distinguish the translational and rotational modes for the flexible structures with closely spaced modes by the modal participation mass ratios. In this paper, a new method of the OSP that computing the mode shape matrix in the weak axis of structure by the simplified multi-DOF system was presented based on the equivalent rigidity parameter identification method. The initial sensor assignment was obtained by the QR-factorization of the structural mode shape matrix. Taking the maximum off-diagonal element of the modal assurance criterion (MAC) matrix as a target function, one more sensor was added each time until the maximum off-diagonal element of the MAC reaches the threshold. Considering the economic factors, the final plan of sensor placement was determined. The numerical example demonstrated the feasibility and effectiveness of the proposed scheme.

• Solar Energy
• /
• v.20 no.2
• /
• pp.75-84
• /
• 2000

Global wanning induced by greenhouse gases such as carbon dioxide is a serious problem for mankind. Carbon dioxide ocean disposal is one of the promising options to reduce carbon dioxide concentration in the atmosphere because the ocean has vast capacity for carbon dioxide sequestration. However, the dissolution rate of liquid carbon dioxide in seawater must be known in advance in order to estimate the amount of carbon dioxide sequestration in the ocean. Therefore, the solubility, the surface concentration, the droplet size and other factors of liquid carbon dioxide at various depths are calculated. The results show that liquid carbon dioxide changes to carbon dioxide bubble around 500 m in depth, and the droplet is completely dissolved below 500 m in depth if carbon dioxide droplet is released both at 1000 m in depth with the initial droplet diameter of 0.011 m or less and at 1500 m in depth with the diameter of 0.015 m or less. In addition, the hydrate film acts as a resistant layer for the dissolution of liquid carbon dioxide. The surface concentration of carbon dioxide droplet with the hydrate film is about 50% at 1500 m in depth and about 60% at 1000 m in depth of the carbon dioxide solubility. Also, the ambient carbon dioxide concentration in the plume is an another crucial parameter for complete dissolution at the intermediate ocean depth, and the injection of liquid carbon dioxide from a moving ship is more effective than that from a fixed pipeline.

• The Journal of Natural Sciences
• /
• v.8 no.1
• /
• pp.145-151
• /
• 1995

The stretching of synthetic fibers by hot dry process is very difficult, because these fibers have high glass transition temperature at above $150^{\circ}C$. But, we used a swell-wet stretching precess; the fibers are stretched in a swelling agent such as organic solvents at lower temperature. In this study, 100% acryl fibers were uniaxially stretched with free width at $70^{\circ}C$ by swell-wet process in organic solvents. The stretchability was estimated by stretching work. This work is concerned with stretching stress and strain, and initial modulus. We found that it is a good parameter for the estimatation of high strength to the acrylic fiber. The effects of stretching conditions on the molecular orientation for high strength and mechanical properties of PAN fibers were measured.

• Journal of the Korean Society for Railway
• /
• v.11 no.3
• /
• pp.280-285
• /
• 2008

Two kinds of failure model, that is, the Gurson model and a shear failure model were used for the finite element analyses of simple and notch tensile specimens and axial compression of a fracture tube with initial saw-cuts. The parameter values for the shear failure model were determined by a combined experimental and numerical analysis of the notch tensile specimens. After fitting the numerical parameters such as the yielding stress and the fracture shear strains, the Gurson model and the shear failure model were applied to the analysis of the fracture tube. Although the Gurson model and the shear failure model showed similar fracture behavior for the case of the tensile specimens, the respective results were different in the axial force and the crack growth rate of the fracture tube. That is, the shear failure model required more axial force to make the cracks propagate along the tube than the Gurson model. These are believed to show the lack of damage evolution process of the shear failure model. To decide which model is better in the tube analysis, experimental verification will be necessary.

• Korean Journal of Crystallography
• /
• v.14 no.1
• /
• pp.1-6
• /
• 2003

NiZn-ferrites were synthesized from the waste catalysts. which were by product of styrene monomer process and buried underground as an industrial wastes, and their magnetic properties were investigated. Nickel oxide and zinc oxide powders were mixed with finely ground waste catalysts, and spinel type ferrite was obtained by calcination at 900℃ and sintering at 1325℃ for 5 hours. The initial permeabilities were measured and reflection losses were calculated from S-parameters for the composition of Ni/sub x/Zn/sub 1-x/Fe₂O₄(x=0.36, 0.50, 0.66) and (Ni/sub 0.5/Zn/sub 0.5)/sub 1-y/Fe/sub 2+y/O₄(y=-0.02, 0, 0.02).

• Magazine of the Korean Society of Agricultural Engineers
• /
• v.33 no.2
• /
• pp.51-60
• /
• 1991

The main objective of this study is to examine the adaptability for the large watershed of the storage tank model which can be applied for the analysis of both long and short terms runoff developed on the basis of hydrologic data for a smaH mountaineous watershed. The results obtained in this study are summarized as follows ; 1. Areal rainfalls of the Dae Chong watershed were calculated by Thiessen method composed of 9 Thiessen networks. 2. Optimal parameters for two types, Model A and Model B of tank models were derived through calibration procedure by standardized Powell method. 3. Monthly simulated flows of Model B are seemed to be closer to the monthly observed than those of Model A during calibration period in the long terms runoff. 4. Relative errors for the simulated flood flows of Model B were apperaed as lower percentage to the observed than those of Model A during calibration period in the short terms runoff. 5. Daily simulated hydrographs of Model B are seemed to be closer to the daily observed than those of Model A during verification period in the long terms runoff. Significance of Model B was highly acknowledged in comparison with Model A in the correlation analysis between annual observed and annual simulated runoff. 6. Reproducibility of simulated flows for Model B is generally seemed to be better than that of Model A during calibration period in the short terms runoff. 7. It can be concluded that reproducibility of Model B is superior to that of Model A in the long and short terms runoff even a large watershed like the result of the small one. 8. It was verified that adaptability for the large watershed of Model B is superior to that of Model A between the two models which were developed by a small watershed characteristics for both long and short terms runoff. 9. Further study for getting a suitable tank model is desirable to be established by the decision, calibration method of initial parameters of tank model and by additional application of another watershed with different watersheds and meterological characteristics.