• Title/Summary/Keyword: Industrial agglomeration

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Effect of Containing Promoter on SCR Catalysts (SCR 촉매에 포함된 조촉매 영향)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.474-481
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    • 2018
  • The policy-making and technological development of eco-friendly automobiles designed to increase their supply is ongoing, but the internal combustion engine still accounts for approximately 95% of automobiles in use. To meet the stricter emission regulations of internal combustion engines based on fossil fuels, the proportion of after-treatments for vehicles and (ocean going) vessels is increasing continuously. As diesel engines have high power and good fuel economy in addition to less CO2 emissions, their market share is increasing not only in commercial vehicles, but also in passenger cars. Because of the characteristics of the diesel combustion, however, NOx is generated in localized high-temperature combustion regions, and particulates are formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for the after-treatment of exhaust gas to reduce NOx in diesel vehicles. This study examined the effect of a containing promoter on SCR catalysts to cope with the severe exhaust gas regulation. The de-NOx performance of the Mn-SCR catalyst was the best, and the de-NOx performance was improved as the ion exchange rate between Mn ion and Zeolyst was good and the activation energy was low. The de-NOx performance of the 7Cu-15Ba/78Zeoyst catalyst was 32% at $200^{\circ}C$ and 30% at $500^{\circ}C$, and showed the highest performance. The NOx storage material of BaO loaded as a promoter was well dispersed in the Cu-SCR catalyst and the additional de-NOx performance of BaO was affected by the reduction reaction of the Cu-SCR catalyst. Among the three catalysts, the 7Cu-15Ba/Zeolyst SCR catalyst was resistant to thermal degradation. The same type of CuO due to thermal degradation migrates and agglomerates because BaO reduces the agglomeration of the main catalyst CuO particles.

A Study on Synthesis and Dispersion of Silver Nano Particle Using Trisodium Citrate (Trisodium Citrate을 이용한 은 나노입자의 합성 및 분산성에 관한 연구)

  • Lee, Jong Jib
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.4
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    • pp.772-779
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    • 2016
  • Silver nanoparticles were prepared by reacting silver nitrate and trisodium citrate in an aqueous solution. Their size and shape were investigated by scanning electron microscopy (SEM). The synthesis was carried with different silver nitrate concentration, addition of TSC, solvent, surfactant, ultrasonication, and dispersing agent. With higher concentration of silver nitrate or TSC, the particles became large or agglomerated. The SEM results showed that the nanoparticles have spherical and pseudospherical shape with a narrow size distribution. The hydrophobic solvent did not affect the dispersibility, but the hydrophilic solvent enhanced it. The addition of HPMC surfactant caused the size to increase (50-100 nm) with non-uniform shapes and partial agglomeration. The dispersibility was significantly improved by ultrasonication for over 3 hours after the addition of a dispersing agent. Complete dispersion was achieved by adding the dispersant, and the nanoparticle sizes were as follows: 30-40 nm (BYK-182) < 42-78 nm (BYK-192) < 51-113 nm (BYK-142). The nanoparticles were 38.45-46.28 nm after the addition of 2-4 wt% TSC in 0.002 M silver nitrate solution.

The Spatial Characteristics on the Mobile Industry's Value Chain in Daegu-Gyeongbuk Region (대구.경북지역 모바일산업의 가치사슬 구조와 공간적 특성)

  • Jeon, Ji Hye;Lee, Chul Woo
    • Journal of the Korean association of regional geographers
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    • v.19 no.1
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    • pp.45-59
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    • 2013
  • This paper was to examine the spatial characteristics on the mobile industry's value chain based on the structure of value chain, the process of development, and the industrial linkages of mobile industry in Daegu-Gyeongbuk region. The mobile industry's value chain in Daegu-Gyeongbuk region consists of the infrastructure, mobile device, platform & embedded SW, and mobile contents sector. Among these sectors, the leading value chain sector in mobile governance is the mobile device sectors, especially the finished products sector. These sectors have developed by policies as well as networks with large enterprises such as Samsung and LG, and it forms a hub-and-spoke cluster. The infrastructure and mobile device sector are located in Gumi, Gyeongbuk, the embedded SW and mobile contents sectors are located in Daegu, which means decentralized agglomeration. The sectors of infrastructure and mobile device form the strong forward-backward linkages with firms in Daegu-Gyeongbuk region. For the embedded SW sector, the forward-backward linkages are active with firms located in Seoul metropolitan area. For mobile contents sector, the backward linkages are formed with firms in Daegu and the forward linkages are formed with firms in Seoul metropolitan area.

