Paper sludge Ash (PA) and Fly Ash (FA) wastes are usually land-filled for reclamation or substituted for cements as a resource. It could also offer some advantages when they are substituted for clay to preserve the environment. To recycle those wastes, the sintered specimen made of PA-FA-Clay system were examined to find the microstructure and physical properties. The ratio of clay to wastes was fixed as 30:70 by wt%, while PA to FA within waste portion were varied in the range of $1:6{\sim}7:0$. Those specimens were fired in $1150{\sim}1350^{\circ}C$. It was found that the relative density of sintered specimen was increased with amount of PA added at low sintering temperature (i.e, $1150{\sim}1200^{\circ}C$). This is due to increased amount of liquid during sintering. It is shown, however that at high sintering temperature ($1250{\sim}1350^{\circ}C$), the relative density of specimens was decreased with amount of PA added. This is because of overfiring phenomenon which may be able to induce an inhomogeneous microstructure and increased porosity. The mechanical properties of sintered specimen were depended upon the homogeneity of microstructure in accordance with SEM (Scanning Electron Microscopy) and pore size distribution analysis. For example, the compressive strength of 10PA-60FA-30Clay specimen sintered at $1225^{\circ}C$ was twice higher than that of 70PA-30Clay specimen even thought the relative density of those specimen was similar. This decreased strength of 70PA-30Clay specimen appears to be an inhomogeneity of microstructure due to overfiring.
Kim, Joung-Dae;Park, Joon-Seok;Do, In-Hwan;Hong, Soo-Youl;Oh, Gil-Jong;Chung, David;Yoon, Jung-In;Phae, Chae-Gun
Journal of Korean Society of Environmental Engineers
/
v.30
no.11
/
pp.1102-1110
/
2008
This research was performed to analyze the characteristics of wood wastes from origin and to suggest grade-classification for them. Korean proximate analysis was conducted, and heating value, heavy metals and Cl concentrations were analyzed for gradeclassification. Wood wastes were sampled from forest, living, construction and demolition, and industrial areas with origin. Moisture content of most wood wastes was ranged in 5$\sim$10%. VS (volatile solids) and ash contents of them showed > 95% and < 5%, respectively. Most wood wastes except wood for growing mushroom permitted the standard (low heating value $\geq$ 3,500 kcal/kg) for refusederived fuel. CCA (Cr, Cu, As) concentration of wood wastes used in bench, wasted fishing boat, and railroad crosstie was higher than that of the other ones. Cl content showed approximately 1.3% in wood box for fish and $\leq$ 0.2% in the other wood wastes. Cl content of all wood wasted used in this research permitted the standard (Cl $\leq$ 0.2%, dry weight basis) for refuse-derived fuel. If the wood wastes were classified in 3-grade, plywoods would be in 2nd grade, and MDF (medium density fiber), wooden bench, painted electric wire drum, wasted fishing boat, and railroad crosstie be in 3rd grade.
Journal of the Korea Organic Resources Recycling Association
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v.11
no.2
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pp.66-73
/
2003
To investigate the availability of solidified wastes as resource, wastewater sludge, waste gypsum and fly ash were mixed and the results with various mixing ratios are as follows. Compressive strength turned out to be increasing as the amount of waste gypsum increases, keeps longer curing inhibition, and higher forming Pressure under the conditions of waste gypsum/sludge ratio 0.31-0.45, and 0.9kg cement as 15% and 1.2kg cement as 20% of total amount. Solidified agent under the fly ash/sludge ratio 0.45, 0.6, compressive strength seemed to be higher than standard one which means solidified wastes with these conditions could be applicable in real life. These results inform that concentrations of the leachate $Cr^{+6}$, Cu, Zn, Cd, Pb solidified matrix, containing low concentration of heavy metal, were cured with/without enough time it still will cause adverse effect on nature environment and application of heavy metal sequester must be needed to reuse industrial wastes from incineration plant solidified matrix. Total cost price, when considering manufacturing capability of the facilities for resourcerizing as 18,000ton was presented 678,664,000 won, as it were, manufacturing cost price was 37,704 won per ton. The results as above has shown that it's possible to use the mixture of waste gypsum/sludge, fly ash/sludge, cement, additions, and solidification matter as substitute of materials like brick, block, interlocking which has proper compressive strength of KS L 5201 and KS F 4004.
