• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.10 no.1
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• pp.32-44
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• 2000

The practice of welding stainless steel is known to produce various valance states of chromium. $CO_2$ flux cored arc welding on stainless was performed in fume collection chamber. Content of total chromium and hexavalent chromium in fumes, content of hexavalent chromium in total chromium, solubility of hexavalent chromium were investigated. Content of total chromium in fumes increases from 2~3% to 7~9% as a function of input energy, but hexavalent chromium, less than 1.2% in fumes, is not related to input energy. Hexavalent chromium in fumes exists as solubles up to 90%. Content of total chromium in flux cored arc welding fumes and solubility of hexavalent chromium are similar to shielded metal arc welding fumes, but content of hexavalent chromium is similar to metal inert gas welding fumes. These characteristics are relevant to flux of wires and $CO_2$ shielding gas.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.9 no.1
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• pp.132-136
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• 1999

Mechanical alloying (MA) by ball mill of $Fe_{30}Cr_{70}$ elemental powders was carried out under the nitrogen gas atmosphere. Amorphization has been observed in this case, while MA under an inert argon gas atmosphere produces the bcc solid solution. The DSC spectrum for the mechanically alloyed $(Fe_{30}Cr_{70})_{0.85}N_{0.15)$powders exhibits a sharp exothermic peak due to crystallization at about $550^{\circ}C$. Structural transformation from the bcc crystalline to amorphous states was observed through X-ray and neutron diffractions. During amorphization process the octahedral unit, which is typical of a polyhedron formed in any crystal structures, was preferentially destroyed and transformed into the tetrahedral unit. Futhermore, neutron diffraction measurements revealed that a nitrogen atom is situated at a center of the tetrahedron formed by metal atoms.

• Journal of Energy Engineering
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• v.19 no.3
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• pp.188-194
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• 2010

Direct Carbon Fuel Cell(DCFC), unlike gas turbines or engines, is a kind of fuel cell which directly generates electricity by electrochemical reaction from a carbon fuel. The advantages of DCFC are higher efficiency and lower emission in comparison with existing power generation facilities. In this study, the effects of CO and $CO_2$ on theoretical potential are examined using the thermodynamic equilibrium method, and the dependence of product on operating temperature is examined via two dimensional CFD method. As a result, when the reaction of CO production (Boudouard reaction) considered, theoretical potential is higher than that in only $CO_2$ reactions, and its value increases as temperature increases. Two dimensional results of computational fluid dynamics(CFD) confirm that the Boudouard reaction becomes more important to be considered as temperature increases and inert gas affects the equilibrium composition of the Boudouard reaction.

• Journal of Powder Materials
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• v.18 no.2
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• pp.141-148
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• 2011

Carbon material shows relatively high strength at high temperature in vacuum atmosphere and can be easily removed as CO or $CO_2$ gas in oxidation atmosphere. Using these characteristics, we have investigated the applicability of carbon mold for precision casting of high melting point metal such as nickel. Disc shape carbon mold with cylindrical pores was prepared and Ni-base super alloy (CM247LC) was used as casting material. The effects of electroless Nickel plating on wettability and cast parameters such as temperature and pressure on castability were investigated. Furthermore, the proper condition for removal of carbon mold by evaporation in oxidation atmosphere was also examined. The SEM observation of the interface between carbon mold and casting materials (CM247LC), which was infiltrated at temperature up to $1600^{\circ}C$, revealed that there was no particular product at the interface. Carbon mold was effectively eliminated by exposure in oxygen rich atmosphere at $705^{\circ}C$ for 3 hours and oxidation of casting materials was restrained during raising and lowering the temperature by using inert gas. It means that the carbon can be applicable to precision casting as mold material.

• Journal of the Korean Ceramic Society
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• v.47 no.6
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• pp.590-597
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• 2010

HTGR using a TRISO coated particles as nuclear raw fuel material can be used to produce clean hydrogen gas and process heat for a next-generation energy source. For these purposes, a TRISO coated particle was prepared with 3 pyro-carbon (buffer, IPyC, and OPyC) layers and 1 silicone carbide (SiC) layer using a CVD technique on a spherical $UO_2$ kernel surface as a fissile material. In this study, a spherical $UO_2$ particle was prepared using a modified sol-gel method with a vibrating nozzle system, and TRISO coating fabrication was carried out using a fluidized bed reactor with coating gases, such as acetylene, propylene, and methyltrichlorosilane (MTS). As the results of this study, a spherical $UO_2$ kernel with a sphericity of 1+0.06 was obtained, and the main process parameters in the $UO_2$ kernel preparation were the well-formed nature of the spherical ADU liquid droplets and the suitable temperature control in the thermal treatment of intermediate compounds in the ADU, $UO_3$, and $UO_2$ conversions. Also, the important parameters for the TRISO coating procedure were the coating temperature and feed rate of the feeding gas in the PyC layer coating, the coating temperature, and the volume fraction of the reactant and inert gases in the SiC deposition.

• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.216-216
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• 1999

The usage of a stationary plasma thruster (SPT) ion source, invented previously for space application in Russia, in experiments with surface modifications and film deposition systems is reported here. Plasma in the SPT is formed and accelerated in electric discharge taking place in the crossed axial electric and radial magnetic fields. Brief description of the construction of specific model of SPT used in the experiments is presented. With gas flow rate 39ml/min, ion current distributions at several distances from the source are obtained. These was equal to 1~3 mA/$\textrm{cm}^2$ within an ion beam ejection angle of $\pm$20$^{\circ}$with discharge voltage 160V for Ar as a working gas. Such an extremely high ion current density allows us to obtain the Ti metal films with deposition rate of $\AA$/sec by sputtering of Ti target. It is shown a possibility of using of reactive gases in SPT (O2 and N2) along with high purity inert gases used for cathode to prevent the latter contamination. It is shown the SPT can be operated at the discharge and accelerating boltages up to 600V. The results of presented experiments show high promises of the SPT in sputtering and surface modification systems for deposition of oxide thin films on Si or polymer substrates for semiconductor devices, optical coatings and metal corrosion barrier layers. Also, we have been tried to establish in application of the modeling expertise gained in electric and ionic propulsion to permit numerical simulation of additional processing systems. In this mechanism, it will be compared with conventional DC sputtering for film microstructure, chemical composition and crystallographic considerations.

• Journal of the Korean Society of Safety
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• v.26 no.2
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• pp.42-47
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• 2011

Going underwater is supposed to begin with the history of human beings. At first it was confined to relatively shallow level, less than several meters by holding breath. Recently, deep level diving has been necessary for such purpose as construction, maritime salvage, military operations, research and sports by using SCUBA(self-contained underwater breathing apparatus) equipment. As one goes down into water, the pressure on the diver is increased due to water pressure with depth, usually 1 atm for each 10 m water level. In deep water, mixed gas or nitrox(EAN, enriched air nitrox) could be applied for the divers lest they should get disease due to high pressure. Of these, the former is usually composed of oxygen and inert gas like helium or hydrogen, the latter contains higher oxygen content than that in normal air in which the oxygen concentration is designated by the character "EAN" followed by vol. % of oxygen, for example, "EAN 40" contains 40% of oxygen. In this case, a victim was found at the 39 m below the sea surface breathing air and nitrox in cylinder wrongly marked as EAN 36, which was analyzed to contain 63% of oxygen by GC/TCD. The cause of death could not be exactly related with the oxygen content in the nitrox cylinder, because the accurate depth for the victim to dive was not known, even though the victim was just found at the depth of 39 m. However, the wrongly marked nitrox could be believed to be the main cause of the death at the depth unless there happened any other accident except that during diving.

• Journal of Welding and Joining
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• v.34 no.2
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• pp.59-66
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• 2016

The Gas Metal Arc(GMA) welding, called Metal Inert Gas(MIG) welding, has been an important component in manufacturing industries. A key technology for robotic welding processes is seam tracking system, which is critical to improve the welding quality and welding capacities. The objectives of this study were to develop the intelligent and cost-effective algorithms for image processing in GMA welding which based on the laser vision sensor. Welding images were captured from the CCD camera and then processed by the proposed algorithm to track the weld joint location. The proposed algorithms that commonly used at the present stage were verified and compared to obtain the optimal one for each step in image processing. Finally, validity of the proposed algorithms was examined by using weld seam images obtained with different welding environments for image processing. The results proved that the proposed algorithm was quite excellent in getting rid of the variable noises to extract the feature points and centerline for seam tracking in GMA welding and could be employed for general industrial application.

• Nuclear Engineering and Technology
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• v.45 no.7
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• pp.941-950
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• 2013

The Korean Nuclear-Hydrogen Technology Development (NHTD) Plan will be performing irradiation testing of coated particle fuel at HANARO to support the development of VHTR in Korea. This testing will be carried out to demonstrate and qualify TRISO-coated particle fuel for use in VHTR. The testing will be irradiated in an inert gas atmosphere without on-line temperature monitoring and control combined with on-line fission product monitoring of the sweep gas. The irradiation device contains two test rods, one has nine fuel compacts and the other five compacts and eight graphite specimens. Each compact contains about 260 TRISO-coated particles. The irradiation device is being loaded and irradiated into the OR5 hole of the in HANARO core from August 2013. The device will be operated for about 150 effective full-power days at a peak temperature of about $1030^{\circ}C$ in BOC (Beginning of Cycle) during irradiation testing. After a peak burn-up of about 4 atomic percentage and a peak fast neutron fluence of about $1.7{\times}10^{21}\;n/cm^2$, PIE (Post-Irradiation Examination) of the irradiated coated particle fuel will be performed at IMEF (Irradiated Material Examination Facility). This paper reviews the design of test rod and irradiation device for coated particle fuel, and discusses the technical results for irradiation testing at HANARO.

• Journal of the Korean Society of Marine Environment & Safety
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• v.29 no.4
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• pp.356-362
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• 2023

The risk of climate change has been long acknowledged, and ongoing efforts to overcome this issue, within the shipping sector, with the international maritime organization playing a central role. Conducting research on characteristics of soot formation is crucial to control its occurrence within the combustion process. In this study, the laser extinction method and chemical reaction numerical analysis were employed to examine the alterations in the state of chemical species associated with flame temperature, flame visual, and soot formation by mixing nitrogen, an inert gas, in the counterflow diffusion flame based on ethylene gas. The findings of the study suggest that as the mixing ratio of nitrogen increased, both the flame temperature and soot volume fraction decreased. Additionally, the area in which soot particles were distributed also decreased, and the volume fraction decrease rate declined when the mixing ratio increased by more than 30%. The mole fraction of the chemical species involved in soot growth also decreased. the chemical species associated with the HACA reaction were affected by variations in the hydrocarbon fuel ratio, and the chemical species related to the odd carbon path were confirmed to be affected by the flame temperature as well as the hydrocarbon fuel ratio.