• Title/Summary/Keyword: Industrial synthesis

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The Effects of binary metal oxide catalysts for the synthesis of glycerol carbonate (이원계 금속산화물 촉매가 글리세롤카보네이트 합성에 미치는 영향)

  • Baek, Jae-Ho;Moon, Myung-Jun;Lee, Man-Sig
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.1
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    • pp.456-461
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    • 2012

  • The glycerol carbonate was synthesized by glycerol and urea using metal oxide catalysts. The physical properties of the prepared metal oxide catalysts were investigated by X-ray diffraction (XRD), specific surface area analysis (BET), field emission scanning electron microscopy (FE-SEM) and temperature programmed desorption (TPD). In addition, we confirmed the conversion of the glycerol and the yield of the glycerol carbonate according to characteristics of metal oxide catalysts. From XRD and FE-SEM analysis, the crystallite size and crystallinity of metal oxide catalysts decrease with addition of Al. In addition, the Zn-Al mixed metal oxide had higher catalytic activity than the pure ZnO due to decreased side reaction in the synthesis of glycerol carbonate.

  • https://doi.org/10.5762/KAIS.2012.13.1.456 인용 PDF KSCI

Synthesis and Characterization of CdSe Quantum Dot with Injection Temperature and Reaction Time (Injection 온도 및 합성시간에 따른 CdSe 양자점 합성 및 특성)

  • Eom, Nu-Si-A;Kim, Taek-Soo;Choa, Yong-Ho;Kim, Bum-Sung
    • Korean Journal of Materials Research
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    • v.22 no.3
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    • pp.140-144
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    • 2012

  • Compared with bulk material, quantum dots have received increasing attention due to their fascinating physical properties, including optical and electronic properties, which are due to the quantum confinement effect. Especially, Luminescent CdSe quantum dots have been highly investigated due to their tunable size-dependent photoluminescence across the visible spectrum. They are of great interest for technical applications such as light-emitting devices, lasers, and fluorescent labels. In particular, quantum dot-based light-emitting diodes emit high luminance. Quantum dots have very high luminescence properties because of their absorption coefficient and quantum efficiency, which are higher than those of typical dyes. CdSe quantum dots were synthesized as a function of the synthesis time and synthesis temperature. The photoluminescence properties were found strongly to depend on the reaction time and the temperature due to the core size changing. It was also observed that the photoluminescence intensity is decreased with the synthesis time due to the temperature dependence of the band gap. The wavelength of the synthesized quantum dots was about 550-700 nm and the intensity of the photoluminescence increased about 22~70%. After the CdSe quantum dots were synthesized, the particles were found to have grown until reaching a saturated concentration as time increased. Red shift occurred because of the particle growth. The microstructure and phase developments were measured by transmission electron microscopy (TEM) and X-ray diffractometry (XRD), respectively.

  • https://doi.org/10.3740/MRSK.2012.22.3.140 인용 PDF KSCI