• Title/Summary/Keyword: Industrial chemical

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Synthesis of Long Chain Alkyl Urocanate and Solubilization in Organic Solvent (긴사슬 알킬 우로칸에스테르의 합성 및 유기물질에서의 가용성)

  • Ro, Y.C.;Jeong, H.K.;Nam, K.D.;Lee, J.H.
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.1
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    • pp.83-91
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    • 1993
  • The syntheses of urocanic acid esters was optimized, starting from p-toluenesulfonic acid salt of this acid and long chain fatty alcohols in the organic solvent and extracting water from it by means of azeotropic Compound. The salts of these urocanic acid esters showed amphoteric properties, but their micellization enhances their rate of hydrolysis leading to the free amine. Nevertheless the long chain gives to the esters themselves an amphoteric character allowing their solubilization in micellar media and in microemulsions the result, yield could enhanced.

Studies on Utilizations of Serpentine [I] Chemical Studies on the Fertilizer of Ignited Serpentine (蛇紋石의 利用에 關한 硏究 [I] 蛇紋石의 化學的 方法에 依한 肥效檢討)

  • Ham, Yong-Mook;Chun, Hai-Soo;Kim, Yong-Bai
    • Journal of the Korean Chemical Society
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    • v.8 no.1
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    • pp.5-8
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    • 1964
  • In order to investigate the availability of serpentines occurring in Korea as fertilizer, the dissolving rates of Magnesia and Silicate contents in 0.5N HCl solution after heat treatment of the serpentines, have been studied. It was found that calcination of the serpentines at $700^{\circC$ for 30 min. was the best condition for utilization of serpentines as fertilizer. The weight decrease on calcining has also been discussed from the chemical point of view.

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Geochemical Investigations of Contaminated River Waters Part II-Chemical Oxygen Demand of River Water and Industrial Waste Water in Seoul (汚濁河川水의 地球化學的인 硏究 (第 II 報) 서울市內 河川水 및 工場排水의 化學的 酸素要求量)

  • Lee, Yong-Keun
    • Journal of the Korean Chemical Society
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    • v.14 no.1
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    • pp.5-12
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    • 1970
  • River water and industrial waste water in Seoul were studied by means of chemical oxygen demand(COD) as an indicator for water pollution, from August 1967 to July 1968. Rivers flowing through residential and industrial areas are badly contaminated and COD of water in Han River increases as it progresses to downstream. Seasonal variation of COD showed that higher value of COD was observed in spring and lower in autumn. It is clear that the seasonal variation of COD is influenced by the precipitation. Close relationship was found between COD and population density. The lowest COD curve obtained by plotting COD values against population density and show that the curve slopes upward. The discontinuation of the curve was shown at the population density of 14,000/km$^2$; an increase in COD was acute over the population density of 14,000/km$^2$.

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Preparation and Electrochemical Characteristics of CNFs/DAAQ Electrode for Energy Storage

  • Kim Hong-Il;Kim Han-Joo;Choi Weon-Kyung;Osaka Testuya;Park Soo-Gil
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.4
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    • pp.171-175
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    • 2005
  • A new type of supercapacitor was constructed by using carbon nanofibers (CNFs) and DAAQ (l,5-diaminoanthraquinone) oligomer. DAAQ was deposited on the carbon nanofibers by chemical polymerization with ammonium peroxodisulfate (($NH_4)_2S_2O_8$) as oxidant in the 0.1 M $H_2SO_4$. Polymerization reaction was carried out with constant sonication. From the analysis, it is clear that surface of carbon nanofibers was quite uniformly coated with DAAQ. The performance characteristics of the supercapacitors have been evaluated using Cyclic Voltammetry. CNFs/DAAQ based composite electrode showed relatively good electrochemical behaviors in acidic electrolyte system. CNFs/DAAQ composite electrode showed relatively good capacitance (7 Ah/kg) compared to conventional capacitors in the range of $-0.4\~0.4$.

