• 제목/요약/키워드: Inert gases

검색결과 82건 처리시간 0.023초

플라즈마 화학증법에 의해 형성된 Diamondlike Carbon 박막의 광학적 특성에 미치는 수소가스의 영향 (Effects of Hydrogen Gas on the Optical Properties of Diamondlike Carbon Thin Films Prepared by Plasma Enhanced Chemical Vapor Deposition)

  • 김한도;주승기
    • 한국재료학회지
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    • 제4권2호
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    • pp.152-158
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    • 1994
  • 메탄가스를 반응가스로 하여 플라즈마 화학증착법으로 Diamondlike Carbon(DLC)박막 제작시 박막의 광학적 특성에 미치는 수소가스의 영향을 조사하였다. 수소가스를 보조가스로 사용하는 경우는 불활성가스인 아르곤이나 헬륭의 경우와는 달리 인가전력의 변화에 따라 수소가스의 역할이 다르게 나타났다. Optical band gap의 변화와 FT-IR 분석결과로부터 수소가스에 의한 C-H 결합의 화학적인 에칭과 스퍼터링 및 수소의 박막 내로의 주입 가능성을 예측하고 이를 아르곤과 헬륨을 보조가스로 사용한 경우와 비교하여 그 타당성을 확인하였다.

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중자에서 발생한 가스 결함 위치 예측 (Prediction of Positions of Gas Defects Generated from Core)

  • 마쓰시타 마코토;코사카 아키라;카나타니 시게히로
    • 한국주조공학회지
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    • 제42권1호
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    • pp.61-66
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    • 2022
  • Hydraulic units are important components of agricultural and construction machinery, and thus require high-quality castings. However, gas defects occurring inside the sand cores of the castings due to the resin used is a problem. This study therefore aimed to develop a casting simulation method that can clarify the gas defect positions. Gas defects are thought to be caused by gas generated after the molten metal fills up the mold cavity. The gas constant is the most effective factor for simulating this gas generated from sand cores. It is calculated by gas generating temperature and analysis of composition in the inert gas atmosphere modified according to the mold filling conditions of molten metal. It is assumed that gases generated from the inside of castings remain if the following formula is established. [Time of occurrence of gas generation] + [Time of occurrence of gas floating] > [Time of occurrence of casting surface solidification] The possibility of gas defects is evaluated by the time of occurrence of gas generation and gas floating calculated using the gas constant. The residual position of generated gases is decided by the closed loops indicating the final solidification location in the casting simulation. The above procedure enables us to suggest suitable casting designs with zero gas defects, without the need to repeat casting tests.

The advancing techniques and sputtering effects of oxide films fabricated by Stationary Plasma Thruster (SPT) with Ar and $O_2$ gases

  • Jung Cho;Yury Ermakov;Yoon, Ki-Hyun;Koh, Seok-Keun
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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    • pp.216-216
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    • 1999
  • The usage of a stationary plasma thruster (SPT) ion source, invented previously for space application in Russia, in experiments with surface modifications and film deposition systems is reported here. Plasma in the SPT is formed and accelerated in electric discharge taking place in the crossed axial electric and radial magnetic fields. Brief description of the construction of specific model of SPT used in the experiments is presented. With gas flow rate 39ml/min, ion current distributions at several distances from the source are obtained. These was equal to 1~3 mA/$\textrm{cm}^2$ within an ion beam ejection angle of $\pm$20$^{\circ}$with discharge voltage 160V for Ar as a working gas. Such an extremely high ion current density allows us to obtain the Ti metal films with deposition rate of $\AA$/sec by sputtering of Ti target. It is shown a possibility of using of reactive gases in SPT (O2 and N2) along with high purity inert gases used for cathode to prevent the latter contamination. It is shown the SPT can be operated at the discharge and accelerating boltages up to 600V. The results of presented experiments show high promises of the SPT in sputtering and surface modification systems for deposition of oxide thin films on Si or polymer substrates for semiconductor devices, optical coatings and metal corrosion barrier layers. Also, we have been tried to establish in application of the modeling expertise gained in electric and ionic propulsion to permit numerical simulation of additional processing systems. In this mechanism, it will be compared with conventional DC sputtering for film microstructure, chemical composition and crystallographic considerations.