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Flexible Specialization: A New Paradigm for Modern Industrial Society ? (柔軟的 專門化(Flexible Specialization) : 현대 産業社會의 새로운 패러다임 ?)

  • Lee, Deog-An
    • Journal of the Korean Geographical Society
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    • v.28 no.2
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    • pp.148-162
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    • 1993
  • There is much speculation that modern capi-talist society is undergoing fundamental and qualitative chnge towards flexible specialization. The purpose of this study is to examine this hypothesis. This paper focusses on: the idea of flexible specialization; the significance of this transition; industrial district; and the implicati-ons of this new production system for Korean industrial space. Main arguments of this study are as follows: First, as all different groups of researchers apply the idea of flexible specialization according to their own specifications, the current debate on this topic is not much fruitful. Not surpri-singly, the concept of flexible specialization has overlapped with subocontracting. This intergration of subcontracting into flexible specialization systems, however, is inappropriate because the two concepts have different historical contexts. The other cause of this controversy is its inherent weekness, conceptual ambiguity. Thus, today's flexibility becomes tomorrow's rigidity. Secondly, transition towards flexible speciali-zation has only been partially achieved even in advanced capitalist countries. The application of dualistic explanatory framework, such as rigidity versus flexibiity, mass production versus small-lot multi-product production, and de-skilling versus re-skilling, has resulted in great exaggeration of the transformation, from Fordism to post-Fordism. There is no intermediary part between two places. Considering that the workers allocated to the Fordist mass production assembly line are not as large as one might imagine, the shift from mass to flexible production has only limited implications for the transformation of capitalist economy. Thirdly, 'industrial district' contorversy has contributed to highlighting the importance of small firms and areas as production space. The agglomeration of small firms in specific areas is common in Korea, but it is quite different from the industrial district based on flexible specialization. The Korean phenomenon stems from close interactions with its major parent firm rather than interactions between flexible, specialized, autonomous and technology-intensive smll firms. Most Korean subcontractors are still low-skilled, labour-intensive, and heavily dependent on their mojor parent firms. Thus, the assertion that the Seoul Metropolitan Area adopts flexible specialization has no base. Fourthly, the main concern of flexible speciali zation is small firms. However, the corporate organization that needs product diversification and technological specialization is oligopolistic large corporations typified by multinational corporations. It is because of this that most of these organizations are adoptiong Fordist mass production methods. The problem of product diversification will be resolved naturally if economic internationalization progresses further. What is more important for business success is the quality and price competitiveness of firms rather than product diversification. Lastly, in order to dispel further misunderst-anding on this issue, it is imparative that the conceptual ambiguity is resolved most urgently. This study recommends adoption of more speci-fied and direct terminology (such as, factory automation, computer design, out-sourcing, the exploitation of part-time labor, job redesign) rather than that of ideological ones (such as, Taylorism, Fordism, neo-Taylorism, neo-Fordism, post-fordism, flexible specialization, peripheral post-Fordism). As the debates on this topic just started, we still have long way to go until consensus is reached.

