• 제목/요약/키워드: Inert gas

검색결과 384건 처리시간 0.028초

고체추진제 비-정상연소의 선형 안정성해석 (A Linear Stability Analysis of Unsteady Combustion of Solid Propellants)

  • 이창진;김성인;변영환
    • 한국추진공학회지
    • /
    • 제2권1호
    • /
    • pp.59-66
    • /
    • 1998
  • 고체 추진제 연소불안정에 관한 해석은 준-정상 1차원 해석인 QSHOD(Quasi-Steady Homo-geneous One-Dimension)에 의하여 단순화된 지배방정식을 이용하여 응축영역을 해석하는 것이 일반적이다. 이때 외부교란에 대한 기체영역과 표면반응 영역의 응답은 화학반응이 발생하지 않는 고체영역의 응답에 비하여 매우 빠르므로 준-정상적인 거동을 한다. 본 연구에서는 복사열전달에 의한 열속(heat flux)이 고체 추진제의 표면에 존재하며 이 중의 일부가 고체영역으로 흡수될 때 표면에서의 선형교란을 고려한 ZN(Zeldovich-Novozhilov) 방법을 이용하여 연소불안정 현상을 이론적으로 해석하여 연소불안정 현상을 설명할 수 있는 연소 응답함수를 구하였다. 응답함수는 T-burner의 실험결과를 예측할 수 있음을 보여주었다.

  • PDF

Magnetotransport Properties of Co-Fe/Al-O/Co-Fe Tunnel Junctions Oxidized with Microwave Excited Plasma

  • Nishikawa, Kazuhiro;Orata, Satoshi;Shoyama, Toshihiro;Cho, Wan-Sick;Yoon, Tae-Sick;Tsunoda, Masakiyo;Takahashi, Migaku
    • Journal of Magnetics
    • /
    • 제7권3호
    • /
    • pp.63-71
    • /
    • 2002
  • Three fabrication techniques for forming thin barrier layer with uniform thickness and large barrier height in magnetic tunnel junction (MTJ) are discussed. First, the effect of immiscible element addition to Cu layer, a high conducting layer generally placed under the MTJ, is investigated in order to reduce the surface roughness of the bottom ferromagnetic layer, on which the barrier is formed. The Ag addition to the Cu layer successfully realizes the smooth surface of the ferromagnetic layer because of the suppression of the grain growth of Cu. Second, a new plasma source, characterized as low electron energy of 1 eV and high density of $10^{12}$ $cm^{-3}$, is introduced to the Al oxidation process in MTJ fabrication in order to reduce damages to the barrier layer by the ion-bombardment. The magnetotransport properties of the MTJs are investigated as a function of the annealing temperature. As a peculiar feature, the monotonous decrease of resistance area product (RA) is observed with increasing the annealing temperature. The decrease of the RA is due to the decrease of the effective barrier width. Third, the influence of the mixed inert gas species for plasma oxidization process of metallic Al layer on the tunnel magnetoresistance (TMR) was investigated. By the use of Kr-O$_2$ plasma for Al oxidation process, a 58.8 % of MR ratio was obtained at room temperature after annealing the junction at $300{^{\circ}C}$, while the achieved TMR ratio of the MTJ fabricated with usual Ar-$0_2$ plasma remained 48.4%. A faster oxidization rate of the Al layer by using Kr-O$_2$ plasma is a possible cause to prevent the over oxidization of Al layer and to realize a large magnetoresistance.

[논문 철회] 친환경 레져선박에 적용되는 Al 5083 합금의 인장특성 및 열응력에 미치는 용접조건의 영향 ([Retracted] The Effect of Welding Conditions on Tensile Characteristics and Thermal Stress of Al 5083 Alloy Applied to Co-environmental Leisure Ships)

  • 문병영;이기열;김규선
    • 대한조선학회논문집
    • /
    • 제51권6호
    • /
    • pp.548-555
    • /
    • 2014
  • As a considerable, experimental approach, an Auto-carriage type of $CO_2$ welding machine and a MIG(Metal Inert Gas) welding robot under inert gas atmosphere were utilized in order to realize Al 5083 welding applied to hull and relevant components of green Al leisure ships. This study aims at investigating the effect of welding conditions(current, voltage, welding speed, etc) on thermal deformation that occurs as welding operation and tensile characteristics after welding, by using Al 5083, non-ferrous material, applied to manufacturing of co-environmental Al leisure ships. With respect to welding condition to minimize the thermal deformation, 150A and 16V at the wire-feed rate of 6mm/sec were acquired in the process of welding Al 5083 through an auto carriage type of $CO_2$ welding feeder. As to tensile characteristics of Al 5083 welding through a MIG welding robot, most of tensile specimens showed the fracture behavior on HAZ(Heat Affected Zone) located at the area joined with weld metal, except for some cases. Especially, for the case of the Al specimen with 5mm thickness, 284.62MPa of tensile strength and 11.41% of elongation were obtained as an actual allowable tensile stress-strain value. Mostly, after acquiring the optimum welding condition, the relevant welding data and technical requirements might be provided for actual welding operation site and welding procedure specification(WPS).