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AC plasma display panel의 페닝 방전가스 혼합비 변화에 따른 방전특성 연구 (A Study on the Discharge Characteristics with New Penning Gas Mixture for AC plasma display panel)

  • 박문필;이승준;이재경;황호정
    • 한국진공학회지
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    • 제11권2호
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    • pp.127-134
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    • 2002
  • 본 논문은 AC PDP에서 사용하는 가스의 혼합비, 압력, 페닝 효과를 고려한 가스 조합의 최적화를 통해 낮은 방전전압으로 휘도의 증가를 얻을 수 있는 고휘도, 고효율 PDP 페닝 기체 혼합비를 찾고자 하였다. He(70%)-Ne(27%)-Xe(3%)의 3원 혼합기체와 Ne(96%)Xe(4%)의 2원 혼합기체에 페닝 효과를 극대화하기 위한 소량의 Ar, Kr을 첨가하여 각각의 첨가비에 따른 방전 개시전압, 방전 유지전압, 휘도, 발광효율 등을 측정하였다. 또한 페닝효과에 의한 방전 공간상의 전자수 증가를 확인하기 위해 셀 내의 전극 위에 쌓이는 벽전하 양을 측정하였다. 소량의 Ar(0.01%-0.03%) 또는 Kr(0.01%-0.03%)을 HE-Ne-Xe과 Ne-Xe 혼합가스에 첨가했을 때 페닝효과에 기인하여 휘도 및 발광효율이 각각 최고 10%-20% 증가하였다. 또한 페닝효과를 확인하기 위한 벽전하의 양은 10%-25% 증가를 보였다. 방전개시전압 및 최소방전유지전압은 대략 2V-3V정도 감소하였다.

Methyl Bromide를 대체하는 훈증 가스의 문화재 재질 안정성 평가 II (The 2nd Stability Appraisement on Cultural Property Material with the Replacing Fumigation Gas of Methyl Bromide II)

  • 강대일
    • 보존과학회지
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    • 제25권4호
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    • pp.465-471
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    • 2009
  • 본 연구에서는 Methyl Bromide를 대체할 15% Ethylene Oxide + 85% HFC 134a, 20% Ethylene Oxide + 80% $CO_2$, 99% Sulfuryl Fluoride + 1% Inert Gas를 이용하여 훈증처리 시, 금속, 안료, 섬유 및 지류시편에 미치는 영향을 관찰한 실험이다. 15% Ethylene Oxide + 85% HFC 134a을 200g/$m^3$, 48시간 훈증 처리 한 결과 Cu 시편은 1차 및 2차 훈증처리 실험 모두 육안으로 식별할 수 있는 평균 3.40, 4.17의 색차값을 나타났다. 그 외의 시편에서는 색차값이 3.0 미만으로 나타났다. 20% Ethylene Oxide + 80% $CO_2$을 150g/$m^3$, 48시간 처리한 1, 2차 훈증처리 모두 전체적으로 실험군의 색차값이 평균 3.0 미만으로 나타났으며 이는 육안으로 식별할 수 없는 미미한 색차이다. 이에 따라 이 연구에 사용된 재질에 비교적 안정적이라고 판단된다. 99% Sulfuryl Fluoride + 1% Inert Gas로 50g/$m^3$, 48시간 처리한 결과, 안료 중 장단 시편은 1, 2차 훈증처리 시 대조군의 색차값과 비교하여 보았을 때 3.0이상 색차값의 변화가 나타났다. 그 외의 시편에서는 색차값이 평균 3.0 미만으로 나타났다.

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Gasification from Surface during Discharge and Thermal Processes in Plasma Display Panel (PDP)

  • Soh, Hyun;Lee, Sang-Moo;Kim, Young-Chai
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.495-498
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    • 2004
  • PDP use the mixture of inert gases to generate a discharge inside display pixels. Inside of PDP, there exist highly reactive conditions in the gap between two glass panels. MgO layer and phosphor have been investigated as a function of discharge and thermal process. Impurities such as CO, $CO_2$, OH and $H_2O$ in discharge region may deteriorate the characteristics of PDP operation during life time. Change of impurity generation of various MgO and phosphor surfaces were measured by using x-ray photoelectron spectroscopy(XPS) and quadropole mass spectrometer (QMS). Carbon containing species such as C, CO and $CO_2$ were drastically increased on the surfaces during discharge and thermal treatment. Carbon impurities on the MgO and phosphor are the dominant factor for their instability.

