• Corrosion Science and Technology
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• 제16권4호
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• pp.187-193
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• 2017

Polymer amines are found to show distinct corrosion inhibition effects in acidic media. The functional groups of organic compounds have a wide role in the physical and chemical properties, for the inhibition efficiency with respect to steric factors, aromaticity, and electron density. The influence of $H^+$ ions and $Cl^-$ ions on the corrosion inhibitive effect of poly(p-aminophenol) for iron in hydrochloric acid was studied using electrochemical methods such as impedance, linear polarization, and Tafel polarization techniques. The experiments were conducted with and without the inhibitor, poly(p-aminophenol). The concentration range of $H^+$ ions and $Cl^-$ ions are from 1 M to 0.05 M and 1 M to 0.1 M, respectively. With the inhibitor poly(p-aminophenol), this study shows that inhibition efficiency decreases with the reduction of $H^+$ ion and $Cl^-$ ion concentrations in aqueous solution. Further, it reveals that the adsorption of an inhibitor on the surface of iron is dependent on the concentrations of $H^+$ and $Cl^-$ ions in the solution and the adsorption of inhibitor on the iron surface through the cationic form of amine.

• 한국물환경학회지
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• 제33권1호
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• pp.8-14
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• 2017

Microcystis aeruginosa (M. aeruginosa) is a cyanobacterium species that can form harmful algal blooms in freshwater bodies worldwide. The use of pine needle extract (PNE) to control nuisance algae by allelopathic inhibition will be environmentally friendly and promising. PNE removed successfully upto 98% of M. aeruginosa at the following optimal conditions: pH 7, $25^{\circ}C$ of temperature, 100 rpm of mixing rate, 5 min of mixing time. These results was indicated that the amount of 1 g/L PNE was removed 1g dryweight/L of M. aeruginosa. The kinetic data showed substrate inhibition kinetics and maximum growth rate was obtained when the M. aeruginosa was grown in medium containing 0.5 g/L of initial concentration of PNE. Different substrate inhibition models were fitted to the kinetic data and found the Luong model was best. The model predicted kinetic parameters were in agreement with the experimental findings. The natural extract, PNE, can be a promising inhibition due to its high efficiency and low dose requirements.

• 한국환경과학회지
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• 제8권3호
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• pp.325-330
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• 1999

This study aims to observe the inhibition of methane generation, the decomposition of organic matter, and the trend of outflowing leachate, using the simulated column of the anaerobic sanitary landfill structure of sulfate addition type which is made by adding sulfate to a current anaerobic landfill structure, and the simulated column of semi-aerobic landfill structure in the laboratory which is used in the country like Japan in order to inhibit methane from a landfill site among the gases caused by a global warming these days, and at the same time to promote the decomposition of organic matter, the index of stabilization of landfill site. As a result of this study, it is thought that the ORP(Oxidation Reduction Potential) of the column of semi-aerobic landfill structure gradually represents a weak aerobic condition as time goes by, and that the inside of landfill site is likely to by in progress into anaerobic condition, unless air effectively comes into a semi-aerobic landfill structure in reality as time goes by. In addition, it can be seen that the decomposition of organic matter is promoted according to sulfate reduction in case of $R_1$, a sulfate-added anaerobic sanitary landfill structure, and that the stable decomposition of organic matter in $R_1$ makes a faster progess than $R_2$. Moreover it can be estimated that $R_1$, a sulfate-added anaerobic sanitary landfill structure has an inhibition efficiency of 55% or so, compared with $R_2$, a semi-aerobic landfill structure, in the efficiency of inhibiting methane.

• Journal of Electrochemical Science and Technology
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• 제10권1호
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• pp.69-81
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• 2019

The corrosion inhibiting mechanism of Vietnam orange peel essential oil (OPEO) for mild steel in 1 N HCl solution was investigated elaborately. Corrosion inhibition ability of OPEO was characterized by electrochemical polarization, electrochemical impedance spectroscopy (EIS), and weight loss method. In the corrosive solution, OPEO worked as a mixed inhibitor and the inhibition efficiency of OPEO increased with the increase of its concentration. High inhibition efficiencies over 90% were achieved for the concentration of 3 - 4 g/L OPEO, comparable to that of 3.5 g/L urotropine (URO), a commercial corrosion inhibitor for acid media used in industry. By using adsorption isotherm models (Langmuir, Temkin and Frumkin), thermodynamic parameters of adsorption were calculated. The obtained results indicated physical adsorption mechanism of OPEO on the steel surface. The components responsible for the corrosion inhibition activity of OPEO were not only D-limonene, but also other compounds, which contain C=O, C=C, O-H, C-O-C, -C=CH and C-H bonding groups in the molecules.

