• Title/Summary/Keyword: Infrared analysis

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Identification of the geographical origin of cheonggukjang by using fourier transform near-infrared spectroscopy and energy dispersive X-ray fluorescence spectrometry (근적외선분광분석기 및 에너지 분산형 X선 형광분석기를 이용한 청국장 원산지 판별)

  • Kang, Dong-Jin;Moon, Ji-Young;Lee, Dong-Gil;Lee, Seong-Hun
    • Korean Journal of Food Science and Technology
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    • v.48 no.5
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    • pp.418-423
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    • 2016
  • This study was conducted to identify the geographical origin of soybeans in Cheonggukjang by analyzing its organic components and inorganic elements with Fourier transform near-infrared spectroscopy (FT-NIRS) and with energy dispersive X-ray fluorescence (ED-XRF) coupled with multivariate statistical analysis. For method development, 280 samples from various regions were collected and analyzed. The discriminant accuracy for the developed methods was 97.5% for FT-NIRS and 98.0% for ED-XRF with multivariate statistical analysis. A validation test confirmed the discriminant accuracy to be 96.3% for FT-NIRS and 95.0% for ED-XRF. Overall, the results showed that methods using FT-NIRS and ED-XRF could be used to identify the geographical origin of Cheonggukjang.

Effect of Organic Solvent Extractives on Korean Softwoods Classification Using Near-infrared Spectroscopy

  • Yeon, Seungheon;Park, Se-Yeong;Kim, Jong-Hwa;Kim, Jong-Chan;Yang, Sang-Yun;Yeo, Hwanmyeong;Kwon, Ohkyung;Choi, In-Gyu
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.4
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    • pp.509-518
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    • 2019
  • This study analyzed the effect of organic solvent extractives on the classification of wood species via near-infrared spectroscopy (NIR). In our previous research, five species of Korean softwood were classified into three groups (i.e., Cryptomeria japonica (cedar)/Chamaecyparis obtuse (cypress), Pinus densiflora (red pine)/Pinus koraiensis (Korean pine), and Larix kaempferi (Larch)) using an NIR-based principal component analysis method. Similar tendencies of extractive distribution were observed among the three groups in that study. Therefore, in this study, we qualitatively analyzed extractives extracted by an organic solvent and analyzed the NIR spectra in terms of the extractives' chemical structure and band assignment to determine their effect in more detail. Cedar/cypress showed a similar NIR spectra patterns by removing the extractives at 1695, 1724, and 2291 nm. D-pinitol, which was detected in cedar, contributed to that wavelength. Red pine/Korean pine showed spectra changes at 1616, 1695, 1681, 1705, 1724, 1731, 1765, 1780, and 2300 nm. Diterpenoids and fatty acid, which have a carboxylic group and an aliphatic double bond, contributed to that wavelength. Larch showed a catechin peak in gas chromatography and mass spectroscopy analysis, but it exhibited very small NIR spectra changes. The aromatic bond in larch seemed to have low sensitivity because of the 1st overtone of the O-H bond of the sawdust cellulose. The three groups sorted via NIR spectroscopy in the previous research showed quite different compositions of extractives, in accordance with the NIR band assignment. Thus, organic solvent extractives are expected to affect the classification of wood species using NIR spectroscopy.

Correlation Analysis of Reflectance and Turbidity through Spectral Characteristics of Near-Infrared (근적외선의 분광특성 분석을 통한 반사율과 탁도의 상관관계 분석)

  • Lee, So-Jin;Jeong, Gyo-Cheol;Lee, Chang-Ju;Kim, Jong-Tae
    • The Journal of Engineering Geology
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    • v.32 no.1
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    • pp.101-111
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    • 2022
  • This study analyzed the relationship between water turbidity and its reflectance, as measured using hyperspectral imaging. First, samples of turbid water were generated in boxes. This was followed by drone-based hyperspectral imaging and analysis of the correlation between the samples' measured turbidity and hyperspectral reflectance. The nine boxes for turbidity measurement were made of black acrylic that absorbed all light turbidity was induced using soil collected near Changhacheon, which causes turbidity in Imha Lake. The results indicate that the reflectance of wavelengths in the near-infrared region followed a pattern of increase with increasing soil content for each box. Analysis of this correlation between the turbidity and average reflectance measured in each box yielded a very high R2 value of 0.8702, indicating that reflectance is a suitable proxy for turbidity.