As a result of population growth and economic growth, household and industrial wastes continue to rapidly increase every year. Especially, sewage sludge produced at final stage is increasing with the constant construction and putting in good order of the sewage plant. In addition to the government's prohibition for filling up the sludge, it became more and more difficult to discharge wastes to the sea as London Dumping Convention '96 came into effect. And sewage sludge and the livestock wastes are expected to be thoroughly prohibited from discharging to the sea from 2012. So we need desperately economical and useful alternatives to compact and reuse these wastes. The purpose of this study is to evaluate the utilization of solidified sludge-soil mixture as an enhancement and covering material. To determine the proper mixed ratio of solidified sludge, this study conducted basic physical properties tests, compaction tests, uniaxial compression tests, and permeability test. It was found that the higher the ratio of solidified sludge, the lower the coefficient of permeability. Upon the results of particle size distribution, the mixed ratio of solidified sludge that meet the enhancement material condition was 59% or lower for SP granite soil and 48% or lower for SM granite soil respectively.
Journal of the Korea Academia-Industrial cooperation Society
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v.10
no.7
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pp.1654-1660
/
2009
Two different cutting-oils from H and B companies which are sold as an eco-friendly cutting-oils were selected and the biodegradability of these commercially available cutting-oils was evaluated by the sequencing batch reactor (SBR) processes. The cutting-oil wastes ($H_1$) pre-treated by coagulation/flocculation was used as an influent to SBR. When the F/M ratio was operated 0.04 to 0.08kgCOD/kgMLSS d, removals of $BOD_5$and $COD_{Cr}$were above 97% and 91%, respectively. T-N and T-P removals were above 76% and 81%, respectively. If the diluted cutting-oil wastes ($B_1$) was used as an influent of the SBR, $COD_{Cr}$removals were above 77% at the F/M ratio of 0.01-0.02kgCOD/kgMLSS d. After the cutting-oil wastes was treated by coagulation/ flocculation ($B_2$), $COD_{Cr}$removals was above 85%. If the pre-treated cutting-oil wastes were mixed with a synthetic wastewater ($B_3$) and fed into the SBR in order to mimic the real wastewater treatment plant situation, $BOD_5$and $COD_{Cr}$removals were above 97%, 91%, respectively. T-N and T-P removals were above 79% and 76%. The ratio between $BOD_5$and $COD_{Cr}$, ($COD_{Cr}$-$BOD_5$)/$COD_{Cr}$, indicating the biodegradability of effluent of the SBR, was calculated to 85% and 61%. This means that significant amounts of non-readily-biodegradable organic compounds in the effluent of $H_1$, $B_3$are still present.
Journal of the Korean Professional Engineers Association
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v.15
no.1
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pp.46-50
/
1982
Following rapid industrial development and urbanization in Korea, there is a need for the Government to implement effective control of pollution and to undertake specific schemes in areas where pollution of the environment is severe. In response to this need, Government of Korea prepare Han River Basin Environmental Master Plan Project for water, air, solid waste to cover environmental protection of the Han River Basin. The Project area is approximately 27,000 sq. Km extending over Seoul, Kyunggi, Kwangwon, Chungbuk Province. The total population of Master Plan Project area is approximately 11.6 million, or one-third of the total population of Korea. There are about 8,000 industries, including those located in 16 industrial complexes, in the project area. The scope of work and terms of reference are the following: (1) A Summary of existing land use and forecasts for changes in land use by the year 2,000. (2) Emission inventories for air, waste water, and solid wastes. (3) Forecasts of future population growth patterns and pollution loadings. (4) Identification of specific projects needs to reduce pollution levels and satisfy the environmental quality standards. (5) A Program of enforcement to include (i) self monitoring, and (ii) governmental inspections and surveillance. (6) A program for quality improvement and quality assurance of environmental measurements. (7) Reports summarizing all data collected analyzed during the study. (8) Conceptual design and feasibility studies, including cost estimates, for needed pollution control projects. (9) A financial plan for future detailed design and construction of public facilities, for financial incentives to industry, and for user charges for industrial use of public treatment of disposal works.
As the industry develops, the amount of wastes is increasing in the economic system with various needs. As a result, the environmental problems are emerging as serious social issues and all the parties are required to make their best efforts. Among the issues proposed as the environmental issues, the logistics-related issues are exhaustion of the resources, global warming, environmental pollution, and acidification and so on. In order to respond to the environmental issues of the earth, the advanced countries are setting retrenched goals, reduction of the new greenhouse gases and accomplishment of retrenched goals by cooperation between the nations. Economic activities inevitably bring environmental problems and logistics is implementing those activities. The companies should perform the roles to resolve the environmental problems as the main cause of environmental pollution. Therefore, along with spreading recognition of social demand, the companies are required to establish policies regarding the environment and they should approach the issues from the perspective of resource circulation. These environment-friendly activities are emerging as the new source of competitiveness in the logistics field. Therefore, this study analyzes the effects of environment-friendly logistics activities on the reduction of logistics cost to reduce and resolve the environmental issues such as environment preservation, recycling and so on.