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메탄/산소 난류 확산화염의 연소 특성에 관한 연구 (A Study on Combustion Characteristics of Turbulent Methane/Oxygen Diffusion Flames)

  • 이상민;김호근;김한석;안국영
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.118-123
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    • 2004
  • The combustion characteristics of 0.03MW turbulent methane/oxygen diffusion flames have been investigated to give basic informations for designing industrial oxyfuel combustors. NOx reduction has become one of the most determining factors in the combustor design since 3-5% nitrogen is intrinsically included from the current oxygen producing processes. Flame lengths and NOx concentrations were measured by varying flow velocities with and without installing quarls. Flame stabilities are significantly enhanced by oxyfuel combustion in contrast to air-fuel combustion. Flame length decreases with increasing fuel or oxygen velocity because of the enhancement of turbulent mixing. NOx concentration was reduced with increasing flo velocities. This can be attributed to the entrainment of inert product gases into flame decreasing flame temperature. The installation of quarl on the burners rather increased NOx concentration since the quarl blocked the entrainment above the nozzles.

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충전층 메탄화 반응기의 수학적 모델 및 전산 수치해석 (Mathematical Model and Numerical Analysis for Packed Bed Methanation Reactors)

  • 지준화
    • 한국수소및신에너지학회논문집
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    • 제26권3호
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    • pp.260-270
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    • 2015
  • One-dimensional packed bed reactor model accounting for interfacial and intra-particle gradients was developed and based on it numerical analyses were performed to investigate the dynamic behavior of a commercial scale methanation reactor. Methanation reaction was almost complete near the reactor inlet and gases with equilibrated composition were discharged from the reactor. Both the intra-particle temperature gradient and differential surface temperature rise were found to be severe near the reactor inlet. To reduce the possible degradation or fracture of catalyst particles and prevent local overheating on the catalyst, addition of inert material can be an effective way.

The influence of atomosphere on high temperature crystal growth

  • Klimm, D.;Schroder, W.
    • 한국결정성장학회지
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    • 제9권4호
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    • pp.360-364
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    • 1999
  • The growth of crystals with high melting point$t_{fus}$$\geq$$1600^{\circ}C$ faces the researcher with experimental problems, as the choice of materials that withstand such high t is rather limited. Many metallic construction materials are in this high t range already molten or exhibit at least a drastically reduced mechanical strength. The very few materials with$t_{fus}$$1600^{\circ}C$ as e.g. W, Mo, and partially even Ir are more or less sensitive against oxygen upon heating. Whenever possible, high t crystal growth is performed under inert atmosphere (noble gases). Unfortunately, many oxides are not thermodynamically stable under such conditions, as reduction takes place within such atmosphere. A thoroughly search for suitable growth conditions has to be performed, that are on the one side "oxidative enough" to keep the oxides stable and on the other side "reductive enough" to avoid destruction of constructive parts of the crystal growth assembly. The relevant parameters are t and the oxygen partial pressure${po}_{2}$. The paper discusses quantitatively relevant properties of interesting oxides and construction materials and wasy to forecast theri behavior under growth conditions.

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흡기조성 변화에 따른 디젤 기관의 연소 특성 변화 (A Study on the Combustion Characteristics of Diesel Engine by the Change of the Intake Air Composition)

  • 김세원;임재문
    • Journal of Advanced Marine Engineering and Technology
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    • 제18권2호
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    • pp.91-96
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    • 1994
  • Intake gases other than air, which is composed of oxygen, nitrogen, carbon dioxide, and argon, are used to study their effects on the performance of the diesel engine experimentally. The engine is operated at constant speed and fixed fuel injection timing, and cylinder pressure and heat release rate are measured at various intake gas compositions. The results show that increase of oxygen concentration improves the performance of the engine generally. The adverse effect is observed when the oxygen concentration is increased over the critical oxygen concentration of this test, mainly because of the over-shortened ignition delay. Increase of carbon dioxide concentration degardes the performance of the engine, mainly due to the lower specific heat ratio of carbon dioxide. Adding argon gas to the intake gas improves the overall performance. Finally, it is found that two most influencing factors affecting the performance of the diesel engine in this study are ignition delay and speific heat ratio of the intake gas.

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