• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2000년도 춘계학술발표대회
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• pp.335-338
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• 2000

To separate BTX degrading microorganisms, four kinds of activated sludges were obtained from waste water treatment plants and VOC generating plants, and adjusted 500 mg/L of BTX for three months. Y consortia degraded benzene and toluene in either individual or mixed compounds fast whereas A consortia degraded p-, m-, o-xylene fast.

• Journal of Korean Society for Atmospheric Environment
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• 제23권1호
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• pp.39-49
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• 2007

In this study, the performance characteristics of solid phase microextraction (SPME) were investigated for three major odorous groups that consist of 10 individual compounds ([1] volatile organic compounds (VOC): benzene, toluene, p-xylene and styrene, [2] reduced sulfur compounds (RSC): hydrogen sulfide, methyl mercaptan, dimethylsulfide (DMS), dimethyldisulfide (DMDS), and carbon disulfide, and [3] amine: trimethylamine (TMA)). For the purpose of a comparative analysis, two types of SPME fiber ([1] polidimethylsiloxane/divinilbenzene (P/D) and [2] $Carboxen^{TM}$/polidimethylsiloxane (C/P)) were test ε d against each other for a series of standards prepared at different concentration levels (100, 200, and 500 ppb). To compare the analytical performance of each fiber, all standards were analyzed for the acquisition of calibration data sets for each compound. The results of P/D fiber generally showed that its calibration slope increased as a function of molecular weight across different VOCs; however, those of C/P fiber showed a fairly reversed trend. Besides, we confirmed that the application of SPME is limited to many sulfur compounds; only two compounds (DMS and DMDS) are sensitive enough to draw calibration results out of SPME. The calibration data for RSC show generally enhanced slop values for C/P relative to P/D fiber. However, in the case of TMA, we were not able to find a notable difference in their performance.

• Journal of Environmental Science International
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• 제15권11호
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• pp.1011-1016
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• 2006

Recently, volatile organic compound(VOC) has been noted as a main cause of air pollution. VOC, with its toxic and offensive odor, is hazardous to health. Furthermore indoor, underground and hish-rise buildings are preferable living spaces. People spend more than 80% of the day indoor, so indoor air pollution is a matter of importance. In Korea, from 2004, 10 types of indoor pollutants in public facilities have been identified. However, there is no standard for individual VOC, so the regulation has not yet effectively been carried out. In this study, we have studied on the diffusion of Benzene in a room using a numerical analysis for various air-controlled conditions consisted of door, window and ventilation system. This study investigates spatial concentration distribution and time-history of room-averaged benzene concentration for several cases. The results of this study show that when the room is ventilated by a small fan only for 30 minutes, the average concentration of benzene is decreased a very little, thus the impact to human body would be serious compared to the case of natural ventilation by window and door, In the case of natural ventilation by window and door, if the wind speed is higher than 0.5m/s, it takes small than 4 minutes for benzene to spread to the target concentration of $1.2mg/m^3$.

• KSCE Journal of Civil and Environmental Engineering Research
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• 제26권6B호
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• pp.695-701
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• 2006

A toluene-degrading bacterial strain was isolated from a mixed culture that was maintained using toluene as a sole carbon and energy source. The isolated bacterium was classified as Pseudomonas sp. TBD4 based on the close relationship to bacteria belonging to this genus. A bottle study to determine biodegradation rates of individual aromatic compounds showed that the biodegradation was faster in the order of toluene, benzene, styrene, and p-xylene. However, when various mixtures were subjected to TDB4, styrene was degraded at the highest rate, indicating that both toluene and p-xylene could stimulate the degradation of other substrates whereas styrene played as an inhibitor. In addition, the mixed culture and TDB4 were inoculated to the bioactive foam reactor (BFR), and the reactor performance and the corresponding change of microbial community were monitored using the fluorescent in situ hybridization (FISH) method. When an inlet concentration of the VOC mixture increased to greater than 250 ppm, the overall removal efficiency dropped significantly. The FISH measurement demonstrated that the ratio of TDB4 to the total bacteria also decreased to less than 20% along with the decline in removal efficiency in the BFR. As a result, the periodic addition of the pre-grown TDB4 might have been beneficial to achieve a stable performance in the BFR operated over an extended period.