Gastrointestinal tract of ruminants as well as monogastric animals are colonised by a variety of microorganisms including bacteria, fungi and protozoa. Gastrointestinal ecosystem, especially the rumen is emerging as an important source for enrichment and natural selection of microbes adapted to specific conditions. It represents a virtually untapped source of novel products (e.g. enzymes, antibiotics, bacteriocins, detoxificants and aromatic compounds) for industrial and therapeutic applications. Several gastrointestinal bacteria and fungi implicated in detoxification of anti-nutritional factors (ANFs) can be modified and manipulated into promising system for detoxifying feed stuffs and enhancing fibre fermentation both naturally by adaptation or through genetic engineering techniques. Intestinal lactobacilli, bifidobacteria and butyrivibrios are being thoroughly investigated and widely recommended as probiotics. Restriction endonucleases and native plasmids, as stable vectors and efficient DNA delivery systems of ruminal and intestinal bacteria, are increasingly recognised as promising tools for genetic manipulation and development of industrially useful recombinant microbes. Enzymes can improve the nutrient availability from feed stuffs, lower feed costs and reduce release of wastes into the environment. Characterization of genes encoding a variety of commercially important enzymes such as cellulases, xylanases, $\beta$-glucanases, pectinases, amylases and phytases will foster the development of more efficacious and viable enzyme supplements and enzyme expression systems for enhancing livestock production.
Junior, Mario Roberto Marostica;Mota, Natasha Onoyama;Baudet, Nathalie;Pastore, Glaucia Maria
Food Science and Biotechnology
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v.16
no.1
/
pp.37-42
/
2007
The biotransformation of monoterpenic agro-industrial wastes (turpentine oil and essential orange oil) was studied. More than 40 fungal strains were isolated from Brazilian tropical fruits and eucalyptus trees and screened for biotransformation of the waste substrates. Solid phase microextraction was used to monitor the presence of volatile compounds in the headspaces of sporulated surface cultures. The selected strains were submitted to submerged liquid culture. The biotransformation of R-(+)-limonene and ${\alpha},\;{\beta}-$ pinenes from the oils resulted in ${\alpha}-terpineol$ and perillyl alcohol, and verbenol and verbenone, respectively, as the main products. The selected strains were also placed in contact with ${\alpha}-$ and ${\beta}-$ pinenes standards. It was confirmed that verbenol, verbenone, and ${\alpha}-terpineol$ were biotransformation products from the terpenes. A concentration of 90 mg/L of verbenone was achieved by Penicillium sp. 2360 after 3 days of biotransformation.
A unique brick series based on Vietnamese clay was manufactured at 114.22 MPa pressure rate for γ-ray attenuation purposes, consisting of (x) metallic waste & (90%-x) red clay mineral & 10% (hardener mixed with epoxy resin), where (x) is equal to the values 0%, 20%, 40%, 50%, and 70%. The impacts of industrial metal waste ratio in the structure and radiation protective characteristics were evaluated experimentally. The increase in metallic waste doping concentrations from 0% to 70% was associated with an increase in the manufactured brick's density (ρ) from 2.103 to 2.256 g/cm3 while the fabricated samples' porosity (Φ) decreased from 11.7 to 1.0%, respectively. Together with a rise in fabricated brick's density and a decrease in their porosities, the manufactured bricks' γ-ray attenuation capacities improved. The measured linear attenuation coefficient (μ, cm-1) was improved by 30.8%, 22.1%, 21.6%, and 19.7%, at Eγ equal to the values respectively 0.662, 1.173, 1.252, and 1.332 MeV, when the metallic waste concentration increased from 0% to 70%, respectively. The study demonstrates that manufactured bricks exhibit superior radiation shielding properties, with radiation protection efficiencies of 88.4%, 90.0%, 91.7%, 92.1%, and 92.4% for bricks with industrial metal waste contents of 0%, 20%, 40%, 50%, and 70%, respectively, at γ-ray energy (Eγ) of 1.332 MeV.
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