Application of near-infrared spectroscopy for hay evaluation at different degrees of sample preparation

  • Eun Chan Jeong;Kun Jun Han;Farhad Ahmadi;Yan Fen Li;Li Li Wang;Young Sang Yu;Jong Geun Kim
    • Animal Bioscience
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    • v.37 no.7
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    • pp.1196-1203
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    • 2024
  • Objective: A study was conducted to quantify the performance differences of the near-infrared spectroscopy (NIRS) calibration models developed with different degrees of hay sample preparations. Methods: A total of 227 imported alfalfa (Medicago sativa L.) and another 360 imported timothy (Phleum pratense L.) hay samples were used to develop calibration models for nutrient value parameters such as moisture, neutral detergent fiber, acid detergent fiber, crude protein, and in vitro dry matter digestibility. Spectral data of hay samples prepared by milling into 1-mm particle size or unground were separately regressed against the wet chemistry results of the abovementioned parameters. Results: The performance of the developed NIRS calibration models was evaluated based on R2, standard error, and ratio percentage deviation (RPD). The models developed with ground hay were more robust and accurate than those with unground hay based on calibration model performance indexes such as R2 (coefficient of determination), standard error, and RPD. Although the R2 of calibration models was mainly greater than 0.90 across the feed value indexes, the R2 of cross-validations was much lower. The R2 of cross-validation varies depending on feed value indexes, which ranged from 0.61 to 0.81 in alfalfa, and from 0.62 to 0.95 in timothy. Estimation of feed values in imported hay can be achievable by the calibrated NIRS. However, the NIRS calibration models must be improved by including a broader range of imported hay samples in the modeling. Conclusion: Although the analysis accuracy of NIRS was substantially higher when calibration models were developed with ground samples, less sample preparation will be more advantageous for achieving rapid delivery of hay sample analysis results. Therefore, further research warrants investigating the level of sample preparations compromising analysis accuracy by NIRS.

Kinetic Analysis of Human Simulation for the Soft Golf Swing (소프트 골프 스윙 동작을 위한 인체 시뮬레이션의 운동역학 분석)

  • Kwak, K.Y.;Yu, M.;So, H.J.;Kim, S.H.;Kim, N.G.;Kim, D.W.
    • Journal of Biomedical Engineering Research
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    • v.31 no.2
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    • pp.141-150
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    • 2010
  • The purpose of this study was to analyze the golf swing motion for a soft golf clubs and regular golf club. Soft golf is a newly developed recreational sports for all ages, including the elderly and the beginners of golf. To quantify the effect of using soft golf club, which much lighter club than regular clubs, a motion analysis has been performed using a 3D optoelectric motion tracking system that utilizes active infrared LEDs and near-infrared sensors. The subject performed swing motion using a regular golf club and a soft golf club in turn. The obtained motion capture data was used to build a 3D computer simulation model to obtain left wrist, elbow shoulder and lumbar joint force and torque using inverse and forward dynamics calculations. The joint force and torque during soft golf swing were lower than regular golf swing. The analysis gave better understanding of the effectiveness of the soft golf club.