• Journal of Korean Society for Atmospheric Environment
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• 제23권1호
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• pp.110-124
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• 2007

In this study, the control efficiency of odorous compounds was measured from diverse control process units of 14 individual companies located within the Ban-Wall industrial complex of Ansan city, Korea (January to July 2005), To quantify the control efficiency levels of major odorous compounds, we collected odor samples from both the front and rear side of 17 control process units ($N=17{\times}2=34$). If the control efficiency is compared for each of 32 compounds between different process units, wet scrubber (WS) was found to be the most effective unit in terms of the sum of pollutants showing the positive control signals. Although the WS system shows generally a good control pattern for VOC, it is not the case for most index odorous pollutants; only 3 out of 12 index compounds were found to show positive control efficiencies. The results of the study also indicated that the control efficiency differ greatly between different industrial sectors and/or control process types. In the case of leather industry, carbonyl compounds were found to exhibit the highest control efficiency with its values varying from 19 to 90%. On the other hand, in the case of metal production sector, VOC recorded the maximum control efficiency with values varying from 18 to 79%. According to this study, most air pollution control facilities operated in most companies show fairly poor control efficiencies for most malodor compounds. Hence, to obtain best control efficiency of odorous pollutant emission, acquisition of better information on source characteristics and establishment of effective control technologies are highly demanding.

• Journal of Korean Society for Atmospheric Environment
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• 제22권6호
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• pp.779-790
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• 2006

This study examines relative contributions of volatile organic compounds (VOCs) to the formation of hydroxyl (OH) and peroxy radicals such as $HO_2$ and $RO_2$ during the intensive sampling period (Jun. $1{\sim}30$, 2004) in the air of Seoul metropolitan area. As to the contribution of VOCs to $HO_x$ levels, the impact of individual VOC concentration change on $HO_2$ concentration change was more than an order of magnitude higher than that on OH concentration change during the study period. The contribution of change in isoprene concentration to $HO_2$ concentration change was 38 times higher than OH and that in the concentration of alkene compounds to $HO_2$ concentration change was 31 times higher than OH. Moreover, the concentration changes of isoprene and aromatic compounds (AROM) played significant roles in $HO_x$ concentration changes. On the other hands, aldehydes (ALD2) and alkanes (ALKA) showed anti-correlation (negative) in $HO_x$ concentration changes with low contribution ($-4{\times}10^{-3}$ pptv/ppbv (OH) and $-58{\times}10^{-3}$ ($HO_2$) for ALD2; $-1{\times}10^{-3}$ (OH) and $-15{\times}10^{-3}$ ($HO_2$) for ALKA). Unlike other VOCs, $C_2H_6$ and $C_3H_8$ showed positive or negative contribution to peroxy radicals, depending on ambient air conditions. The contribution of VOC concentration changes to changes in $CH_3O_2$ and $RO_2$ concentration showed similar pattern to $HO_x$ contribution.

• Analytical Science and Technology
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• 제19권6호
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• pp.544-552
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• 2006

Emission tests were carried out to investigate the characteristics of concentration according to flooring sort using small chamber method. The target Volatile Organic Compounds (VOC) included 27 individual compounds of environmental concern, which were determined by adsorption sampling and thermal desorption coupled with GC/MS method and by DNPH cartridge/HPLC method. The emission factor of Total Volatile Organic Compounds (TVOC) and Formaldehyde (HCHO) was detected $0.3mg/m^2{\cdot}h$ and $0.2mg/m^2{\cdot}h$ respectively, and the floorings of 37 (9 PVC Tile, 10 PVC Sheet, 18 Flooring) were satisfied emission standard. TVOC emission factor appeared in order of concentration of PVC Sheet, PVC Tile, and floor flooring, while HCHO was detected very high emission factor (as $0.4mg/m^2{\cdot}h$) at floor flooring above PVC series (as $0.001mg/m^2{\cdot}h$).