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Locational Characteristics of Knowledge Service Industry and Related Employment Opportunity Estimation in the Seoul Metropolitan Area (서울대도시권 지식서비스산업의 입지적 특성과 관련 업종별 고용기회 예측)

  • Park, So Hyun;Lee, Keumsook
    • Journal of the Economic Geographical Society of Korea
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    • v.19 no.4
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    • pp.694-711
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    • 2016
  • This study analyzes the spatial characteristics of knowledge industry which has shown relatively rapid growth in the low-growth economy situation in recent years. In particular, we catch hold of the locational characteristics of the knowledge service industry which occupies the highest ratio by professional-expert jobs favoured by young generations, as well as estimate their occupational employment opportunities. By applying Location Quotient(LQ) and LISA, we reveal the spatial distribution patterns of publishing business, information service business and education service business in the Seoul Metropolitan area, and examine the changes in the spatial patterns during the last ten years. In order to understand the socio-economic factors which explain their locations, we apply the stepwise multiple regression analysis. Furthermore, we predict the changes distribution of Knowledge service industrial employment by applying Markov Chain Model. As the result, we found their clusters at the specific locations, while there is the significant variations in the socio-economic variables related their locations respectively. The related job opportunities of the knowledge service businesses in the Seoul Metropolitan area are predicted steady growth trend for the next four years, even though dull or stagnant trend is expected for other industries. This study provides basic resources to the planning for young generation employment problem.

Dispersion Method of Silica Nanopowders for Permalloy Composite Coating (퍼멀로이 합금도금을 위한 나노실리카 분산방법에 관한 연구)

  • Park, So-Yeon;Jung, Myung-Won;Lee, Jae-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.4
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    • pp.39-42
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    • 2011
  • The composite electroplating is accomplished by adding inert materials during the electroplating. Permalloy is the term for Ni-Fe alloy and it is used for industrial applications due to its high magnetic permeability, surface wear resistance, corrosion protection. Microhardness for microdevices is enhanced after composite coating and it increases the life cycle. However, the hydroxyl group on the silica makes their surface susceptible to moisture and it causes the silica nanoparticles to be agglomerated in the aqueous solution. The agglomeration problem causes poor dispersion which eventually interrupts uniform deposition of silica nanoparticles. In this study, the dispersion of silica nanoparticles in the permalloy electroplated layer is reported with variation of additives and current densities. The optimum current density was 20 $mA/cm^2$ and the silica content was 9 at% at $50^{\circ}C$. The amount of silica nanopowder codeposition and surface morphologies were influenced with variation of additives. In the bath, smooth surface morphology and relatively high contents of silica nanopowder codeposition were obtained with addition of sodium lauryl sulfate.

Effects of the Particle Size and Shape of Silver Nanoparticles on Optical and Electrical Characteristics of the Transparent Conductive Film with a Self-assembled Network Structure (은 나노입자의 크기 및 형태가 자가조립 망상구조를 갖는 투명전도성 필름의 광학 및 전기 특성에 미치는 영향)

  • Shin, Yong-Woo;Kim, Kyu-Byung;Noh, Su-Jin;Soh, Soon-Young
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.162-167
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    • 2018
  • The effect of the average particle size and shape of silver nanoparticles for the transparent conductive film (TCF) was studied. Optical and electrical properties of silver conductive lines coated on the polyethylene terephthalate (PET) film was also measured. Silver nanoparticles produced by Ag-CM, Ag-ME, Ag-EE methods showed an excellent conductivity compared to those produced by Ag-EB, Ag-CR and Ag-PL methods, but a little difference in the transparency. In the case of the former three silver nanoparticles, the average particle size was about 80 nm or less and the size was uniform. For the latter case, the severe agglomeration phenomena of particles was observed and the average particle size was 100 nm or more. This result was consistent with the result of the uniformity of the pattern shape and thickness on conductive line patterns observed by SEM. Therefore, it was confirmed that the electrical characteristics could be obtained when the average particle size of silver nanoparticles is smaller and the uniformity of the particles is maintained.