Structure and Properties in the $PbO-B_2O_3$ Glass System with Addition of Divalent Metallic Oxides (2가 금속산화물 첨가에 따른 납붕산염유리의 구조 및 물성)

  • 이찬수;김철영
    • Journal of the Korean Ceramic Society
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    • v.20 no.3
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    • pp.236-242
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    • 1983
  • The purpose of present study is to find the structures physical properties and their inter-relations in the system of (60-x) PbO.xMO.$40B_2O_3$ glasses where MO represents for ZnO and CdO. The experiments such as differential thermal analysis infrared spectral analysis X-ray diffraction analysis density and thermal expansion measurements have been done. From infrared spectral analysis the structural units of glasses and the corresponding crystallized glasses were com-posed of $BO_3$ triangles and $BO_4$ tetrahedra. These basic units found in $PbO-B_2O_3$ binary glass system did not charge even though the divalent metallic oxides were substituted for PbO. The structures of these ternary glasses were more coalescenced than $PbO-B_2O_3$ binary glass system. This fact was supported bydecrease in thermal expansion coeffici-ent and molar volume with substitution of divalent metallic oxide for PbO. Crystalline phases obtained from the heat treatment of the $PbO-ZnO-B_2O_3$ glasses were 4PbO.2ZnO.$5B_2O_3$ PbO.2ZnO.$B_2O_3$ and unknown phases.

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A Frequency Spectrum Analysis based on FFT of Fire Thermal Image (FFT를 이용한 화재 열영상의 주파수 스펙트럼 분석)

  • Kim, Won-Ho;Jang, Bok-Gyu
    • Journal of the Institute of Convergence Signal Processing
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    • v.12 no.1
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    • pp.33-37
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    • 2011
  • This paper presents the frequency spectral analysis based on FFT of the infrared ray fire thermal image, it is an object to deduce the conditions for determining fire alarm through the image processing with the frequency domain. After the candidate regions are separated by using pre-defined brightness value, the fast fourier transform is performed for consecutive infrared thermal images, the frequency spectral analysis of the thermal image analyzed DC and AC frequency distribution. The fire criterion of the thermal image was presented based on the analyzed result and a practicality was confirmed through the computer simulation.

USE OF NEAR-INFRARED SPECTROSCOPY TO PREDICT OIL CONTENT COMPONENTS AND FATTY ACID COMPOSITION IN OLIVE FRUIT

  • Lorenzo, Leon-Moreno;Ana, Garrido-Varo;Luis, Rallo-Romero
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1512-1512
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    • 2001
  • The University of Cordoba conducts since 1991 a breeding program to obtain new olive cultivars from intraspecific crosses. The objective is to obtain new early bearing and high-quality cultivars. In plant breeding, many seedlings must be tested to increased the chance of getting desirable genotypes. Therefore, fast, cheap and accurate methods of analysis are necessary. The conventional laboratory techniques are costly and time-consuming. Near Infrared Spectroscopy (NIRS) can satisfy the characteristics requested by plant breeders and offers many advantages such as the simultaneous analysis of many traits and cheap cost. The objective of this work was to asses the performance of NIRS to estimate oil fruit components (fruit weight, flesh moisture, flesh/stone ratio and oil flesh content in dry weight basis) and fatty acid composition in olive fruit. Genotypes from reciprocal crosses between ‘Arbequina’, ‘Frantoio’ and ‘Picual’ cultivars have been used in this study. A total of 287 samples, each from a single plant, were scanned using a DA-7000 Diode Array VIS/NIR Analysis System (Perten Instruments), which covers the visible and NIR range from 400-1700 nm. All samples were analysed for fatty acid composition (gas chromatography) and 220 for oil fruit components (oil content by nuclear magnetic resonance), 70% and 30% of samples were randomly assign for the calibration and validation sets respectively. The preliminary results shows that calibration for palmitic, oleic and linoleic acids were highly accurate with calibration and validation values of $r^2$ from 0.85 to 0.95 and 0.76 to 0.91 respectively. Calibration for palmitoleic and estearic acids were less accurate, probably because of the narrow range of variability available for these fatty acids. For the oil fruit components, calibration were high accurate for flesh moisture and oil flesh content in dry weight basis ($r^2$ higher than 0.90 in both calibration and validation sets) and less accurate for the other characteristics evaluated. The first results obtained indicate that NIRS analysis could be an ideal technique to reduce the cost, time and chemical wasted necessary to evaluate a large number of genotypes and it is accurate enough to use for pre-selecting genotypes in a breeding program.