• Corrosion Science and Technology
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• 제7권5호
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• pp.283-287
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• 2008

The drag reduction agency (DRA) for gas pipeline, a novel method used for reducing friction or drag on a gas flowing to increase the transmission efficiency of gas pipeline, is a more flexible and economical technology than internal flow efficient coatings. In this paper, an effective DRA has been developed in Authors' Institute by analyzing the hydrodynamic friction resistance on internal gas pipeline and then studying the work mechanism and molecular structure of DRA. In the meantime, a group of property test for selecting DRA material has been determined, including viscosity, contact angle, volatility, corrosion, slab extending, and flow behavior in horizontal tube. The inhibition efficiency and drag reduction efficiency of the developed DRA have been investigated finally based on the relevant test methods. Results of corrosion test show that the developed DRA has very good inhibition effect on mild steel by brushing a thin layer of DRA on steel specimens, giving inhibition efficiency of 91.2% and 73.1% in 3%NaCl solution and standard salt fog environment respectively. Results of drag-reducing test also show that the Colebrook formula could be used to calculate friction factors on internal pipes with DRA as the Reynolds number is in the range of $0.75\times10^5\sim2.0\times10^5$. By comparing with normal industrial pipes, the friction resistance coefficient of the steel pipe with DRA on internal wall decreases by 13% and the gas flux increases by 7.3% in testing condition with Reynolds number of $2.0\times10^5$.

• Journal of Electrochemical Science and Technology
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• 제4권2호
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• pp.47-56
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• 2013

Inhibition performance of Lornoxicam & Tenoxicam against corrosion of carbon steel in 1M $H_2SO_4$ solutions was investigated by weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements. The inhibition efficiency increased with increasing inhibitor's concentration, but decreased with increase in temperature. Potentiodynamic polarization curves showed that, the inhibitors were of mixed type. The apparent activation energy ($E^*_a$) and other thermodynamic parameters for the corrosion process have also been calculated and discussed. The inhibition of carbon steel corrosion is due to the adsorption of the inhibitor molecules on the surface, which follows Temkin adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors.

• Journal of Electrochemical Science and Technology
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• 제4권2호
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• pp.81-87
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• 2013

Inhibition of corrosion of mild steel in sulphuric acid by acidic extract of Jatropha Curcas leaves has been studied using weight loss and thermometric measurements. It was found that the leaves extract act as a good corrosion inhibitor for mild steel in all concentrations of the extract. The inhibition action depends on the concentration of the Jatropha Curcas leaves extract in the acid solution. Results for weight loss and thermometric measurements indicate that inhibition efficiency increase with increasing inhibitor concentration. The adsorption of Jatropha curcas leaves extract on the surface of the mild steel specimens obeys Langmuir adsorption isotherm. Based on the results, Jatropha curcas leaves extract is recommended for use in industries as a replacement for toxic chemical inhibitors.

• 대한화학회지
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• 제54권6호
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• pp.680-686
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• 2010

인공해수에서 일어나는 구리의 부식에 대하여 알라닌, 아스파라긴, 아스파틱산, 글루타민 그리고 메티오닌의 부식억제 효과를 조사하였다. 아미노산들의 흡착은 흡착 분자들의 상호작용 때문에 Temkin의 logarithmic isotherm이 잘 적용되었으며, 부식억제 효율은 아미노산의 농도에 의존하였다.

• 대한화학회지
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• 제58권1호
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• pp.25-32
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• 2014

Corrosion inhibition of 304 stainless steel (SS) in 1 M HCl by aqueous extract of coriander seeds was studied using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. Values of inhibition efficiency obtained are dependent upon the concentration of extract and temperature. Generally, inhibition was found to increase with inhibitor concentration, but decrease with temperature. Physical adsorption mechanism has been proposed for the inhibition with Langmuir adsorption isotherm obeyed. Values of activation energy of the inhibited corrosion reaction of 304 SS are greater than the value obtained for the blank. Thermodynamic consideration reveals that adsorption of aqueous extract of coriander seeds 304 SS surface is spontaneous.

• Journal of the Korean Association of Oral and Maxillofacial Surgeons
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• 제29권2호
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• pp.86-94
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• 2003

It has been known that transglutaminase C (TGase C, TGase II) is directly participated in the DNA organization of chromosome, and affects the cellular processes such as proliferation, differentiation, and apoptosis of cells, but still not known what mechanism is working on. In this study, the cytogenetic and the immunohistochemical methods were used to observe the TGase C expression in the nuclear chromosome of the proliferating cells, especially in mitotic stage. The human gastric adenocarcinoma (SNU-1) cell line was used for immunohistochemistry and antisense inhibition study in vitro. The present study was also aimed to disclose the efficiency of antisense inhibition by using antisense oligonucleotide DNA labeled with fluorescence, and found that anti-TGase C probe was diffusely infiltrated into the cytoplasm and the nucleus of the cell. By the antisense inhibition the nuclei of SNU-1 cells became rough nuclear shape, as they were greatly reduced in TGase C immunoreactivity both for the normal and apoptotic SNU-1 cells. However, it is clearly presumed that the TGase C directly interacts with the chromosome of SNU-1 cells and it may play an important role in the division and organization of the chromosome during the mitotic stage.