Dry Etching Characteristics of Zinc Oxide Thin Films in Cl2-Based Plasma

  • Woo, Jong-Chang;Ha, Tae-Kyung;Li, Chen;Kim, Seung-Han;Park, Jung-Soo;Heo, Kyung-Mu;Kim, Chang-Il
    • Transactions on Electrical and Electronic Materials
    • /
    • 제12권2호
    • /
    • pp.60-63
    • /
    • 2011
  • We investigated the etching characteristics of zinc oxide (ZnO) and the effect of additive gases in a $Cl_2$-based inductively coupled plasma. The inert gases were argon, nitrogen, and helium. The maximum etch rates were 44.3, 39.9, and 37.9 nm/min for $Cl_2$(75%)/Ar(25%), $Cl_2$(50%)/$N_2$(50%), and $Cl_2$(75%)/He(25%) gas mixtures, 600 W radiofrequency power, 150 W bias power, and 2 Pa process pressure. We obtained the maximum etch rate by a combination of chemical reaction and physical bombardment. A volatile compound of Zn-Cl. achieved the chemical reaction on the surface of the ZnO thin films. The physical etching was performed by inert gas ion bombardment that broke the Zn-O bonds. The highly oriented (002) peak was determined on samples, and the (013) peak of $Zn_2SiO_4$ was observed in the ZnO thin film sample based on x-ray diffraction spectroscopy patterns. In addition, the sample of $Cl_2$/He chemistry showed a high full-width at half-maximum value. The root-mean-square roughness of ZnO thin films decreased to 1.33 nm from 5.88 nm at $Cl_2$(50%)/$N_2$(50%) plasma chemistry.

수소분석기 개조 및 조사후 지르칼로이 피복관의 총수소분석 (Modification of Hydrogen Determinator for Total Hydrogen Analysis in Irradiated Zircaloy Cladding Tube)

  • 박순달;최광순;김종구;조기수;김원호
    • 분석과학
    • /
    • 제12권6호
    • /
    • pp.490-497
    • /
    • 1999
  • 불활성기체용융-열전도도 측정법의 수소분석기를 개조하여 글로브박스에 설치했으며 조사핵연료피복관의 수소분석에 사용했다. Zr과 Ti 매질의 수소표준물질로 용융조제인 주석을 사용하지 않고도 수소함량 $3{\mu}g$까지 분석가능하였다. 시료의 크기가 작을수록 수소 회수율이 높았으며 지르칼로이 시료의 수소분석시 Ti 매질의 표준물질을 사용할 수 있음을 확인하였다. 수소분석에 사용한 실제 조사핵연료피복관의 평균 방사능은 10 mR/hr였으며 평균수소농도는 130 ppm이었다.

  • PDF

Application of Pulsed Chemical Vapor Deposited Tungsten Thin Film as a Nucleation Layer for Ultrahigh Aspect Ratio Tungsten-Plug Fill Process

  • Jang, Byeonghyeon;Kim, Soo-Hyun
    • 한국재료학회지
    • /
    • 제26권9호
    • /
    • pp.486-492
    • /
    • 2016
  • Tungsten (W) thin film was deposited at $400^{\circ}C$ using pulsed chemical vapor deposition (pulsed CVD); film was then evaluated as a nucleation layer for W-plug deposition at the contact, with an ultrahigh aspect ratio of about 14~15 (top opening diameter: 240~250 nm, bottom diameter: 98~100 nm) for dynamic random access memory. The deposition stage of pulsed CVD has four steps resulting in one deposition cycle: (1) Reaction of $WF_6$ with $SiH_4$. (2) Inert gas purge. (3) $SiH_4$ exposure without $WF_6$ supply. (4) Inert gas purge while conventional CVD consists of the continuous reaction of $WF_6$ and $SiH_4$. The pulsed CVD-W film showed better conformality at contacts compared to that of conventional CVD-W nucleation layer. It was found that resistivities of films deposited by pulsed CVD were closely related with the phases formed and with the microstructure, as characterized by the grain size. A lower contact resistance was obtained by using pulsed CVD-W film as a nucleation layer compared to that of the conventional CVD-W nucleation layer, even though the former has a higher resistivity (${\sim}100{\mu}{\Omega}-cm$) than that of the latter (${\sim}25{\mu}{\Omega}-cm$). The plan-view scanning electron microscopy images after focused ion beam milling showed that the lower contact resistance of the pulsed CVD-W based W-plug fill scheme was mainly due to its better plug filling capability.