• Journal of Korean Society for Atmospheric Environment
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• 제34권2호
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• pp.244-258
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• 2018

We performed this study to investigate the spatial, seasonal, and daily variations of the concentrations of volatile organic compounds (VOCs) in Pohang, where large steel industrial complexes are located. Ambient air sampling was undertaken at 4 sites during 4 seasons. Each sample was taken for 4 hours continuously for 8 consecutive days per season at each site. Three sites were located within the Pohang city, but one as a control site in Gyeongju. A total of 72 individual VOCs were determined by thermal desorption coupled with GC/MS, including aliphatics, aromatics, carbonyls and halides. The most abundant VOC was toluene, being followed by ethylbenzene and xylenes. Benzene concentrations(c.a. 0.7 ppb) were found to be much lower than the national ambient standard of 1.5 ppb. Overall, the VOCs levels in Pohang appeared to be lower than other national industrial complexes in Korea such as Shiwha-Banwol, Yeosu-Gwangyang, Gumi, and Ulsan. This implies that steel industry may not give significant impacts on the atmospheric levels of VOCs as much as petrochemical, electronic, and/or textile industries, where large amounts of organic solvents are used.

• KSII Transactions on Internet and Information Systems (TIIS)
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• 제14권12호
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• pp.4706-4724
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• 2020

With various structured data, such as the company size, loan balance, and savings accounts, the voice of customer (VOC), which is text data containing contact history and counseling details was analyzed in this study. To analyze unstructured data, the term frequency-inverse document frequency (TF-IDF) analysis, semantic network analysis, sentiment analysis, and a convolutional neural network (CNN) were implemented. A performance comparison of the models revealed that the predictive model using the CNN provided the best performance with regard to predictive power, followed by the model using the TF-IDF, and then the model using semantic network analysis. In particular, a character-level CNN and a word-level CNN were developed separately, and the character-level CNN exhibited better performance, according to an analysis for the Korean language. Moreover, a systematic selection model for optimal text mining techniques was proposed, suggesting which analytical technique is appropriate for analyzing text data depending on the context. This study also provides evidence that the results of previous studies, indicating that individual customers leave when their loyalty and switching cost are low, are also applicable to corporate customers and suggests that VOC data indicating customers' needs are very effective for predicting their behavior.

• Asian Journal of Atmospheric Environment
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• 제8권4호
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• pp.192-201
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• 2014

A comprehensive profile of volatile organic compounds (VOCs) in public spaces is needed for interpreting indoor air measurements. Seasonal differences in profiles are critical for epidemiological study and risk assessment. The purposes of this study were to establish profiles for individual VOCs in 50 indoor public places in Korea and to determine seasonal variations in their concentrations. Air samples were taken during working hours. Seventy-two of the 91 targeted VOCs were identified using multiple standards. Six VOCs detected in all summer and winter samples were toluene, acetone, m,p-xylenes, ethylbenzene, benzene, and styrene. In summer, methyl ethyl ketone and 1-butanol were also found in all samples. In both seasons, the dominant indoor VOCs were toluene, m,p-xylenes, ethylbenzene, acetone, and isopropyl alcohol. Other chemicals associated with gasoline emissions were dominant in summer. Limonene was dominant only in winter due to the consumption of tangerines. The nine VOCs with the highest concentrations comprised 64.8% and 49.6% of the TVOC in summer and winter, respectively. Comparing two types of adsorbent tube, a single adsorbent tube with Tenax-TA had similar detection performance as a double adsorbent tube with Tenax and Carbotrap.