A Study on the Size Distribution and Chemical Composition of total Suspended Particulates at Industrial Region (공단지역에서 대기중 총 부유분진의 입자크기 분포와 화학적 성분에 관한 분석과 연구)

  • Park, Heung-Jae;Lee, Seong-Uk;Park, Won-U
    • Journal of Environmental Science International
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    • v.2 no.3
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    • pp.201-206
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    • 1993
  • The concentration of Total Suspended Particulates(T.S.P), size distribution of suspended particulates, and soluble anions of T.S.P in atmosphere of industrial region in Busan were investigated. T.S.P was measured by High-Volume Air Sampler and particle size distribution was measured by Anderson Air Sampler. We analyzed the chemical component of the T.S.P by ion Chromatography and measure4 the shape and size of T.S.P by Scanning Electron Micrography The small size of T.S.P mainly exist in industrial region, but the large size of T.S.P mainly exist in residentail area.

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Progresses in membrane and advanced oxidation processes for water treatment

  • Khulbe, K.C.;Feng, C.Y.;Matsuura, T.;Ismail, A.F.
    • Membrane and Water Treatment
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    • v.3 no.3
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    • pp.181-200
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    • 2012
  • At present water crisis is not an issue of scarcity, but of access. There is a growing recognition of the need for increased access to clean water (drinkable, agricultural, industrial use). An encouraging number of innovative technologies, systems, components, processes are emerging for water-treatment, including new filtration and disinfectant technologies, and removal of organics from water. In the past decade many methods have been developed. The most important membrane-based water technologies include reverse osmosis (RO), ultrafiltration (UF), microfiltration (MF), and nanofiltration. Beside membrane based water-treatment processes, other techniques such as advanced oxidation process (AOP) have also been developed. Some unconventional water treatment technology such as magnetic treatment is also being developed.

COD removal from industrial wastewater plants using reverse osmosis membrane

  • Madaeni, S.S.;Samieirad, S.
    • Membrane and Water Treatment
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    • v.1 no.4
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    • pp.273-282
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    • 2010
  • Treatment and reuse of industrial wastewater is becoming a major goal due to water scarcity. This may be carried out using membrane separation technology in general and reverse osmosis (RO) in particular. In the current study, polyamide (FT-30) membrane was employed for treatment of wastewater obtained from Faraman industrial zone based in Kermanshah (Iran). The effects of operating conditions such as transmembrane pressure, cross flow velocity, temperature and time on water flux and rejection of impurities including COD by the membrane were elucidated. The aim was an improvement in membrane performance. The results indicate that most of the chemical substances are removed from the wastewater. In particular COD removal was increased from 64 to around 100% as temperature increased from 15 to $45^{\circ}C$. The complete COD removal was obtained at transmembrane pressure of 20 bars and cross flow velocity of 1.5 m/s. The treated wastewater may be reused for various applications including makeup water for cooling towers.

Carbon bead-supported copper-dispersed carbon nanofibers: An efficient catalyst for wet air oxidation of industrial wastewater in a recycle flow reactor

  • Yadav, Ashish;Verma, Nishith
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.448-460
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    • 2018
  • Copper nanoparticle-doped and graphitic carbon nanofibers-covered porous carbon beads were used as an efficient catalyst for treating synthetic phenolic water by catalytic wet air oxidation (CWAO) in a packed bed reactor over 10-30 bar and $180-230^{\circ}C$, with air and water flowing co-currently. A mathematical model based on reaction kinetics assuming degradation in both heterogeneous and homogeneous phases was developed to predict reduction in chemical oxygen demand (COD) under a continuous operation with recycle. The catalyst and process also showed complete COD reduction (>99%) without leaching of Cu against a high COD (~120,000 mg/L) containing industrial wastewater.

Industrial Crystallization of Organic Compounds

  • Kim, Kwang-Joo
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.10a
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    • pp.33-38
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    • 1997
  • Fundamentals and industrial applications of crystallization of organic compounds are reviewed. The methods to upgrade organic products in terms of its purity and its morphology are introduced. How crystallization of organics can be useful in producing ultra-pure materials are also described.

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