급속응고한 Al-Mg 합금의 미세조직 및 인장특성에 미치는 첨가원소의 영향 (Effects of Alloying Elements on the Microstructure and Tensile Properties of Rapidly Solidified Al-Mg Alloys)

  • 박현호;박종성;김명호
    • 한국주조공학회지
    • /
    • 제17권4호
    • /
    • pp.356-364
    • /
    • 1997
  • In order to study effects of Cu and Be on the microstructure and tensile properties of rapidly solidified Al-Mg alloys, Al-Mg-Cu-Be alloys have been rapidly solidified by inert gas atomization process. Microstructure of rapidly solidified Al-Mg-Cu-Be powders exhibited refinement and good dispersion of Be particles as increasing of solidification rate. Solidification rate of atomized powders was estimated to be about $5{\times}10^{3{\circ}}C/s$. Inert gas atomized Al-Mg-Cu-Be powders were hot-processed by vacuum hot pressing at $450^{\circ}C$ under 100 MPa and hot extruded with reduction ratio in area of 25: 1 at $450^{\circ}C$. The extruded Al-Mg-Cu-Be powders consisted of recrystallized fine Al grains and homogeneously dispersed fine Be particles, and exhibited improved tensile properties with increase in Cu content. $Al_2CuMg$ compounds precipitated in grain and grain boundaries of Al-Mg-Cu-Be alloys with aging heat treatment after solution treatment. Hardness and tensile properties were improved by increasing Cu content and Be addition. Compared with extruded Al-Mg-Cu powders, the extruded Al-Mg-Cu-Be powders exhibited finer recrystallized grains and improved tensile properties by dispersion hardening of Be and subgrain boundaries pinned by fine Be particles. After aging treatment, hardness and tensile properties were improved due to restricted precipitation by increasing of dislocation density around Be particles in matrix.

  • PDF

오피스텔 모델건물의 생애주기비용 분석에 의한 다층유리창 경제성 비교 (Comparison on the Economical Efficiency of the Multiple Glazed Windows According to Life Cycle Costing of an Officetel Model Building)

  • 정근주
    • 한국주거학회논문집
    • /
    • 제17권4호
    • /
    • pp.101-109
    • /
    • 2006
  • The purpose of this study was to suggest ways on reducing the cooling and heating energy cost of the officetel building with the multiple glazing windows according to Life Cycle Costing. This study consisted of an hour-by hour energy simulation program and further data from the EnergyPlus V1-2-2 to the four pane type windows that were applied with 2 low-e polyester film and krypton gas to the officetel model building. It was determined that the four panes type windows that had 2 low-e polyester film and krypton gas applied to, them showed a cooling and heating cost reduction over traditional double glazed windows that were filled with air. According to this study, as well as the information from chart 4.5 and the LCC it was determined that the present value of the four panes of windows that had 2 low-e polyester film and krypton gas applied to them showed. a 11.4% reduction in heating and cooling in comparison to the traditional double glazed windows that were filled with air.

고온 불활성 기체 분위기에서 아산화질소 열분해 및 반응속도에 관한 연구 (A Study of Nitrous Oxide Thermal Decomposition and Reaction Rate in High Temperature Inert Gas)

  • 이한민;윤재근;홍정구
    • 한국분무공학회지
    • /
    • 제25권3호
    • /
    • pp.132-138
    • /
    • 2020
  • N2O is hazardous atmosphere pollution matter which can damage the ozone layer and cause green house effect. There are many other nitrogen oxide emission control but N2O has no its particular method. Preventing further environmental pollution and global warming, it is essential to control N2O emission from industrial machines. In this study, the thermal decomposition experiment of N2O gas mixture is conducted by using cylindrical reactor to figure out N2O reduction and NO formation. And CHEMKIN calculation is conducted to figure out reaction rate and mechanism. Residence time of the N2O gas in the reactor is set as experimental variable to imitate real SNCR system. As a result, most of the nitrogen components are converted into N2. Reaction rate of the N2O gas decreases with N2O emitted concentration. At 800℃ and 900℃, N2O reduction variance and NO concentration are increased with residence time and temperature. However, at 1000℃, N2O reduction variance and NO concentration are deceased in 40s due to forward reaction rate diminished and reverse reaction rate appeared.

정적 예혼합 프로판 화염의 매연생성에 미치는 난류연소 영향에 관한 연구 (A Study on the Effect of Turbulent Combustion upon Soot Formation in Premixed Constant-Volume Propane Flames)

  • 배명환;안수환
    • Journal of Advanced Marine Engineering and Technology
    • /
    • 제27권7호
    • /
    • pp.889-898
    • /
    • 2003
  • The soot yield is studied by a premixed propane-oxygen-inert gas combustion in a specially designed disk-type constant-volume combustion chamber to investigate the effect of turbulence on soot formation. Premixtures are simultaneously ignited by eight spark plugs located on the circumference of chamber at 45 degree intervals in order to observe the soot formation under high pressures and high temperatures. The eight flames converged compress the end gases to a high pressure. The laser schlieren and direct flame photographs for observation field with 10 mm in diameter are taken to examine into the behaviors of flame front and gas flow in laminar and turbulent combustion. The soot volume fraction in the chamber center during the final stage of combustion at the highest pressure is measured by the in situ laser extinction technique and simultaneously the corresponding burnt gas temperature by the two-color pyrometry method. It is found that the soot yield of turbulent combustion decreases in comparison with that of laminar combustion because the burnt gas temperature increases with the drop of heat loss.