Preparation and Physical Properties of Eco-Friendly Biodegradable PLA/PBAT/HCO Blended Films (친환경 생분해성 PLA/PBAT/HCO 블랜드 필름 제조 및 물리적 특성)

  • Lee, Seung-Min;Kim, Han-Seong;Yun, Yeon-Hum;Hyung, Tae-Gyung;Yoon, Soon-Do
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.416-422
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    • 2020
  • In this study, eco-friendly biodegradable materials were prepared using poly(lactic acid) (PLA), poly(butylene adipate-co-terephthalate) (PBAT), and hydrogenated castor oil power (HCO) as an additive. The prepared PLA/PBAT/HCO blended films were characterized by the scanning electron microscope (SEM) and fourier-transform infrared spectroscopy (FT-IR). The results of SEM analysis indicated that PLA/PBAT (8 : 2) blended films added HCO showed no rough area, crack, or large agglomeration when compared with those adding various additives (12-hydroxy stearic acid (12HSA) and cellulose). The FT-IR results indicated the presence of specific peak of HCO in the PLA/PBAT blended films, and its peak intensity increased with increasing HCO content (0~5.0 wt%). Tensile strength, elongation at break, and water barrier and thermal properties of the prepared PLA/PBAT/HCO blended films were also investigated, indicating that the physical and thermal properties was improved more than three times by the addition of HCO. The biodegradability test in soil revealed that the prepared biodegradable materials were degraded by about 6.0~20% after 90 days.

Improvement in the Dispersion Stability of Iron Oxide (Magnetite, Fe3O4) Particles with Polymer Dispersant Inject (고분자 분산제 주입을 통한 철산화물(Magnetite, Fe3O4) 입자의 분산 안정성 향상)

  • Song, Geun Dong;Kim, Mun Hwan;Lee, Yong Taek;Maeng, Wan Young
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.656-662
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    • 2013
  • The iron oxide ($Fe_3O_4$) particles in the coolant of the secondary system of a nuclear power plant reduce the heat transfer performance or induce corrosion on the surface of the heat transfer tube. To prevent these problems, we conducted a study to improve the dispersion stability of iron oxide using polymeric dispersant injection in simulated secondary system water. The three kinds of anionic polymers containing carboxyl groups were selected. The dispersion characteristics of the iron oxide particles with the polymeric dispersants were evaluated by performing a settling test and measuring the transmission, the zeta potential, and the hydrodynamic particle size of the colloid solutions. Polymeric dispersants had a significant impact on the iron oxide dispersion stability in an aqueous solution. While the dispersant injection tended to improve the dispersion stability, the dispersion stability of iron oxide did not increase linearly with an increase in the dispersant concentration. This non-linearity is due to the agglomerations between the iron oxide particles above a critical dispersant concentration. The effect of the dispersant on the dispersion stability improvement was significant when the dispersant concentration ratio (ppm, dispersant/magnetite) was in the range of 0.1 to 0.01. This suggests that the optimization of dispersant concentration is required to maximize the iron oxide removal effect with the dispersant injection considering the applied environments, the iron oxide concentration and the concentration ratio of dispersant to iron oxide.

Financing and Knowledge Accumulation in the Film Industry: Spatial Characteristics of Korean and American Film Industry (영화산업의 자본조달구조와 지식축적과정에 대한 공간적 고찰: 한국과 미국 영화산업의 비교를 통하여)

  • Chung, SunWha
    • Journal of the Economic Geographical Society of Korea
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    • v.20 no.4
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    • pp.453-485
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    • 2017
  • One of the oldest chestnuts in economic geography is this: Cultural and creative industries strongly gather in large cities and this geographic concentration of economic activities leads to regional development. Of course, depending on the circumstances, such a proposition still holds good. But, under the current paradigm shift to knowledge-based economy, it may be open to question. This study aims to investigate financing and knowledge accumulation in the film industry through an alternative framework for explaining their spatial distributions, "formation mechanism of economic space." From the fact that their production organizations are formed on a project basis, project-based financing structure in the investment stage and knowledge accumulation process in the production stage form both axes of it. Film industry as the most mature industry among the cultural and creative industries does not always concentrate in a certain place (industrial agglomeration) or show metropolis-oriented preference. This allows us to reconsider our long brooding theory.