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PREDICTION OF PHYSICO-CHEMICAL AND TEXTURE CHARACTERISTICS OF BEEF BY NEAR INFRARED TRANSMITTANCE SPECTROSCOPY

  • Olivan, Mamen;Delaroza, Begona;Mocha, Mercedes;Martinez, Maria Jesus
    • Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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    • 2001.06a
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    • pp.1256-1256
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    • 2001
  • The physico-chemical and texture characteristics of meat determine the nutritional, technological and sensory quality. However, the analysis of meat quality requires expensive, laborious and time consuming analytical methods. The objective of this study was to evaluate NIR spectroscopy using transmittance for determining the moisture, fat, protein and total pigment content, the water holding capacity (WHC) and the toughness of beef meat. A total of 318 spectra were recorded from ground beef samples by a Feed Analyzer 1265 of Infratec. The samples were obtained from the Longissimus muscle of the 10$^{th}$ rib of yearling bulls, ground with an electrical chopper, vacuum packaged, aged during 7 days and frozen at -24$^{\circ}C$ until the analyses were done. Moisture content was measured by oven drying at 10$0^{\circ}C$, fat content was determined by Soxhlet extraction and protein content was estimated from nitrogen content using the Kjeldahl analysis. The total pigment content was determined by the method of Hornsey and the WHC using the method of filter paper press. The instrumental evaluation of texture (maximum load WB, maximum stress MS and toughness) was conducted in an Instron equipment with a Warner-Bratzler shearing device. This analysis was performed on a chop of 3.5 cm obtained from the longissimus of the 8$^{th}$ rib, aged during 7 days, kept frozen at -24$^{\circ}C$ and cooked before the analysis. Near infrared spectra were recorded as log 1/T (T=transmittance) at 2 nm intervals from 850 to 1050 nm using a Feed Analyzer 1265 of Infratec. Calibrations were performed with the WinISI software (vs. 1.02) using the MPLS method. To examine the effect of scatter correction o. derivation of spectra on the calibration performance, calibrations were calculated with the crude spectra or pretreated with different mathematical treatments (inverse MSC, SNVD) and/or second derivative operation. For chemical composition, the use of the scatter corrections improved the calibration statistics, in terms of lower SECV and higher $r^2$. In most of the variables, the use of the 2$^{nd}$ derivative improved the predictions, mainly when combined with the SNVD treatment. However, for predicting the texture traits, the best estimation was obtained from the crude spectrum. These results showed that the equations obtained for predicting moisture, fat and total pigments were very accurate, with $r^2$ being higher that 0.9. However, the prediction of the texture traits (WB, MS, toughness) from ground meat was poor.

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Utilization of Near Infrared Spectroscopy for Analysis of Proximate Composition and Starch in Alaska Pollack Surimi (명태 수리미의 일반성분 및 전분의 분석을 위한 근적외선 분광분석법의 이용)

  • Song Ho Su;Lee Keun Tai;Park Seong Min;Hwang Sun Young
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.4
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    • pp.321-326
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    • 2002
  • Near infrared spectroscopy (NIR), is recently applied to analysis of food, and it gives non-destructive and highly reproducible results. The objectives of this study were to assay protein, lipid and starch content in Alaska pollack surimi and to investigate application in seafood. NIR spectra showed the absorbance signal at 1,510 nm, 2,050 nm, 2,170 nm and 2,180 nm for protein, and signal were increased with protein content. Standard error of equation (SEE) was 0,296 and standard error of prediction (SEP) was 0.327. In analysis of lipid in Alaska pollack surimi by NIR, near infrared spectra of lyophilized Alaska pollack surimi were scanned and the signals of absorbance from C-H functional groups in lipid were identified at 1,730 nm, 1,740 nm and 2,300 nm and these signals were risen as Increasing lipid contents of Alaska pollack surimi as samely protein. SEE and SEP were 0.319, 0,353, respectively. In starch analysis using NIR the signals of starch distinctly changed at wavelength of 1,450 nm and 1,950 nm. Collected values of SEE and SEP were 0.304 and 0.318, respectively and the range of errors was $0.0186\~0.6470$ in starch contents.